Polymetric film

• US 5,690,994 A
• Filed: 06/05/1995
• Issued: 11/25/1997
• Est. Priority Date: 02/17/1992
• Status: Expired due to Term

• Current Assignee: Imperial Chemical Industries PLC (IMPERIAL CHEMICAL INDUSTRIES)
• Original Assignee: Imperial Chemical Industries PLC (IMPERIAL CHEMICAL INDUSTRIES)
• Inventors: Robinson, Julian Neal
• Primary Examiner(s): Hill, Jr., Robert J.
• Assistant Examiner(s): Delaney, Patrick R.
• Application Number:
  US08/465,096
• Time in Patent Office: 904 Days
• Field of Search: 428/411.1, 428/482, 428/516, 428/520, 430/533, 430/528, 427/171, 427/407.1
• US Class Current: 427/171
• CPC Class Codes: G03C 1/91 characterised by subbing layers or subbing means
• CPC Class Codes: G03C 1/93 Macromolecular substances therefor
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31794 Of cross-linked polyester
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer

Abstract

A coated film having a polymeric film substrate with a subbing layer containing an organic acid and a polymer which has a repeating unit(s) containing a pendant nitrogen atom(s). The ratio of organic acid to polymer in the subbing layer is in the range from 1:0.1 to 20 by weight. The coated film exhibits excellent adhesion to photographic emulsion layers, even when applied prior to completion of any film stretching operation.

Claims

1. A method of producing a coated film by forming a substrate layer of polymeric material, and applying, prior to the completion of any film stretching operation, to at least one surface of the substrate, a subbing layer composition comprising an organic acid which has a molecular weight in the range from 70 to 800 and a polymer comprising at least one or more repeating units comprising at least one or more pendant nitrogen atoms, the ratio of organic acid to polymer in the subbing layer being in the range from 1:

0.1 to 20 by weight, said repeating unit having the structure ##STR2## wherein Z represents amine, amide, quaternary ammonium, and/or wherein Z is protonated and associated with a negatively charged counter ion wherein the counter ion is selected from the group consisting of halide, phosphate and carboxylate,

R₁, R₂ and R₃ are the same or different and represent hydrogen, halogen, alkyl, nitrile, amine, amide, quaternary ammonium, ketone, ether, vinyl, and/or halide, phosphate or carboxylate salts thereof, and

Y, Y₁, Y₂ and Y₃ are optional alkylene groups having up to 10 carbon atoms, which may be the same or different.

2. A method according to claim 1 wherein the subbing layer is applied to the substrate between the two stages (longitudinal and transverse) of a biaxial stretching operation.

3. A method according to claim 1 wherein the coated film is heat set at a temperature in the range from 150°

to 250°

C.

4. A method according to claim 1 wherein the thickness of the subbing layer is in the range from 0.005 to 2.0 μ

m.

5. A method according to claim 4 wherein the thickness of the subbing layer is in the range from 0.025 to 0.3 μ

m.

6. A method according to claim 1 wherein the polymer comprises greater than 60 mole % of repeating units comprising at least one or more pendant nitrogen atoms.

7. A method according to claim 1 wherein Z represents a primary amine and/or salt thereof.

8. A method according to claim 1 wherein the repeating unit is derived during the polymerisation of monoallylamine and/or N-substituted monoallylamines.

9. A method according to claim 1 wherein the organic acid comprises a sulphonic acid group.

10. A method according to claim 1 wherein the subbing layer composition comprises a cross-linking agent.

11. A method of producing a coated film by forming a substrate layer of polymeric material, and applying, prior to the completion of any film stretching operation, to at least one surface of the substrate, a subbing layer composition comprising an organic acid having a molecular weight of from 70 to 800 and a polymer comprising a homopolymer derived during polymerization of monoallylamine and/or N-hydrocarbyl substituted monoallylamines, the ratio of organic acid to polymer in the subbing layer being in the range from 1:

0.1 to 20 by weight.

12. A method of producing a coated film by forming a substrate layer of polymeric material, and applying, prior to the completion of any film stretching operation, to at least one surface of the substrate, a subbing layer composition comprising an organic acid which has a molecular weight in the range from 70 to 800 and a polymer comprising greater than 60 mole % of at least one or more repeating units comprising at least one or more pendant nitrogen atoms, wherein the repeating unit has the general structure ##STR3## wherein Z represents amine, amide, quaternary ammonium, and/or wherein Z is protonated and associated with a negatively charged counter ion wherein the counter ion is selected from the group consisting of halide, phosphate and carboxylate,

R₁, R₂ and R₃ are the same or different and represent hydrogen, halogen, alkyl, nitrile, amine, amide, quaternary ammonium, ketone, ether, vinyl, and/or halide, phosphate or carboxylate salts thereof, and Y, Y₁, Y₂ and Y₃ are optional and, if present, represent an alkylene group having up to 10 carbon atoms, the ratio of organic acid to polymer in the subbing layer being in the range from 1:

0.1 to 20 by weight.