Method of preparing beta titanium-fiber reinforced composite laminates

• US 5,693,157 A
• Filed: 08/01/1996
• Issued: 12/02/1997
• Est. Priority Date: 10/18/1993
• Status: Expired due to Fees

• Current Assignee: Salzburtg Trading Corporation
• Original Assignee: Ticomp, Inc.
• Inventors: Kingston, William R.
• Primary Examiner(s): SHEEHAN, JOHN P
• Application Number:
  US08/690,801
• Time in Patent Office: 488 Days
• Field of Search: 148/421, 148/516, 148/518, 148/537, 148/670, 148/527, 428/608, 428/622, 428/634, 428/635, 428/457, 428/614, 428/626, 428/660, 428/670, 428/668, 427/388.1, 427/376.8, 156/153, 156/281, 156/330
• US Class Current: 148/537
• CPC Class Codes: A63B 2102/18 Baseball, rounders or similar games
• CPC Class Codes: A63B 2209/02 with reinforcing fibres, e.g. carbon, polyamide fibres
• CPC Class Codes: A63B 53/12 Metallic shafts
• CPC Class Codes: A63B 59/50 Substantially rod-shaped bats for hitting a ball in the air, e.g. for baseball
• CPC Class Codes: A63B 60/54 with means for damping vibrations
• CPC Class Codes: B32B 15/043 of metal B32B15/01 takes precedence
• CPC Class Codes: B32B 15/08 of synthetic resin
• CPC Class Codes: B32B 15/14 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 2038/0016 Abrading
• CPC Class Codes: B32B 2038/0076 Curing, vulcanising, cross-linking
• CPC Class Codes: B32B 2262/101 Glass fibres
• CPC Class Codes: B32B 2262/106 Carbon fibres, e.g. graphite fibres
• CPC Class Codes: B32B 2305/08 Reinforcements
• CPC Class Codes: B32B 2311/00 Metals, their alloys or their compounds
• CPC Class Codes: B32B 2311/06 Platinum
• CPC Class Codes: B32B 2311/18 Titanium
• CPC Class Codes: B32B 38/0036 Heat treatment for heating or cooling of layers during lamination B32B37/06, B32B37/08
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: Y10T 428/12444 Embodying fibers interengaged or between layers [e.g., paper, etc.]
• CPC Class Codes: Y10T 428/12542 More than one such component
• CPC Class Codes: Y10T 428/12569 : Synthetic resin
• CPC Class Codes: Y10T 428/12806 : Refractory [Group IVB, VB, or VIB] metal-base component
• CPC Class Codes: Y10T 428/12875 : Platinum group metal-base component
• CPC Class Codes: Y10T 428/31678 : Of metal

Abstract

A method of preparing a beta titanium-fiber reinforced composite laminate comprising the steps of, first, providing a beta titanium alloy having a first yield strength to modulus of elasticity ratio; then, heating the beta titanium alloy at a first preselected temperature for a first preselected time to produce a beta titanium alloy having a second yield strength to modulus of elasticity ratio; and then, adhering a fiber reinforced composite having a strength to modulus of elasticity ratio to the beta titanium alloy to produce a beta titanium-fiber reinforced composite laminate; wherein the first preselected temperature and the first preselected time are preselected such that the second yield strength to modulus of elasticity ratio of the beta titanium alloy is substantially similar to the strength to modulus of elasticity ratio of the fiber reinforced composite.

Claims

1. A method of preparing a beta titanium-fiber reinforced composite laminate comprising the steps of:

(a) providing a beta titanium alloy having a surface with an area and having a first yield strength to modulus of elasticity ratio;

(b) heating the beta titanium alloy at a first temperature for a first time to produce a beta titanium alloy having a second yield strength to modulus of elasticity ratio; and

(c) adhering a fiber reinforced composite having a strength to modulus of elasticity ratio to the beta titanium alloy to produce a beta titanium-fiber reinforced composite laminate;

wherein the first temperature and the first time are such that the second yield strength to modulus of elasticity ratio of the beta titanium alloy is substantially similar to the strength to modulus of elasticity ratio of the fiber reinforced composite.

2. The method of claim 1, additionally comprising a step of coating the surface of the beta titanium alloy with a noble metal to produce a coated beta titanium alloy after the providing step (a).

3. The method of claim 2, wherein the noble metal is platinum.

4. The method of claim 1, additionally comprising a step of abrading the surface of the beta titanium alloy to increase the area of the surface after the providing step (a).

5. The method of claim 1, additionally comprising a step of priming the surface with a primer after the heating step (b).

6. The method of claim 5, wherein the primer is a low solid, high solvent epoxy glue.

7. The method of claim 1, wherein the adhering step (c) comprises applying an adhesive to the surface of the beta titanium alloy.

8. The method of claim 1, wherein the adhering step (c) comprises heating the beta titanium alloy and the fiber reinforced composite at a second temperature for a second time.

9. The method of claim 1, wherein the beta titanium alloy provided in step (a) is selected from the group consisting of (Ti 15V-3Cr-3Al-3Sn), (Ti 15Mo-3Al-3Nb), (Ti 3Al-8V-6Cr-4Zr-4Mo) and (Ti 13V-11Cr-3Al).

10. The method of claim 1, wherein the fiber reinforced composite of step (c) is selected from the group consisting of graphite reinforced epoxies and S2-glass reinforced epoxies.

11. The method of claim 1, wherein the first temperature of step (b) is approximately 510°

C. and the first time of step (b) is approximately 8 hours.

12. The method of claim 1, wherein the second yield strength to modulus of elasticity ratio of the beta titanium alloy produced by step (b) is within about 40% of the strength to modulus of elasticity ratio of the fiber reinforced composite of step (c).

13. The method of claim 1, wherein the second yield strength to modulus of elasticity ratio of the beta titanium alloy produced by step (b) is within about 10% of the strength to modulus of elasticity ratio of the fiber reinforced composite of step (c).

14. A method of making an article of manufacture, comprising the steps of:

(i) preparing a beta titanium-fiber reinforced composite laminate according to the method of claim 1; and

(ii) incorporating the beta titanium-fiber reinforced composite laminate into the article of manufacture.

15. The method of making an article of manufacture of claim 14, wherein the article of manufacture of step (ii) is selected from the group consisting of a motor vehicle, a golf club, a softball bat, a ski, a surf board, a snow board and a container.

16. The method of making an article of manufacture of claim 14, wherein the article of manufacture of step (ii) is a motor vehicle part.

17. A method of preparing a metal-fiber reinforced composite laminate comprising the steps of:

(a) providing a metal having a surface with an area and having a first yield strength to modulus of elasticity ratio;

(b) heating the metal at a first temperature for a first time to produce a metal having a second yield strength to modulus of elasticity ratio; and

(c) adhering a fiber reinforced composite having a strength to modulus of elasticity ratio to the metal to produce a metal-fiber reinforced composite laminate;

wherein the first temperature and the first time are such that the second yield strength to modulus of elasticity ratio of the metal is substantially similar to the strength to modulus of elasticity ratio of the fiber reinforced composite; and

wherein the metal has a second yield strength to modulus of elasticity ratio that is greater than about 1.2%.