Light-emitting thin film and thin film EL device

• US 5,700,591 A
• Filed: 03/23/1994
• Issued: 12/23/1997
• Est. Priority Date: 03/14/1990
• Status: Expired due to Fees

• Current Assignee: Matsushita Electric Industrial Company Limited (Panasonic Holdings Corporation)
• Original Assignee: Matsushita Electric Industrial Company Limited (Panasonic Holdings Corporation)
• Inventors: Okajima, Michio, Tohda, Takao
• Primary Examiner(s): NOLD, CHARLES R
• Application Number:
  US08/216,853
• Time in Patent Office: 1,371 Days
• Field of Search: 422/690, 422/917, 422/691, 313/503, 313/509, 313/506
• US Class Current: 428/690
• CPC Class Codes: H05B 33/145 Arrangements of the electroluminescent material
• CPC Class Codes: Y10S 428/917 Electroluminescent

Abstract

A phosphor thin film of a compound of zinc, cadmium, manganese or alkaline earth metals and an element of group VI is sandwiched by barrier layers having a larger energy gap than that of the phosphor thin film, and a plurality of the sandwich structures are accumulated thicknesswise to constitute a light-emitting device. The phosphor thin film ensures the confinement of injected electrons and holes within the phosphor thin film. The light-emitting device has a high brightness and a high efficiency.

Claims

1. A light emission film having a multi-layer structure, comprising:

at least one phosphor film sandwich, each at least one phosphor film sandwich including a phosphor film and first and second barrier layers, said first and second barrier layers being separated by and in contact with said phosphor film,

wherein the thickness of said phosphor film is less than 50 nm and larger than 1 nm, and the energy gap of said barrier layers is larger than that of said phosphor film to thereby confine carriers within said phosphor film.

2. The light emission film in accordance with claim 1, wherein said multi-layer structure further comprises at least one additional phosphor film sandwich.

3. The light emission film in accordance with claim 1 or 2, wherein said barrier layers contain at least one chemical compound selected from the group consisting of chemical compounds of zinc, cadmium, manganese and alkaline earth metals together with elements from group VI.

4. The light emission film in accordance with claim 1 or 2, wherein said barrier layers contain at least one chemical compound selected from the group consisting of fluorides of alkaline earth metals.

5. The light emission film in accordance with claim 1 or 2, wherein both said phosphor film and said barrier layers have the same crystal structure.

6. The light emission film in accordance with claim 1 or 2, wherein at least one of said phosphor film and said barrier layers contains the chemical compound of magnesium sulfide and at least one chemical compound selected from the group consisting of the chemical compounds of other sulfides of alkaline earth metals.

7. The light emission film in accordance with claim 3, wherein said chemical compounds of manganese and elements of group VI contain at least one chemical compound selected from the group consisting of manganese telluride (MnTe), manganese selenide (MnSe), and manganese sulfide (MnS).

8. The light emission film in accordance with claim 3, wherein said chemical compounds selected from the group of chemical compounds of manganese and one of the elements of group VI have a zinc-blend crystal structure.

9. The light emission film in accordance with claim 1 or 2, wherein said phosphor film and barrier layer are epitaxial films.

10. The light emission film in accordance with claim 1 or 2, Wherein said light emission film is for use in a thin film electroluminescent device adapted to apply a voltage to said light emission film.

11. The light emission film in accordance with claim 10, wherein a dielectric film is formed at least on one surface of said light emission film, and in contact with the first barrier layer of said at least one phosphor film sandwich of said multi layer structure, to receive the voltage applied to said light emission film by the thin film electroluminescent device.

12. The light emission film in accordance with claim 1 or 2, wherein a plurality of phosphor film sandwiches are stacked such that adjacent interfaces of adjacent sandwiches share a common barrier layer interposed therebetween.

13. A light emission film having a multi-layer structure, comprising:

at least one phosphor film sandwich, each at least one phosphor film sandwich including a phosphor film and first and second barrier layers, said first and second barrier layers being separated by and in contact with said phosphor film,

wherein the thickness of said phosphor film is less than 50 nm and larger than 1 nm, and the energy gap of said barrier layers is larger than that of said phosphor film to thereby confine carriers within said phosphor film, and said phosphor film contains at least one chemical compound selected from the group consisting of chemical compounds of zinc, cadmium, manganese and alkaline earth metals together with elements from group VI.

14. The light emission film according to claim 13, wherein said barrier layers have a band gap energy exceeding 3.5 eV.

15. The light emission film according to claim 13, wherein said barrier layers have a band gap energy of 3.8 to 5.4 eV.