Pesticidal compositions of polyoxyalkylene alkylamine surfactants having reduced eye irritation

• US 5,703,015 A
• Filed: 12/19/1994
• Issued: 12/30/1997
• Est. Priority Date: 08/09/1990
• Status: Expired due to Term

• Current Assignee: Monsanto Technology LLC (Bayer AG)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Berger, Paul D., Jimenez, Antonio M.
• Primary Examiner(s): CLARDY, S
• Application Number:
  US08/358,274
• Time in Patent Office: 1,107 Days
• Field of Search: 504/206
• US Class Current: 504/206
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 25/32 Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
• CPC Class Codes: A01N 57/20 containing acyclic or cycloaliphatic radicals
• CPC Class Codes: C09K 23/017 Mixtures of compounds
• CPC Class Codes: C09K 23/16 Amines or polyamines
• CPC Class Codes: Y10S 516/05 Organic amine, amide, or n-base containing
• CPC Class Codes: Y10S 516/07 Organic amine, amide, or n-base containing
• CPC Class Codes: Y10S 516/916 The compound contains repeating -OCnH2n-, i.e. repeating unsubstituted oxyalkylene

Abstract

There are provided compositions of certain polyoxyalkylene alkylamine surfactants having eye irritation reduced by the addition of an effective amount of a sulfated polyoxyalkylene alkylphenol, alcohol sulfate, polyoxyalkylene alcohol sulfate, mono- or dialcohol phosphate mono- or di- (polyoxyalkylene alcohol) phosphate, mono-or di- (polyoxyalkylene alkylphenol) phosphate, polyoxyalkylene alkylphenol carboxylate or polyoxyalkylene alcohol carboxylate surfactant. Also provided are pesticidal, particularly herbicidal, compositions comprising polyoxyalkylene alkylamine surfactants having eye irritation reduced by addition of these eye irritation reducing compounds.

Claims

1. A composition which is an aqueous solution comprising:

(a) a glyphosate herbicide in a herbicidally effective amount,

(b) an amine surfactant component having the chemical structure ##STR8## wherein x is a number from about 7 to about 19;

n₁ and n₂ are numbers independently selected from 1 to about 30;

the average sum of n₁ and n₂ is 2 or greater;

R₁ and R₂ are C2-C4 alkylene radicals, said amine surfactant being in an amount sufficient to potentiate the glyphosate herbicidal activity but at the same time sufficient to cause unacceptable eye irritation; and

(c) an effective eye irritation reducing amount of a phosphate monoester or mixture of phosphate monoesters having the general formula ##STR9## wherein R¹ is C₈ -C₂₀ alkyl or C₈ -C₂₀ alkylphenyl;

R is C₂ -C₄ alkylene;

m is zero or a number up to about 60;

alone or in combination with a phosphate diester or mixture of phosphate diesters having the general formula;

##STR10## wherein R, R₁, and m are as just described, provided the weight percentage of phosphate monoester (on monoesters) exceeds that of the phosphate diester (or diesters).

2. The composition of claim 1 wherein R¹ is nonylphenyl and m is about 4.

3. The composition of claim 1 wherein R¹ is C₈ -C₁₀ straight chain alkyl and m is 0.

4. The composition of claim 1, 2, or 3 wherein in the anime surfactant component R₁ and R₂ are each ethylene and the average sum of m, and n₂ is from about 4 to about 20.

5. The composition of claim 4 wherein the amine surfactant component comprises ethoxylated tallow anime having 8-13 moles of ethylene oxide.

6. The composition of claim 1 wherein (b) and (c) are present in a weight/weight ratio of about 80:

20 to about 85;

15.

7. The composition of claim 1 wherein the weight/weight ratio of glyphosate herbicide, expressed as acid equivalent, to the total of components (b) and (c) is in the range of 1:

1 to 5;

1.

8. In an aqueous herbicidal solution of a glyphosate herbicide potentiated with a polyoxyalkylene alkylamine surfactant having the chemical structure ##STR11## wherein x is a number from about 7 to about 19;

n₁ and n₂ are numbers independently selected from 1 to about 30;

the average sum of n₁ and n₂ is 2 or greater; and

R₁ and R₂ are C₂ -C₄ alkylene radicals, the improvement characterized by having incorporated in the solution an amount effective to appreciably reduce the eye irritation of the solution of a phosphate monoester or diester surfactant or a mixture thereof having the general formula ##STR12## wherein R¹ is C₈ -C₂₀ alkyl or C₈ -C₂₀ alkylphenyl;

R is C₂ -C₄ alkylene radical, ethylene or propylene;

m is zero or a number up to about 60; and

R² is hydroxyl or the R¹ --O--(RO)_m radical wherein R, R¹ and m are as just described, wherein the weight percentage of phosphate monoester surfactant equals or exceeds that of phosphate diester surfactant.

9. A method of controlling vegetation comprising spraying on the foliage of the vegetation a herbicidally effective amount of the composition of claim 8.