Infrared and ultraviolet radiation absorbing blue glass composition

• US 5,688,727 A
• Filed: 06/17/1996
• Issued: 11/18/1997
• Est. Priority Date: 06/17/1996
• Status: Expired due to Term

• Current Assignee: Vitro Flat Glass LLC (Compagnie De Saint-Gobain)
• Original Assignee: PPG Industries Incorporated (Nouryon BV)
• Inventors: Shelestak, Larry J., Haskins, David R.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): GROUP, KARL E
• Application Number:
  US08/664,942
• Time in Patent Office: 519 Days
• Field of Search: 501/70, 501/71
• US Class Current: 501/71
• CPC Class Codes: C03C 3/087 containing calcium oxide, e.g. common sheet or container glass
• CPC Class Codes: C03C 4/02 for coloured glass
• CPC Class Codes: C03C 4/082 for infrared absorbing glass
• CPC Class Codes: C03C 4/085 for ultraviolet absorbing glass

Abstract

The present invention provides a blue colored glass using a standard soda-lime-silica glass base composition and additionally iron and cobalt as solar radiation absorbing materials and colorants. In particular, the blue colored glass includes about 0.53 to 1.1 wt. % total iron, preferably about 0.6 to 0.85 wt. % and about 5 to 40 PPM CoO, preferably about 15 to 30 PPM and a luminous transmittance of at least 55%. If desired, the composition may include up to about 100 PPM Cr₂ O₃. The redox ratio for the glass of the present invention is maintained between about 0.25 to 0.35, preferably between about 0.28 to 0.33. The glass color is characterized by a dominant wavelength (DW) of about 485 to 491 nanometers and an excitation purity (Pe) of about 3 to 18 percent. In one particular embodiment of the invention, the color of the glass is characterized by a dominant wavelength in the range of about 487 to 489 nanometers and an excitation purity of about 3 to 8 percent at a thickness of about 0.084 to 0.126 inches, an excitation purity of about 5 to 12 percent at a thickness of about 0.126 to 0.189 inches, and an excitation purity of about 10 to 18 percent at a thickness of about 0.189 to 0.315 inches.

Claims

1. A blue colored, infrared and ultraviolet radiation absorbing glass composition having a base glass portion comprising:

SiO₂ about 66 to 75 percent by weight

Na₂ O about 10 to 20 percent by weight

CaO about 5 to 15 percent by weight

MgO 0 to about 5 percent by weight

Al₂ O₃ 0 to about 5 percent by weight

K₂ O 0 to about 5 percent by weight

and a solar radiation absorbing and colorant portion consisting essentially of;

total iron about 0.53 to 1.1 percent by weight

CoO about 5 to 40 PPM

Cr₂ O₃ 0 to about 100 PPM,

the glass having a redox of about 0.25 to 0.35, a luminous transmittance of at least 55%, and a color characterized by a dominant wavelength of 485 to 489 nanometers and an excitation purity of about 3 to 18 percent.

2. The composition as in claim 1 wherein the total iron concentration is from about 0.6 to 0.85 weight percent and the redox is from about 0.28 to 0.33.

3. The composition as in claim 2 wherein the CoO concentration is from about 15 to 30 PPM.

4. The composition as in claim 3 wherein the color of the glass is characterized by a dominant wavelength in the range of 487 to 489 nanometers and an excitation purity of about 3 to 8 percent at a thickness of about 0.084 to 0.126 inches, an excitation purity of about 5 to 12 percent at a thickness of about 0.126 to 0.189 inches, and an excitation purity of about 10 to 18 percent at a thickness of about 0.189 to 0.315 inches.

5. The composition as in claim 4 wherein the glass has a luminous transmittance of about 70 percent or greater.

6. The composition as in claim 4 wherein the glass has a solar transmittance of about 60 to 70 percent and a shading coefficient of about 0.70 or less.

7. The composition as in claim 1 wherein the CoO concentration is from about 15 to 30 PPM.

8. The composition as in claim 1 wherein the Cr₂ O₃ concentration is from about 25 to 50 PPM.

9. The composition as in claim 1 wherein the glass has a luminous transmittance of about 70 percent or greater.

10. The composition as in claim 9 wherein the glass has a total solar ultraviolet transmittance of about 60 percent or less, a total solar infrared transmittance of about 35 percent or less and a total solar energy transmittance of about 55 percent or less at a thickness of about 0.154 inches.

11. The composition as in claim 10 wherein the glass has a total solar ultraviolet transmittance of about 50 percent or less, a total solar infrared transmittance of about 30 percent or less and a total solar energy transmittance of about 50 percent or less at a thickness of about 0.154 inches.

12. The composition as in claim 1 wherein the glass has a solar transmittance of about 60 to 70 percent and a shading coefficient of about 0.70 or less at a thickness of about 0.223 inches.

13. The composition as in claim 12 wherein the glass has a solar transmittance of about 63 to 67 percent and a shading coefficient of about 0.65 or less at a thickness of about 0.223 inches.

14. The composition as in claim 1 wherein the color of the glass is characterized by a dominant wavelength in the range of 487 to 489 nanometers.

15. The composition as in claim 1 wherein the color of the glass is characterized by an excitation purity of about 3 to 8 percent at a thickness of about 0.084 to 0.126 inches, an excitation purity of about 5 to 12 percent at a thickness of about 0.126 to 0.189 inches, and an excitation purity of about 10 to 18 percent at a thickness of about 0.189 to 0.315 inches.

16. A glass sheet made from the composition as recited in claim 1.

17. The glass sheet as in claim 16 wherein the sheet has a thickness between 1.8 to 10 mm.

18. A blue colored, infrared and ultraviolet radiation absorbing glass composition having a base glass portion comprising:

SiO₂ about 66 to 75 percent by weight

Na₂ O about 10 to 20 percent by weight

CaO about 5 to 15 percent by weight

MgO 0 to about 5 percent by weight

Al₂ O₃ 0 to about 5 percent by weight

K₂ O 0 to about 5 percent by weight

and a solar radiation absorbing and colorant portion consisting essentially of;

total iron about 0.53 to 1.1 percent by weight

CoO about 5 to 40 PPM

SnO₂ 0 to about 2.0 percent by weight

CeO₂ 0 to about 1.0 percent by weight

TiO₂ 0 to about 0.5 percent by weight

ZnO 0 to about 0.5 percent by weight

Nd₂ O₃ 0 to about 0.5 percent by weight

MnO₂ 0 to about 0. 1 percent by weight

MoO₃ 0 to about 100 PPM

Cr₂ O₃ 0 to about 100 PPM,

V₂ O₅ 0 to about 75 PPM

NiO 0 to about 10 PPM

Se 0 to about 3 PPM

the glass having a redox of about 0.25 to 0.35, a luminous transmittance of at least 55%, and a color characterized by a dominant wavelength of 485 to 489 nanometers and an excitation purity of about 3 to 18 percent.

19. The composition as in claim 18 wherein the color of the glass is characterized by a dominant wavelength in the range of 487 to 489 nanometers and an excitation purity of about 3 to 8 percent at a thickness of about 0.084 to 0.126 inches, an excitation purity of about 5 to 12 percent at a thickness of about 0.126 to 0.189 inches, and an excitation purity of about 10 to 18 percent at a thickness of about 0.189 to 0.315 inches.

20. A blue colored, infrared and ultraviolet radiation absorbing glass composition having a base glass portion comprising:

SiO₂ about 66 to 75 percent by weight

Na₂ O about 10 to 20 percent by weight

CaO about 5 to 15 percent by weight

MgO 0 to about 5 percent by weight

Al₂ O3 0 to about 5 percent by weight

K₂ O 0 to about 5 percent by weight

and a solar radiation absorbing and colorant portion consisting essentially of;

total iron about 0.53 to 1.1 percent by weight

CoO about 5 to 40 PPM

Cr₂ O₃ 0 to about 100 PPM,

the glass having a redox of about 0.25 to 0.35, a luminous transmittance of at least 65% at a thickness of 3.9 mm, and a color characterized by a dominant wavelength of about 485 to 491 nanometers and an excitation purity of about 3 to 18 percent.

21. The composition as in claim 20 wherein the total iron concentration is from about 0.6 to 0.85 weight percent and the redox is from about 0.28 to 0.33.

22. The composition as in claim 21 wherein the CoO concentration is from about 15 to 30 PPM.

23. The composition as in claim 22 wherein the color of the glass is characterized by a dominant wavelength in the range of about 487 to 489 nanometers and an excitation purity of about 3 to 8 percent at a thickness of about 0.084 to 0.126 inches, an excitation purity of about 5 to 12 percent at a thickness of about 0.126 to 0.189 inches, and an excitation purity of about 10 to 18 percent at a thickness of about 0.189 to 0.315 inches.

24. The composition as in claim 23 wherein the glass has a luminous transmittance of about 70 percent or greater.

25. The composition as in claim 23 wherein the glass has a solar transmittance of about 60 to 70 percent and a shading coefficient of about 0.70 or less.

26. The composition as in claim 20 wherein the CoO concentration is from about 15 to 30 PPM.

27. The composition as in claim 20 wherein the Cr₂ O₃ concentration is from about 25 to 50 PPM.

28. The composition as in claim 20 wherein the glass has a luminous transmittance of about 70 percent or greater.

29. The composition as in claim 28 wherein the glass has a total solar ultraviolet transmittance of about 60 percent or less, a total solar infrared transmittance of about 35 percent or less and a total solar energy transmittance of about 55 percent or less at a thickness of about 0.154 inches.

30. The composition as in claim 29 wherein the glass has a total solar ultraviolet transmittance of about 50 percent or less, a total solar infrared transmittance of about 30 percent or less and a total solar energy transmittance of about 50 percent or less at a thickness of about 0.154 inches.

31. The composition as in claim 20 wherein the glass has a solar transmittance of about 60 to 70 percent and a shading coefficient of about 0.70 or less at a thickness of about 0.223 inches.

32. The composition as in claim 31 wherein the glass has a solar transmittance of about 63 to 67 percent and a shading coefficient of about 0.65 or less at a thickness of about 0.223 inches.

33. The composition as in claim 20 wherein the color of the glass is characterized by a dominant wavelength in the range of about 487 to 489 nanometers.

34. The composition as in claim 20 wherein the color of the glass is characterized by an excitation purity of about 3 to 8 percent at a thickness of about 0.084 to 0.126 inches, an excitation purity of about 5 to 12 percent at a thickness of about 0.126 to 0.189 inches, and an excitation purity of about 10 to 18 percent at a thickness of about 0.189 to 0.315 inches.

35. A glass sheet made from the composition as recited in claim 20.

36. The glass sheet as in claim 35 wherein the sheet has a thickness between 1.8 to 10 mm.

37. A blue colored, infrared and ultraviolet radiation absorbing glass composition having a base glass portion comprising:

SiO₂ about 66 to 75 percent by weight

Na₂ O about 10 to 20 percent by weight

CaO about 5 to 15 percent by weight

MgO 0 to about 5 percent by weight

Al₂ O₃ 0 to about 5 percent by weight

K₂ O 0 to about 5 percent by weight

and a solar radiation absorbing and colorant portion consisting essentially of;

total iron about 0.53 to 1.1 percent by weight

CoO about 5 to 40 PPM

SnO₂ 0 to about 2.0 percent by weight

CeO₂ 0 to about 1.0 percent by weight

TiO₂ 0 to about 0.5 percent by weight

ZnO 0 to about 0.5 percent by weight

Nd₂ O₃ 0 to about 0.5 percent by weight

MnO₂ 0 to about 0.1 percent by weight

MoO₃ 0 to about 100 PPM

Cr₂ O₃ 0 to about 100 PPM,

V₂ O₅ 0 to about 75 PPM

NiO 0 to about 10 PPM

Se 0 to about 3 PPM

the glass having a redox of about 0.25 to 0.35, a luminous transmittance of at least 65% at a thickness of 3.9 mm, and a color characterized by a dominant wavelength of about 485 to 491 nanometers and an excitation purity of about 3 to 18 percent.

38. The composition as in claim 37 wherein the color of the glass is characterized by a dominant wavelength in the range of about 487 to 489 nanometers and an excitation purity of about 3 to 8 percent at a thickness of about 0.084 to 0.126 inches, an excitation purity of about 5 to 12 percent at a thickness of about 0.126 to 0.189 inches, and an excitation purity of about 10 to 18 percent at a thickness of about 0.189 to 0.315 inches.