Multilayer material, anti-erosion and anti-abrasion coating incorporating said multilayer material

• US 5,702,829 A
• Filed: 04/26/1996
• Issued: 12/30/1997
• Est. Priority Date: 10/14/1991
• Status: Expired due to Term

• Current Assignee: Commissariat a L'Energie Atomique (AES Corporation), Etat Francais Represente Par Le Delegue General Pour L'Armement, Turbomeca
• Original Assignee: Commissariat a L'Energie Atomique (AES Corporation), Etat Francais Represente Par Le Delegue General Pour L'Armement, Turbomeca
• Inventors: Farges, Guy, Monge-Cadet, Pierre, Ernoult, Jacques, Pauleau, Yves, Paidassi, Serge, Brun, Michel
• Primary Examiner(s): Zimmerman, John J.
• Application Number:
  US08/634,899
• Time in Patent Office: 613 Days
• Field of Search: 428/610, 428/665, 428/635, 428/627, 428/681, 428/651, 428/680
• US Class Current: 428/610
• CPC Class Codes: C23C 14/0021 Reactive sputtering or evaporation
• CPC Class Codes: C23C 14/0073 by exposing the substrates to reactive gases intermittently
• CPC Class Codes: C23C 14/06 characterised by the coating material C23C14/0021 , C23C14/04 take precedence
• CPC Class Codes: C23C 14/16 on metallic substrates or on substrates of boron or silicon
• CPC Class Codes: C23C 28/02 only coatings only including layers of metallic material
• CPC Class Codes: Y10T 428/12458 having composition, density, or hardness gradient
• CPC Class Codes: Y10T 428/12576 Boride, carbide or nitride component
• CPC Class Codes: Y10T 428/12632 Four or more distinct components with alternate recurrence of each type component
• CPC Class Codes: Y10T 428/1284 W-base component

Abstract

The present invention relates to a multilayer material useful as an anti-erosion and anti-abrasion coating, and to a process for producing the multilayer material at low temperatures. The multilayer material comprises a substrate covered with at least one metallic tungsten ductile layer and at least one hard layer of a solid solution of an additional element chosen from carbon or nitrogen or a mixture of carbon and nitrogen in tungsten or a tungsten alloy, the two types of layers ar alternating. The multilayer material is particularly useful as a coating for parts used in aeronautics.

Claims

1. A multilayer material, characterized in that it comprises a substrate covered with at least one ductile, metallic tungsten or tungsten alloy layer and at least one hard layer of a solid solution of nitrogen, in tungsten or in a tungsten alloy, the two types of layers alternating.

2. Multilayer material according to claim 1, characterized in that the nitrogen content in the solid solution is between 0.5 and 15 atomic %.

3. Multilayer material according to claim 1, characterized in that the nitrogen content in the solid solution is between 1 and 10 atomic %.

4. Multilayer material according to claim 1, characterized in that it comprises at least two successive hard layers of solid solution having constant nitrogen contents within each hard layer, and two successive hard layers having different nitrogen contents.

5. Multilayer material according to claim 1, characterized in that it comprises at least two successive hard layers of solid solution having constant nitrogen contents within each hard layer and increasing nitrogen contents within the assembly of successive hard layers.

6. Multilayer material according to claim 1, characterized in that it comprises at least two successive hard layers of solid solution having constant nitrogen contents within each hard layer and increasing nitrogen contents within the assembly of successive hard layers, and in that the hard layer closest to the substrate has the lowest nitrogen content of all the successive hard layers.

7. Multilayer material according to claim 1, characterized in that at least one of the hard layers internally has an increasing gradient of nitrogen in the solid solution, the part of the said hard layer having the lowest nitrogen content being directed towards the substrate.

8. Multilayer material according to claim 1, characterized in that the tungsten alloy used is an alloy constituted by tungsten and one or more other elements selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, nickel, copper, aluminum, cobalt, iron, platinum and palladium.

9. Multilayer material according to claim 1, characterized in that the substrate is chosen from among a titanium alloy, stainless steel, an aluminum alloy, a nickel alloy, polymers or composite materials.

10. A mechanical part subject to the impact of abrasive particles including an anti-erosion and anti-abrasion coating, characterized in that it comprises a multilayer material according to any one of the claims 1-9.