Portable hydrogen generator

• US 5,702,491 A
• Filed: 09/20/1996
• Issued: 12/30/1997
• Est. Priority Date: 06/07/1995
• Status: Expired due to Fees

• Current Assignee: Ball Aerospace & Technologies Corporation (Ball Corporation)
• Original Assignee: Ball Corporation
• Inventors: Lynch, Frank, Schmidt, Jeff, Long, Eugene
• Primary Examiner(s): MCMAHON, TIMOTHY M
• Application Number:
  US08/716,965
• Time in Patent Office: 466 Days
• Field of Search: 422/111, 422/129, 423/657, 48/61, 48/197 R
• US Class Current: 48/197.00R
• CPC Class Codes: B01J 7/02 by wet methods
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A hydrogen generator employs substantially adiabatic hydrolysis and thermal decomposition of chemical hydrides to provide a controllable generation of hydrogen from a small, lightweight container. The hydrogen generator includes a thermally isolated container for containing a chemical hydride, a preheater to heat the chemical hydride to a predetermined temperature before the chemical hydride is hydrolyzed, a water supply controlled to maintain substantially adiabatic and controlled generation of hydrogen from said chemical hydride, and a buffer to supply an initial flow of hydrogen during generator start-up, absorb excess hydrogen during generator shut-down, and to smooth the hydrogen flow due to changing loads.

Claims

1. A method for generating hydrogen, comprising the steps of:

placing a first chemical hydride in a thermally isolated container;

heating said first chemical hydride to a predetermined temperature;

hydrolyzing said first chemical hydride only after said first chemical hydride reaches said predetermined temperature;

recovering hydrogen from said container; and

controlling an amount of hydrogen generated by said hydrogen generator.

2. The method of claim 1, wherein said thermally isolated container comprises a dewar having an outer shell and an inner vessel defining a vacuum space therebetween, and having thermal insulation positioned in said vacuum space.

3. The hydrogen generator of claim 1, wherein said first chemical hydride comprises a metal hydride.

4. The hydrogen method of claim 1, further comprising the step of providing a buffer chamber containing a rechargeable hydride for supplying hydrogen to an outlet conduit when said first chemical hydride is being heated, for absorbing excess hydrogen after hydrolysis of said first chemical hydride is stopped and for smoothing the hydrogen flow due to changing load demands.

5. A method of generating hydrogen, comprising the steps of:

providing a thermally isolated container;

providing a water source having a water conduit for supplying water into said container;

placing a first chemical hydride placed in said container;

positioning a chemical composition in said container between said first chemical hydride and an outlet of said water conduit, said chemical composition including components to react exothermically with water supplied into said container to heat said first chemical;

operating said water source to supply water to said container, prior to hydrolysis of said first chemical hydride, to generate within said container a temperature sufficient to prevent said first chemical hydride from forming undesirable products when said first chemical hydride is hydrolyzed and thereafter at a rate to maintain an adiabatic generation of hydrogen by said first chemical hydride; and

recovering hydrogen from said container.

6. A method for generating hydrogen, comprising the steps of:

providing a container forming a dewar having an outer shell and an inner vessel defining a vacuum space therebetween, and having thermal insulating material positioned in said vacuum space;

placing a first chemical hydride in said inner vessel;

heating said first chemical hydride to a predetermined temperature sufficient to prevent said first chemical hydride from undergoing unstable reactions when hydrolyzed;

hydrolyzing said first chemical hydride only after a temperature of said first chemical hydride reaches said predetermined temperature, said water supply including a water pump for supplying water into said inner vessel via a water conduit;

providing a hydrogen conduit coupled to said inner vessel for supplying a flow of hydrogen from said inner vessel;

controlling said water pump and the generation of hydrogen; and

providing a buffer containing a rechargeable hydride for generating hydrogen prior to the temperature of said first chemical hydride reaching said predetermined temperature, for absorbing excess hydrogen after said water pump is stopped from supplying water to said container, and for smoothing the hydrogen flow due to changing loads.