Electronically graded multilayer ferroelectric composites

• US 5,693,429 A
• Filed: 05/13/1996
• Issued: 12/02/1997
• Est. Priority Date: 01/20/1995
• Status: Expired due to Fees

• Current Assignee: The United States Of America As Represented By The Secretary Of The Army
• Original Assignee: The United States Of America As Represented By The Secretary Of The Army
• Inventors: Sengupta, Louise C., Sengupta, Somnath, Ngo, Eric, Stowell, Steven, O'Day, Michelina E., Hynes, Thomas V., Lancto, Robert
• Primary Examiner(s): SPEER, TIMOTHY M
• Application Number:
  US08/647,260
• Time in Patent Office: 568 Days
• Field of Search: 428/699, 428/701, 428/702, 343/772, 501/137, 501/153
• US Class Current: 428/699
• CPC Class Codes: B32B 18/00 Layered products essentially comprising ceramics, e.g. refractory products
• CPC Class Codes: C04B 2237/34 Oxidic
• CPC Class Codes: C04B 2237/343 Alumina or aluminates
• CPC Class Codes: C04B 2237/346 Titania or titanates
• CPC Class Codes: C04B 2237/348 Zirconia, hafnia, zirconates or hafnates
• CPC Class Codes: C04B 2237/58 Forming a gradient in composition or in properties across the laminate or the joined articles
• CPC Class Codes: C04B 2237/704 of one or more of the ceramic layers or articles
• CPC Class Codes: C04B 35/465 based on alkaline earth metal titanates
• CPC Class Codes: H01Q 1/38 formed by a conductive layer on an insulating support patch antennas H01Q9/0407; microstrip dipole antennas H01Q9/065; microstrip slot antennas H01Q13/106; transmission line microstrip antennas H01Q13/206; manufacturing reflecting surfaces using insulating material for supporting the reflecting surface H01Q15/142
• CPC Class Codes: H01Q 3/36 with variable phase-shifters
• CPC Class Codes: H01Q 3/44 varying the electric or magnetic characteristics of reflecting, refracting, or diffracting devices associated with the radiating element

Abstract

A laminated ceramic ferroelectric material has adjacent layers of Barium ontium Titanate (BSTO)--oxide composite stacked in order of descending oxide content and sized in thickness to produce a generally equal capacitance across each layer, resulting in a material having a graded dielectric constant for use in phased array antenna, for example. The oxides are from the metallic oxide group consisting of alumina, zirconia and magnesia and the layers are produced by tape casting.

Claims

1. A laminated ceramic ferrolectric material having a graded dielectric constant comprising a plurality of adjacent layers, said layers having no air gaps between the discrete layers and formed of a composition comprising 0 to 100% of Ba_1-x Sr_x TiO₃ wherein x is greater than 0.0 but less than 0.75, and 100 to 0% by weight of at least one low dielectric constant low dielectric loss oxide selected from the group consisting of Al₂ O₃ ZrO₂ and MgO, wherein the ratio of said Ba_1-x Sr_x TiO₃ to said oxide is different in each layer, said layers being arranged in order of decreasing dielectric constant and laminated together.

2. The laminated ceramic ferroelectric material of claim 1 wherein the thickness of said layers varies inversely with the barium-strontium-titanate content of said layers.

3. The laminated ceramic ferroelectric material of claim 1 wherein the thickness of each of said layers is selected to produce a constant capacitance across each of said layers.

4. The laminated ceramic ferroelectric material of claim 3 wherein the thicknesses of said layers are determined in accordance with the equation ε

'"'"'=Ct/Aε

₀ where ε

'"'"' is the dielectric constant of said layer, C is the capacitance of barium-strontium-titanate, t is the thickness of said layer, and A is the area of said material.

5. The laminated ceramic ferroelectric material of claim 1 wherein said ratios of Ba_1-x Sr_x TiO₃ to oxide are selected and arranged to produce a linear grading of dielectric constant.

6. The laminated ceramic ferroelectric material of claim 1 wherein said ratios of Ba_1-x Sr_x TiO₃ to oxide are selected and arranged to produce increments of dielectric grading following a predetermined non-linear function.

7. The laminated ceramic ferroelectric material of claim 1 wherein said low dielectric constant, low dielectric loss oxide is selected from the group consisting of alumina, zirconia, magnesia and mixtures thereof.

8. The laminated ceramic ferroelectric material of claim 1 wherein said layers are laminated together by heating said arranged layers to a temperature in the range of 150°

to 400°

C., uniaxially pressing said layers to a pressure in the range of 5000 to 10,000 psi and sintering said layers.

9. The laminated ceramic ferroelectric material of claim 1 wherein said layers are laminated together by pressing said layers in a warm isostatic press to a pressure in the range of 5000 to 10,000 psi at a temperature of about 70°

C. and sintering said layers.

10. A laminated ceramic ferrolectric material having a selectively graded dielectric constant comprising a plurality of adjacent layers;

said layers having no air gap between the discrete layers, each formed of composition of materials selected from the group consisting of Ba_1-x Sr_x TiO₃ where x is greater than 0.00 but less than 0.75, at least one dielectric constant, low dielectric loss oxide and a low dielectric constant, low dielectric loss adjusting material, wherein the total combined % by weight of said Ba_1-x Sr_x TiO₃, said oxide and said adjusting material equals 100% and each of said compositions contain a different ratio of said materials to produce layers having different dielectric constants;

said layers being arranged in order of of decreasing dielectric constant and laminated together.

11. The laminated ceramic ferroelectric material of claim 10 wherein said low dielectric constant, low dielectric loss adjusting material is selected from the group consisting of polymer and silica and mixtures thereof.

12. The laminated ceramic ferroelectric material of claim 10 wherein said ratios of Ba_1-x Sr_x TiO₃, said oxide and said adjusting material are selected to produce selected increments of dielectric grading and said layers are arranged to follow a predetermined mathematical function.

13. The laminated ceramic ferroelectric material of claim 10 wherein said oxide is selected from the group consisting of alumina, zirconia and magnesia, mixtures thereof.

14. The laminated ceramic ferroelectric material of claim 10 wherein said layers are laminated together by heating said arranged layers to a temperature in the range of 150°

to 400°

C., uniaxially pressing said layers to a pressure in the range of 5000 to 10,000 psi and sintering said layers.

15. The laminated ceramic ferroelectric material of claim 10 wherein said layers are laminated together by pressing said layers in a warm isostatic press to a pressure in the range of 5000 to 10,000 psi at a temperature of about 70°

C. and sintering said layers.

16. The laminated ceramic ferroelectric material of claim 10 wherein said adjusting material comprises 0 to 20% by weight of the total material weight.