Treatment of polyvinylchloride

• US 5,698,759 A
• Filed: 01/13/1995
• Issued: 12/16/1997
• Est. Priority Date: 07/15/1992
• Status: Expired due to Fees

• Current Assignee: Derek Fray
• Original Assignee: Derek Fray
• Inventors: Fray, Derek
• Primary Examiner(s): Straub, Gary P.
• Application Number:
  US08/367,308
• Time in Patent Office: 1,068 Days
• Field of Search: 588/205, 588/206, 588/207, 588/208, 588/209, 588/213, 588/234, 588/235, 588/255, 585/241, 75/353, 75/401, 423/44, 423/59, 423/60, 423/75, 423/76, 423/79, 423/87, 423/96, 423/97, 423/107, 423/108, 423/133, 423/136, 423/150.3
• US Class Current: 588/316
• CPC Class Codes: A62D 2101/08 Toxic combustion residues, e.g. toxic substances contained in fly ash from waste incineration
• CPC Class Codes: A62D 2101/22 containing halogen
• CPC Class Codes: A62D 2101/43 containing heavy metals, in the bonded or free state
• CPC Class Codes: A62D 3/38 by oxidation; by combustion
• CPC Class Codes: C21B 3/04 Recovery of by-products, e.g. slag
• CPC Class Codes: C21C 2005/4666 for charging with organic contaminated scrap
• CPC Class Codes: C21C 2005/5282 with organic contaminated scrap
• CPC Class Codes: C22B 19/30 from metallic residues or scraps
• CPC Class Codes: C22B 7/02 Working-up flue dust
• CPC Class Codes: Y02P 10/20 Recycling
• CPC Class Codes: Y02W 30/50 Reuse, recycling or recovery technologies

Abstract

A method is described which allows two hazardous waste products, namely PVC and electric arc furnace dust, both of which have negative commercial value, to be combined to produce an iron oxide suitable for steel making and making pure cadmium lead and zinc and chlorine, all of which can be sold. The heat generated during the exothermic reaction may be used to generate electricity which may be sold or used in plants where the reaction is carded out. The method can also be used for metal scraps.

Claims

1. A method of treating PVC, chlorinated rubbers or chlorinated polymers comprising the steps of:

combining PVC, chlorinated rubber, or chlorinated polymer at an elevated temperature with a mixture of metals and/or metal compounds containing at least one ferrous metal value and at least one non-ferrous metal value, wherein the non-ferrous metal value is selected from zinc, lead, cadmium, copper, and tin;

reacting the PVC, chlorinated rubber, or chlorinated polymer with an excess of air or oxygen with the mixture to convert the non-ferrous metal values to volatile chlorides, to partially convert the ferrous metals to ferrous metal oxides, and to remain unchanged any ferrous metal oxides.

2. A method according to claim 1 wherein the PVC, chlorinated rubber, or chlorinated polymer is combined with electric arc furnace dust from steel making.

3. A method according to claim 1 or claim 2 further comprising the step of adding silicon oxide or boron oxide to the PVC, chlorinated rubber, or chlorinated polymers and the mixture of metals or metal compounds, which silicon oxide or boron oxide reacts with any group IIA oxide which may exist in the mixture to form a stable group IIA silicate or borate compound which will not chlorinate during the reaction.

4. A method according to claim 1 wherein the ferrous metal is iron.

5. A method of treating PVC, chlorinated rubbers or chlorinated polymers comprising the steps of:

burning PVC, chlorinated rubber, or chlorinated polymer in excess of air or oxygen to produce chlorinated combustion gases;

contacting a mixture of metals and/or metal compounds containing at least one ferrous metal value and at least one non-ferrous metal value with the chlorinated combustion gases in oxygen or excess air, wherein the non-ferrous metal value is selected from zinc, lead, cadmium, copper, and tin, and wherein the non-ferrous metal values are converted to volatile chlorides, the ferrous metals are partially converted to ferrous metal oxides, and the ferrous metal oxides remain unchanged.

6. A method of treating a feed containing one or more iron metal values contaminated with one or more non-ferrous metal values selected from zinc, lead, cadmium, copper, and tin, comprising the steps of:

combining said feed with PVC, chlorinated rubber or a chlorinated polymer, and air or oxygen in the presence of boron oxide or silicon oxide at an elevated temperature, wherein the PVC, chlorinated rubber or chlorinated polymer burns in the air or oxygen to produce hydrochloric acid; and

reacting the non-ferrous metal values with the hydrochloric acid to form volatile chlorides and partially converting the ferrous metals into ferrous oxides.