Process and apparatus for the gas-phase polymerization of .alpha.-olefins

• US 5,698,642 A
• Filed: 07/19/1996
• Issued: 12/16/1997
• Est. Priority Date: 07/20/1995
• Status: Expired due to Term

• Current Assignee: Basell Poliolefine Italia Srl (Lyondellbasell Industries NV)
• Original Assignee: Montell Technology Company BV
• Inventors: Rinaldi, Roberto, Covezzi, Massimo, Govoni, Gabriele, Galli, Paolo
• Primary Examiner(s): WEBER, THOMAS
• Application Number:
  US08/684,411
• Time in Patent Office: 515 Days
• Field of Search: 526/65, 526/352, 526/901
• US Class Current: 526/65
• CPC Class Codes: B01J 19/2435 Loop-type reactors
• CPC Class Codes: B01J 8/1863 followed by a downward movement outside the reactor and subsequently re-entering it
• CPC Class Codes: B01J 8/388 externally, i.e. the particles leaving the vessel and subsequently re-entering it
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 110/06 Propene
• CPC Class Codes: C08F 2/001 Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer C08F295/00, C08F297/00 take precedence
• CPC Class Codes: C08F 2/34 Polymerisation in gaseous state
• CPC Class Codes: C08F 210/14 Monomers containing five or more carbon atoms
• CPC Class Codes: C08F 210/16 Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
• CPC Class Codes: C08F 2500/08 Low density, i.e. < 0.91 g/cm3
• CPC Class Codes: C08F 2500/12 Melt flow index or melt flow ratio
• CPC Class Codes: C08F 2500/18 Bulk density
• CPC Class Codes: Y10S 526/901 Monomer polymerized in vapor state in presence of transition metal containing catalyst

Abstract

Process for gas-phase polymerization carried out in two interconnected polymerization zones, to which one or more α-olefins CH₂ ═CHR are fed in the presence of catalyst under reaction conditions and from which the polymer product is discharged. The process is characterized in that the growing polymer flows through a first polymerization zone under fast fluidization conditions, leaves said first zone and enters a second polymerization zone through which it flows in a densified form under the action of gravity, leaves said second zone and is reintroduced into the first polymerization zone, thus establishing a circulation of polymer around the two polymerization zones. The novel process allows olefins to be polymerized in the gas phase with high productivity per unit volume of the reactor without incurring the problems of the fluidized-bed technologies of the known state of the art.

Claims

1. Process for the gas-phase polymerization of α

-olefins CH₂ ═

CHR, where R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, carried out in a first and in a second interconnected polymerization zones, to which one or more of said α

-olefins are fed in the presence of a catalyst under reaction conditions and from which the polymer product is discharged, wherein the growing polymer particles flow through the first of said polymerization zones under fast fluidization conditions, leave said first polymerization zone and enter the second of said polymerization zones through which they flow in a densified form under the action of gravity, leave said second polymerization zone and are reintroduced into said first polymerization zone, thus establishing a circulation of polymer between the two polymerization zones.

2. Process according to claim 1, wherein said fast fluidization conditions are established by feeding a gaseous mixture comprising one or more of said α

-olefins CH₂ ═

CHR to said first polymerization zone.

3. Process according to claim 2, wherein said gaseous mixture is fed to said first polymerization zone in a region below the point of reintroduction of the polymer into said first polymerization zone.

4. Process according to claim 3, wherein the feeding of said gaseous mixture is carried out by means of gas distributor means.

5. Process according to claim 2, wherein the polymer and the gaseous mixture leaving said first polymerization zone are conveyed to a solid/gas separation zone and the polymer leaving said solid/gas separation zone enters said second polymerization zone.

6. Process according to claim 1, wherein the control of the polymer circulating between the said two polymerization zones is effected by metering the quantity of polymer leaving said second polymerization zone.

7. Process according to claim 1, wherein the polymer produced is withdrawn continuously from said second polymerization zone.

8. Process according to claim 1, wherein the catalyst components are fed to said first polymerization zone.

9. Process according to claim 1, wherein any of the reaction zones is fed with a catalyst in a prepolymerized form.

10. Process according to claim 1, wherein any of the reaction zones is fed with a catalyst dispersed in a polymer slurry.

11. Process according to claim 1, wherein any of the reaction zones is fed with a catalyst dispersed in a dry polymer.

12. Process according to claim 5, wherein the gaseous mixture leaving said solid/gas separation is compressed, cooled and transferred, if appropriate with addition of make-up monomers, to said first polymerization zone.

13. Process according to claim 5, wherein part of the gaseous mixture leaving the solid/gas separation zone is used for transferring the polymer from said second zone to said first polymerization zone.

14. Process according to claim 5, wherein part of the gaseous mixture leaving said solid/gas separation zone is compressed and transferred to said second polymerization zone in the vicinity of the region where the polymer leaves said second zone.

15. Process according to claim 12, wherein the gaseous mixture leaving said solid/gas separation zone is cooled to temperatures below the dew point.

16. Process according to claim 1, wherein said first polymerization zone is cooled by external cooling means.

17. Process according to claim 1, wherein the make-up monomer or monomers are fed in an at least partially condensed form to said first polymerization zone.

18. Process according to claim 2, wherein the velocity of the fluidizing gas into said first polymerization zone is between 2 and 15 m/s, preferably between 3 and 8 m/s.

19. Process according to claim 1, wherein the polymer is in the form of spheroidal particles having mean dimensions of between 0.2 and 5 mm, preferably between 0.5 and 3 mm.

20. Process according to claim 1, wherein the working pressure is between 0.5 and 10 MPa, preferably between 1.5 and 6 MPa.

21. Process according to claim 1, wherein one or more inert gases are present in said polymerization zones at partial pressures of between 5 and 80% of the total pressure of the gases.

22. Process according to claim 21, wherein the inert gas is nitrogen or an aliphatic hydrocarbon having 2-6 carbon atoms, preferably propane.

23. Process according to claim 1, wherein an intermediate polymerization zone, operating with a fluid bed, is interposed between said first and said second polymerization zones.