Preparing consolidated thermite compositions

• US 5,700,974 A
• Filed: 02/25/1997
• Issued: 12/23/1997
• Est. Priority Date: 09/25/1995
• Status: Expired due to Fees

• Current Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Original Assignee: Morton International Incorporated (Autoliv Incorporated)
• Inventors: Taylor, Robert D.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US08/806,083
• Time in Patent Office: 301 Days
• Field of Search: 149/37, 149/109.6, 149/17
• US Class Current: 149/109.6
• CPC Class Codes: C06B 33/12 the material being two or more oxygen-yielding compounds
• CPC Class Codes: C06D 5/00 Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets explosive compositions containing an oxidizer, fuels for rocket engines intended for reaction with an oxidant other than air C06B

Abstract

An improved heat generating thermite composition suitable for use in an inflator of a motor vehicle airbag restraint system comprises a hard consolidated pellet, grain or wafer shaped formulation of a powdered metal fuel, a powdered metal oxide oxidizer, a binder and a supplemental oxidizing agent.

Claims

1. A process for producing a hard consolidated form of heat generating thermite composition suitable for use in an inflator for an airbag restraint system of a motor vehicle, said process comprising:

1) mixing in a slurry medium until in intimate admixture;

a) about 20 to about 30 weight percent of a powdered metal fuel,

b) about 40 to about 70 weight percent of a powdered metal oxide oxidizer,

c) about 5 to about 25% weight percent of an essentially non gas-producing, non hot particulate-producing binder, and

d) about 2 to about 10 weight percent of a supplemental oxidizing agent,

2) extruding the resulting slurry mixture into a consolidated form,

3) cutting the consolidated extruded slurry mixture into appropriately sized and shaped pellets, grains or wafer forms,

4) drying the pellet, grain or wafer forms to remove the slurry medium therefrom, to form the consolidated extruded slurry mixture forms into hard consolidated shapes.

2. The process of claim 1 wherein the slurry medium is water, the consolidated extruded slurry mixture is cut into pellets, the powdered metal fuel is aluminum powder of about 5 to about 30 microns particle size, the metal oxide oxidizer is ferric powder of about 0.1 to 3 microns particle size, the binder is hydrated calcium sulfate and the supplemental oxidizing agent is potassium perchlorate.

3. The process of claim 1 wherein the powdered metal fuel has a particle size of about 5 to 30 microns and the powdered metal oxide oxidizer has a particle size of about 0.1 to 3 microns.

4. The process of claim 1 wherein the binder is hydrated calcium sulfate and the supplemental oxidizing agent is selected from the group consisting of potassium perchlorate, potassium chlorate and ammonium perchlorate.

5. The process of claim 1 wherein the binder is hydrated calcium sulfate and the supplemental oxidizing agent is selected from the group consisting of potassium perchlorate, potassium chlorate and ammonium perchlorate.

6. The process of claim 1 wherein the powdered metal fuel is aluminum metal powder and the metal oxide oxidizer is ferric oxide powder.

7. The process of claim 3 wherein the powdered metal fuel is aluminum metal powder and the metal oxide oxidizer is ferric oxide powder.

8. The process of claim 4 wherein the powdered metal fuel is aluminum metal powder and the metal oxide oxidizer is ferric oxide powder.

9. The process of claim 5 wherein the powdered metal fuel is aluminum metal powder and the metal oxide oxidizer is ferric oxide powder.

10. The process of claim 1 wherein:

a) the powdered metal fuel has a particle size of from about 5 to 30 microns and is selected from the group consisting of aluminum, titanium, titanium hydride, vanadium and boron powder,

b) the powdered metal oxide oxidizer has a particle size of from about 0.1 to 3 microns and is selected from the group consisting of ferric oxide, titanium oxide, cupric oxide, cobaltic oxide, cobaltous ferrite and manganese oxide,

c) the binder is hydrated calcium sulfate in an amount of about 5 to 10% weight percent, and

d) the supplemental oxidizing agent is selected from potassium perchlorate, potassium chlorate and ammonium perchlorate and is present in an amount of from about 5 to about 10 weight percent.