Electrostatic-image developer and image forming process

• US 5,693,444 A
• Filed: 12/12/1996
• Issued: 12/02/1997
• Est. Priority Date: 12/18/1995
• Status: Expired due to Term

• Current Assignee: Fuji Xerox Company Limited (Xerox Holdings Corp.)
• Original Assignee: Fuji Xerox Company Limited (Xerox Holdings Corp.)
• Inventors: Takagi, Masahiro, Iizuka, Akihiro, Ishigaki, Satoru, Ichimura, Masanori
• Primary Examiner(s): Rodee, Christopher D.
• Application Number:
  US08/762,875
• Time in Patent Office: 355 Days
• Field of Search: 430/106.6, 430/110, 430/111, 430/126, 430/108
• US Class Current: 430/110.4
• CPC Class Codes: G03G 9/0819 characterised by the dimensions of the particles
• CPC Class Codes: G03G 9/097 Plasticisers; Charge controlling agents
• CPC Class Codes: G03G 9/1075 Structural characteristics of the carrier particles, e.g. shape or crystallographic structure
• CPC Class Codes: G03G 9/1085 with non-ferrous metal oxide, e.g. MgO-Fe2O3

Abstract

An electrostatic-image developer which comprises a toner and a carrier comprising core particles coated with a coating resin, wherein the toner comprises toner particles having a volume-average particle diameter of from 3 to 9 μm and having a specific particle diameter distribution, at least 20% of the total surface area of the toner particles is covered with (a) an external additive having an average particle diameter of from 20 nm to 100 nm, and at least 40% of the total surface area of the toner particles is covered with (b) an external additive having an average particle diameter of from 7 nm to 20 nm, and wherein the core particles of the carrier are magnetic particles formed from a composition comprising 100 parts by weight of a ferrite component represented by the following formula (3):

(M.sub.y O).sub.100-x (Fe.sub.2 O.sub.3).sub.x             (3)

(wherein M is a metal atom selected from the group consisting of Li, Mg, Ca and Mn; x is from 45 to 95 mol %; and y is 1 or 2) and from 0.01 to 10 parts by weight of an oxide of at least one element selected from the group consisting of Groups IA, IIA, IIIA, IVA, VA, IIIB, IVB, and VB of the periodic table by granulating the composition and sintering the granules, and the magnetic particles have a silicon content of from 500 to 5,000 ppm. An image forming process using the developer is also disclosed.

Claims

1. An electrostatic-image developer which comprises a toner and a carrier comprising core particles coated with a coating resin,

wherein the toner comprises toner particles having a volume-average particle diameter of from 3 to 9 μ

m and having a particle diameter distribution satisfying the following expressions (1) and (2);

space="preserve" listing-type="equation">D16v/D50v≦

1.475-0.036·

D50v (1)

space="preserve" listing-type="equation">D50p/D84p≦

1.45 (2)

(wherein D16v and D50v represent, in terms of absolute value, a cumulative 16% diameter (μ

m) and a cumulative 50% diameter (μ

m), respectively, of a cumulative volume particle diameter distribution of the toner particles depicted from the maximum particle diameter and D50p and D84p represent, in terms of absolute value, a cumulative 50% diameter (μ

m) and a cumulative 84% diameter (μ

m), respectively, of a cumulative population particle diameter distribution of the toner particles depicted from the maximum particle diameter), and at least 20% of the total surface area of the toner particles is covered with (a) an external additive having an average particle diameter of from 20 nm to 100 nm, excluding 100 nm, and at least 40% of the total surface area of the toner particles is covered with (b) an external additive having an average particle diameter of from 7 nm to 20 nm, excluding 20 nm, the total percentage of the coverage with the two external additives is from 60% to 120%, excluding 120%, based on the total surface area of the toner particles, and

wherein the core particles of the carrier are magnetic particles formed from a composition comprising 100 parts by weight of a ferrite component represented by the following formula (3);

space="preserve" listing-type="equation">(M.sub.y O).sub.100-x (Fe.sub.2 O.sub.3).sub.x (

     3)

(wherein M represents at least one metal atom selected from the group consisting of Li, Mg, Ca and Mn;

x represents a mole percentage of 45 to 95%; and

y represents 1 or

     2) and from 0.01 to 10 parts by weight of an oxide of at least one element selected from the group consisting of Groups IA, IIA, IIIA, IVA, VA, IIIB, IVB, and VB of the periodic table by granulating the composition and sintering the granules, and the magnetic particles have a silicon content of from 500 to 5,000 ppm.

2. The electrostatic-image developer according to claim 1, wherein the oxide is a metal oxide selected from the group consisting of Li₂ O, BaO, SrO, Al₂ O₃, TiO₂, SiO₂, SnO₂ and Bi₂ O₅.

3. The electrostatic-image developer according to claim 1, wherein the oxide is a metal oxide selected from the group consisting of Li₂ O, SrO, Al₂ O₃, SiO₂ and Bi₂ O₅.

4. The electrostatic-image developer according to claim 1, wherein the magnetic particle has a silicon content of 1000 to 3000 ppm.

5. The electrostatic-image developer according to claim 1, wherein the carrier is coated with the coating resin in an amount of 0.1 to 5% by weight based on the weight of the carrier.

6. The electrostatic-image developer according to claim 1, wherein the carrier is coated with the coating resin in an amount of 0.3 to 3% by weight based on the weight of the carrier.

7. The electrostatic-image developer according to claim 1, wherein the coating resin is a homopolymer or a copolymer comprising a monomer selected from the group consisting of a fluorinated vinyl monomer, styrene, a derivative of styrene, an aliphatic α

-methylene monocarboxylic acid and an alkyl ester of an aliphatic α

-methylene monocarboxylic acid, or a silicone resin.

8. The electrostatic-image developer according to claim 1, wherein the developer comprises a color toner.

9. The electrostatic-image developer according to claim 1, wherein the toner comprises a binder resin comprising polyester.

10. An image forming method comprising:

forming a latent image on a latent-image holding member;

developing the latent image using a developer to form a toner image; and

transferring the toner image to a transferring member, wherein the developer is the developer as claimed in claim 1.

11. The image forming method according to claim 10, wherein the oxide is a metal oxide selected from the group consisting of Li₂ O, BaO, SrO, Al₂ O₃, TiO₂, SiO₂, SnO₂ and Bi₂ O₅.

12. The image forming method according to claim 10, wherein the oxide is a metal oxide selected from the group consisting of Li₂ O SrO, Al₂ O₃, SiO₂ and Bi₂ O₅.

13. The image forming method according to claim 10, wherein the magnetic particle has a silicon content of 1000 to 3000 ppm.

14. The image forming method according to claim 10, wherein the carrier is coated with the coating resin in an amount of 0.1 to 5% by weight based on the weight of the carrier.

15. The image forming method according to claim 10, wherein the carrier is coated with the coating resin in an amount of 0.3 to 3% by weight based on the weight of the carrier.

16. The image forming method according to claim 10, wherein the coating resin is a homopolymer or a copolymer comprising a monomer selected from the group consisting of a fluorinated vinyl monomer, styrene, a derivative of styrene, an aliphatic α

-methylene monocarboxylic acid and an alkyl ester of an aliphatic s-methylene monocarboxylic acid, or a silicone resin.

17. The image forming method according to claim 10, wherein the developer comprises a color toner.

18. The image forming method according to claim 10, wherein the toner comprises a binder resin comprising polyester.