Manufacturing process of rubber layered structure

• US 5,690,768 A
• Filed: 10/20/1995
• Issued: 11/25/1997
• Est. Priority Date: 11/22/1990
• Status: Expired due to Fees

• Current Assignee: Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Original Assignee: Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Inventors: Yasukawa, Takemasa, Iwasa, Tadanobu
• Primary Examiner(s): Ball, Michael W.
• Assistant Examiner(s): YAO, SAMCHUAN CUA
• Application Number:
  US08/545,932
• Time in Patent Office: 767 Days
• Field of Search: 156/108, 156/244.11, 156/308.2, 156/309.9, 156/324, 156/334, 156/244.23
• US Class Current: 156/108
• CPC Class Codes: B32B 2262/0276 Polyester fibres
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 25/08 of synthetic resin
• CPC Class Codes: B32B 25/16 comprising polydienes homopolymers or poly-halodienes homopolymers B32B25/12 takes precedence
• CPC Class Codes: B32B 2605/08 Cars
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/12 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B60J 10/15 characterised by the material
• CPC Class Codes: B60J 10/16 consisting of two or more plastic materials having different physical or chemical properties B60J10/17 takes precedence
• CPC Class Codes: B60J 10/17 provided with a low-friction material on the surface
• CPC Class Codes: B60J 10/24 having tubular parts
• CPC Class Codes: B60J 10/74 for sliding window panes, e.g. sash guides
• CPC Class Codes: B60J 10/75 for sealing the lower part of the panes
• CPC Class Codes: B60J 10/80 specially adapted for opening panels, e.g. doors for non-fixed roofs B60J10/90
• CPC Class Codes: Y10T 428/23943 Flock surface
• CPC Class Codes: Y10T 428/24198 Channel-shaped edge component [e.g., binding, etc.]
• CPC Class Codes: Y10T 428/24736 Ornamental design or indicia
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31913 : Monoolefin polymer
• CPC Class Codes: Y10T 428/31917 : Next to polyene polymer
• CPC Class Codes: Y10T 428/3192 : Next to vinyl or vinylidene chloride polymer
• CPC Class Codes: Y10T 428/31924 : Including polyene monomers
• CPC Class Codes: Y10T 428/31928 : Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 442/679 : Natural or synthetic rubber sheet or film

Abstract

A rubber layered structure used for a weather strip or a glass run, which includes an EPDM rubber base and an ornamental surface layer or a functional surface layer for enhancing slidability of a door glass. An ornamental or functional surface layer is stuck to an EPDM rubber base with a laminated film. The laminated film includes a first layer of an olefin resin with polar functional groups and a second layer of a polar thermoplastic resin. The first layer, which includes a non-polar olefin resin and polar functional groups, adheres to both the EPDM rubber base and the second layer of a polar resin such as polyester. The second layer securely adheres to the surface layer.

Claims

1. A method of forming a rubber layered structure having a EPDM rubber base layer and a laminated film layer, comprising the steps of:

(a) preparing a laminated film comprising a first film layer of a non-polar olefin resin modified by the introduction of maleic arthydride to form a modified olefin resin, said modified olefin resin being directly bondable to the EPDM rubber base layer, and a second film layer of a polar thermoplastic resin directly attached to said modified olefin resin first film layer;

(b) extrusion-forming said EPDM rubber base layer;

(c) vulcanizing said EPDM rubber base layer; and

(d) attaching and roller pressing said non-polar olefin first film layer onto said EPDM rubber base layer by melting and re-solidifying at least surface of said non-polar olefin first film layer with heat from said EPDM rubber base layer remaining from said vulcanizing step.

2. A method according to claim 1, wherein said rubber layered structure is a weather strip for sealing an opening of an automobile body, and said laminated film further comprises an ornamental surface layer.

3. A method according to claim 2, wherein said second film of said polar thermoplastic resin layer is made of a polyester resin, and said ornamental surface layer is made of a polyester fabric.

4. A method as in claim 1, wherein said rubber layered structure is a glass run for sealing and guiding a window glass of an automobile, the method of forming a rubber layered structure includes the further step of attaching a surface layer onto said second film layer with the surface layer comprising a surface for reducing sliding resistance of the window glass.

5. A method according to claim 4, wherein said second film layer of said polar thermoplastic resin is made of a polyester resin, and the surface layer is made of a polyester fabric.

6. A method according to claim 4, wherein the surface layer is attached onto said polar thermoplastic resin layer of the laminated film layer during said preparing step, and wherein at said attaching and roller pressing step said modified olefin first film layer is roller pressed onto at least the portion of the EPDM rubber base that is to contact the window glass.

7. A method as in claim 1 wherein the vulcanizing step heats the EPDM rubber base layer to a temperature between about 180°

C. to 240°

C. and the step of attaching and roller pressing occurs immediately following vulcanizing.