Method for making transparent reflective films

• US 5,695,808 A
• Filed: 05/03/1996
• Issued: 12/09/1997
• Est. Priority Date: 04/16/1993
• Status: Expired due to Term

• Current Assignee: Crown Roll Leaf, Inc.
• Original Assignee: Crown Roll Leaf, Inc.
• Inventors: Cueli, Peter
• Primary Examiner(s): Beck, Shrive
• Assistant Examiner(s): PARKER, FREDERICK JOHN
• Application Number:
  US08/642,594
• Time in Patent Office: 585 Days
• Field of Search: 427/9, 427/10, 427/591, 427/161, 427/166, 427/255.5, 427/296, 427/248.1, 73/866
• US Class Current: 427/9
• CPC Class Codes: C23C 14/0629 of zinc, cadmium or mercury
• CPC Class Codes: C23C 14/26 by resistance or inductive heating of the source
• CPC Class Codes: C23C 14/562 for coating elongated substrates
• CPC Class Codes: G03H 1/0011 for security or authentication holograms on information-bearing cards B42D25/328; testing papers with holograms G07D7/0032
• CPC Class Codes: G03H 1/02 Details of features involved during the holographic process; Replication of holograms without interference recording
• CPC Class Codes: G03H 1/0244 Surface relief holograms replicating hologram without interference recording G03H1/0276
• CPC Class Codes: G03H 1/0256 having specific functional layer
• CPC Class Codes: G03H 1/028 by embossing
• CPC Class Codes: G03H 2001/0055 in advertising or decorative art
• CPC Class Codes: G03H 2250/10 arranged to be transferred onto a carrier body adhesive layer G03H2250/35
• CPC Class Codes: G03H 2250/36 Conform enhancement layer

Abstract

A method for making transparent, reflective films includes coating a polymer film with ZnS by charging a set of carbon crucibles with ZnS cubes or pellets. The crucibles are heated by induction in a vacuum deposition chamber having a supply roll of the polymer film and a take-up roll. The ZnS cubes sublimate at a rate matched to web advance to insure a coating thickness for colorless films of at least 1,000 angstroms. The thickness of the ZnS layer on the film is monitored by visual observation of color by a source of visible white light and the rate of transfer of the film is adjusted to control the thickness of the ZnS layer.

Claims

1. A method for coating polymer film with zinc sulfide, comprising the steps of:

(a) placing a crucible containing zinc sulfide solids in a vacuum deposition chamber having a supply roll of the polymer film and a take-up roll for the polymer film;

(b) evacuating the vacuum deposition chamber;

(c) heating the crucible containing said zinc sulfide solids by induction to sublimate the zinc sulfide into a zinc sulfide vapor;

(d) transferring the polymer film from the supply roll to the take-up roll at a rate of at least 60 ft./min. and passing the polymer film in proximity to the crucible, and depositing the zinc sulfide vapor onto the polymer film to form a layer of zinc sulfide on the polymer film, wherein the thickness of the layer of zinc sulfide formed is at least 1000 Angstroms;

(e) passing the polymer film containing the zinc sulfide layer past a source of visible white light at a location between the location of the crucible containing the zinc sulfide and the take-up roll;

(f) monitoring the zinc sulfide layer that is deposited on the polymer film by visually observing the presence or absence of color generated from the surface of the zinc sulfide layer as the polymer film passes the source of visible white light; and

(g) adjusting the rate of transfer of the polymer film from the supply roll to the take-up roll in response to said monitoring step to thereby control the thickness of the zinc sulfide layer on the polymer film.

2. The method of claim 1, wherein said vacuum deposition chamber is evacuated to a pressure of 10^-5 Torr during said step of evacuating and said crucible is heated to a temperature greater than or equal to 1000 degrees Centigrade.

3. The method of claim 1, wherein the weight of the zinc sulfide solids in the crucible placed into the vacuum deposition chamber is about 6 kilograms and said polymer film has a width of about 24 inches and a length of about 15,000 feet.

4. The method of claim 3, wherein the rate of transfer of said polymer film is greater than or equal to 500 ft./minute.

5. The method of claim 4, wherein said roll of polymer film is substantially entirely coated on one side with zinc sulfide using about 30 kilowatts of electrical power.

6. The method of claim 1, wherein said polymer film has a diffraction grating microtexture on at least one surface thereof.

7. The method of claim 1, wherein said polymer film has a hologram microtexture on at least one surface thereof.

8. The method of claim 2, wherein said polymer film passes to within about 12 inches of said crucible during said step of transfer.

9. The method of claim 1, wherein said step of adjusting includes increasing the rate of transfer of said film to decrease the thickness of said zinc sulfide layer.

10. The method of claim 1 wherein the thickness of the zinc sulfide layer is between 1000 and 2000 Angstroms.

11. The method of claim 1 wherein the step of adjusting is performed to regulate the rate of transfer of the film such that the observed zinc sulfide layer is substantially colorless.

12. The method of claim 1 wherein the step of adjusting is performed to regulate the rate of transfer of the film such that the observed zinc sulfide layer is green.

13. The method of claim 1 wherein the thickness of the zinc sulfide layer is in excess of 2000 Angstroms and exhibits color.

14. The method of claim 1 wherein the source of visible white light is a white fluorescent tube.

15. The method of claim 1 wherein the zinc sulfide solids are cube-shaped and have dimensions in the range of about 1/8 to 3/8 inches on a side.

16. The method of claim 1 wherein the transfer rate of the polymer film is from about 400 ft./min. to about 600 ft./min.

17. The method of claim 12 wherein the transfer rate of the polymer film is from about 400 ft./min. to about 600 ft./min.