Degumming of crude glyceride oils not exposed to prior enzymatic activity

• US 5,696,278 A
• Filed: 12/13/1995
• Issued: 12/09/1997
• Est. Priority Date: 03/17/1993
• Status: Expired due to Fees

• Current Assignee: Unilever Patent Holdings BV (Unilever PLC)
• Original Assignee: Unilever Patent Holdings BV (Unilever PLC)
• Inventors: Segers, Jacobus Cornelis
• Primary Examiner(s): Dees, Jose G.
• Assistant Examiner(s): Carr, Deborah D.
• Application Number:
  US08/532,846
• Time in Patent Office: 727 Days
• Field of Search: 554/176, 554/179
• US Class Current: 554/176
• CPC Class Codes: C11B 1/04 of vegetable raw material C11B1/025 takes precedence
• CPC Class Codes: C11B 1/08 by hot pressing
• CPC Class Codes: C11B 3/04 with acids

Abstract

The present invention relates to a process for the preparation of degummed glyceride oils, which comprises applying an acid degumming treatment to a crude glyceride oil which has not substantially been exposed to enzymatic activity. Preferably such crude glyceride oil has been obtained by heating and pressing glyceride oil containing vegetable material, optionally preceded by a cold pressing step, where the heating comprises an exposure of the vegetable material to a temperature of 30°-80° C. for 0.1-20 minutes, preferably for 0.1-15 minutes, more preferably 0.1-5 minutes, and then to a temperature of 80°-140° C., preferably 90°-110° C. for 1-60 minutes, preferably 15-20 minutes. Residual phosphorus levels of <7 ppm and even <2 ppm can be easily and consistently attained.

Claims

1. In a process for the preparation of degummed glyceride oil by subjecting crude glyceride oil to an acid degumming treatment, the improvement which comprises using crude glyceride oil which has not substantially been exposed to enzymatic activity, said crude glyceride oil being obtained by heating and pressing glyceride oil containing vegetable material, optionally preceded by a cold pressing step, where the heating comprises an exposure of the vegetable material to a temperature of 30°

-80°

C. for 0.1-20 minutes and then to a conditioning temperature of 90°

-140°

C. for 1-60 minutes.

2. Process according to claim 1 wherein the glyceride oil containing vegetable matter is initially at a temperature of 0-40°

C. and within 0.1-15 minutes is heated to a temperature of 90°

-130°

C., and maintained at that temperature for 1-60 minutes.

3. Process according to claim 1 wherein the moisture content of the oil containing vegetable material is 1-16 wt. %, with respect to the non-oil and non-moisture part of the vegetable material.

4. Process according to claim 1 wherein the oil after said conditioning is collected and is then dried within 1-60 minutes after separation from the vegetable material.

5. Process according to claim 4, wherein the collected oil is dried to a moisture content of 0.03-0.1. wt. %.

6. Process according to claim 1 wherein all or part of non-soluble vegetable material is removed from the collected oil, to a concentration of 0.01-0.25 wt. %.

7. Process according to claim 1 wherein the crude oil is subjected to the acid degumming treatment as a mixture of cold pressed oil and hot pressed oil, in a ratio of 5:

1 to 1;

5.

8. Process according to claim 1 wherein the acid degumming treatment comprises consecutively:

a. adding an aqueous solution of an edible acid or acid anhydride to the oil,

b. exposing the oil to the acid,

c. optionally, adding an aqueous alkali solution,

d. contacting the oil during 0.5-180 minutes with water or with the alkali solution,

e. removing the sludge separated from the oil.

9. Process according to claim 8, wherein the oil/water mixture of step d. is kept at a temperature of 10°

-40°

C.

10. Process according to claim 9 wherein alkali added, if any, is not greater than the amount of alkali necessary for neturalising the acid or acid anhydride previously added to the oil.

11. Process according to claim 10 wherein the sludge separated from the oil during the acid degumming treatment is effectively removed by not more than one centrifuge-separation.

12. Process according to claim 11 wherein a degummed oil is obtained with a phosphorus content of 0.1-7 ppm.

13. Process according to claim 12 wherein a degummed oil is obtained with a magnesium content of 0.01-0.07 ppm and an iron content of 0.001-0.04 ppm.

16. A process according to claim 1 wherein the heating is carried out for 0.1 to 5 minutes and the conditioning is carried out at 90°

-110°

C. for 15-20 minutes.

17. A process according to claim 4 wherein the collected oil is dried within 1-10 minutes.

18. A process according to claim 7 wherein the ratio of cold pressed oil and hot pressed oil is 3:

1 to 1;

1.

19. A process according to claim 12 wherein the phosphorous content of the degummed oil is 0.1-2 ppm.

14. Degummed glyceride oil which is not bleached and not alkali refined, characterised in that it contains 0.01-0.07 ppm magnesium.

15. Degummed glyceride oil which is not bleached and not alkali refined, characterised in that it contains 0.001-0.04 ppm iron.

20. Degummed glyceride oil according to claim 15 which contains 0.001-0.01 ppm iron.