Fuel cell device equipped with catalyst material for removing carbon monoxide and method for removing carbon monoxide

• US 5,702,838 A
• Filed: 08/07/1996
• Issued: 12/30/1997
• Est. Priority Date: 08/18/1995
• Status: Expired due to Term

• Current Assignee: Matsushita Electric Industrial Company Limited (Panasonic Holdings Corporation)
• Original Assignee: Matsushita Electric Industrial Company Limited (Panasonic Holdings Corporation)
• Inventors: Yasumoto, Eiichi, Hatoh, Kazuhito, Gamou, Takaharu
• Primary Examiner(s): NUZZOLILLO, MARIA
• Application Number:
  US08/692,963
• Time in Patent Office: 510 Days
• Field of Search: 429/13, 429/17, 429/40, 429/41, 423/224, 423/237, 423/239.2, 502/78, 502/79, 502/344, 502/74
• US Class Current: 429/412
• CPC Class Codes: B01J 29/7407 A-type
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 8/0662 Treatment of gaseous reactants or gaseous residues, e.g. cleaning
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

There are disclosed a catalyst material for removing carbon monoxide and a polymer electrolyte fuel cell device using the same catalyst material. This catalyst material comprises an A type zeolite carrying at least one metal selected from the group consisting of Pt, Pd, Ru, Au, Rh and Ir, or an alloy of two or more metals. The catalyst material is capable of removing carbon monoxide in a reformed gas which is fed to the fuel cell by oxidation at a low temperature with good selectivity.

Claims

1. A fuel cell device comprising a polymer electrolyte fuel cell, a reformer, a fuel gas feeding path for feeding a reformed gas to a fuel electrode of said fuel cell from said reformer, a feeding path for feeding an oxidant gas to a cathode of said fuel cell and a device for removing carbon monoxide provided in said fuel gas feeding path, wherein said device for removing carbon monoxide is equipped with a catalyst material comprising an A type zeolite carrying at least one metal selected from the group consisting of Pt, Pd, Ru, Au, Rh and Ir, or an alloy of two or more metals.

2. A fuel cell device according to claim 1, wherein cationic species constituting said A type zeolite comprise at least one metal selected from the group consisting of K, Na, Ca and Mg.

3. A process for removing carbon monoxide in a reformed gas which is reformed from a hydrocarbon material and then fed to a fuel electrode of a fuel cell, comprising passing the reformed gas through a catalyst material for removing carbon monoxide at a temperature of said catalyst of 50°

to 200°

C., said catalyst comprising an A type zeolite carrying at least one metal selected from the group consisting of Pt, Pd, Ru, Au, Rh and Ir, or an alloy of two or more metals.

4. A process according to claim 3, wherein cationic species constituting said A type zeolite comprise at least one metal selected from the group consisting of K, Na, Ca and Mg.

5. The process for removing carbon monoxide in the reformed gas fed to the fuel cell in accordance with claim 3, wherein an amount of oxygen introduced into said catalyst material, together with the reformed gas, is 0.5 to 2 times greater than that of carbon monoxide in said reformed gas.

6. The process for removing carbon monoxide in the reformed gas fed to the fuel cell in accordance with claim 4, wherein an amount of oxygen introduced into said catalyst material, together with the reformed gas, is 0.5 to 2 times greater than that of carbon monoxide in said reformed gas.