Composite film for windows comprising a non-stoichiometric aluminum oxide layer

• US 5,693,415 A
• Filed: 06/21/1995
• Issued: 12/02/1997
• Est. Priority Date: 06/21/1995
• Status: Expired due to Term

• Current Assignee: Hanita Coatings RCA Ltd (Avery Dennison Corporation)
• Original Assignee: Hanita Coatings
• Inventors: Eisenstadt, Dan, Matalon-Cohen, Avigail, Zait, Eitan
• Primary Examiner(s): Le, H. Thi
• Application Number:
  US08/493,262
• Time in Patent Office: 895 Days
• Field of Search: 428/458, 428/469, 428/472.2, 428/412, 428/480, 428/421, 428/332, 428/336, 428/337, 428/702, 428/913
• US Class Current: 428/332
• CPC Class Codes: B32B 15/08 of synthetic resin
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 2369/00 Polycarbonates
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 27/365 comprising polycarbonates
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: C09J 2301/16 by the structure of the carrier layer
• CPC Class Codes: C09J 2400/163 in the substrate
• CPC Class Codes: C09J 2427/006 in the substrate
• CPC Class Codes: C09J 2467/006 in the substrate
• CPC Class Codes: C09J 7/20 characterised by their carriers
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/266 of base or substrate
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/3154 Of fluorinated addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31786 : Of polyester [e.g., alkyd, etc.]

Abstract

A composite film adhereable to a surface of an object for changing its thermal and optical properties. According to one preferred embodiment the composite film includes a substrate, a non stoichiometric aluminum oxide layer deposited on one side of said substrate, and an adhesive layer for coating said non stoichiometric aluminum oxide layer, whereby said composite film is adhereable to a surface of said object. According to a second preferred embodiment the composite film includes a substrate, a first aluminum metal layer deposited on one side of said substrate, an aluminum oxide layer deposited on said first aluminum layer, a second aluminum layer deposited on said aluminum oxide layer, and an adhesive layer for coating said aluminum oxide layer, whereby said composite film is adhereable to a surface of said object. According to yet another preferred embodiment of the present invention the composite film includes a substrate, a first aluminum oxide layer deposited on one side of said substrate, an aluminum metal layer deposited on said first aluminum layer, a second aluminum oxide layer deposited on said aluminum oxide layer and an adhesive layer for coating said aluminum oxide layer, whereby said composite film is adhereable to a surface of said object.

Claims

1. A composite film adhereable to a surface of an object for changing its thermal and optical properties comprising:

a substrate;

a layer consisting of nonstoichiometric aluminum oxide deposited on one side of said substrate and bonded thereto, said non stoichiometric aluminum oxide layer having a substantially uniform thickness; and

an adhesive layer for coating said nonstoichiometric aluminum oxide layer on its side opposite said substrate, whereby said composite film is adhereable to a surface of said object.

2. A composite film according to claim 1 and also comprising a protective layer between said non stoichiometric aluminum oxide layer and said adhesive layer, said protective layer being adhesively secured to said aluminum oxide layer.

3. A composite film according to claim 1 wherein said substrate is selected from the group consisting of polyester, polyvynilydene fluoride and polycarbonate.

4. A composite film according to claim 3 wherein said polyester is selected from the group consisting of polyethylene terephthalate and polyethylene naphthalate.

5. A composite film according to claim 4 wherein the thickness of said substrate ranges between 10-200 microns.

6. A composite film according to claim 1 wherein said non stoichiometric aluminum oxide layer comprises a surplus of aluminum with respect to stoichiometric Al₂ O₃.

7. A composite film according to claim 6 wherein said non stoichiometric aluminum oxide layer is deposited by thermal evaporation on said substrate wherein said substrate is moving in a selected rate during said deposition, whereby the substantially constant thickness of said non stoichiometric aluminum oxide layer is determined.

8. A composite film according to claim 6 wherein the thickness of said non stoichiometric aluminum oxide layer ranges between 50-2000 Angstroms, the composite film being a neutral grey color.