Golf ball compositions based on blends of olefinic ionomers and metallocene catalyzed polymers

• US 5,703,166 A
• Filed: 06/07/1995
• Issued: 12/30/1997
• Est. Priority Date: 01/24/1995
• Status: Expired due to Term

• Current Assignee: Acushnet Company (FILA Holdings Corp.)
• Original Assignee: Acushnet Company (FILA Holdings Corp.)
• Inventors: Rajagopalan, Murali, Harris, Kevin
• Primary Examiner(s): WEBER, THOMAS
• Application Number:
  US08/482,514
• Time in Patent Office: 937 Days
• Field of Search: 525/196, 525/221, 473/351, 473/372, 473/373, 473/385, 273/235, 273/DIG. 22
• US Class Current: 525/196
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0024 Materials other than ionomers or polyurethane
• CPC Class Codes: A63B 37/0031 Hardness
• CPC Class Codes: A63B 37/0033 Thickness
• CPC Class Codes: A63B 37/0035 Density; Specific gravity
• CPC Class Codes: A63B 37/0037 Flexural modulus; Bending stiffness
• CPC Class Codes: A63B 37/0043 Hardness
• CPC Class Codes: A63B 37/0045 Thickness
• CPC Class Codes: A63B 37/0049 Flexural modulus; Bending stiffness
• CPC Class Codes: A63B 37/0052 Liquid cores
• CPC Class Codes: A63B 37/0064 Diameter
• CPC Class Codes: A63B 37/0066 Density; Specific gravity
• CPC Class Codes: A63B 37/0074 Two piece balls, i.e. cover and core
• CPC Class Codes: A63B 37/0075 Three piece balls, i.e. cover, intermediate layer and core
• CPC Class Codes: A63B 37/04 Rigid cores
• CPC Class Codes: A63B 37/12 Special coverings , i.e. outer layer material balls with finger holes A63B37/0001, golf ball covers A63B37/0023
• CPC Class Codes: C08L 23/08 Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 23/0815 Copolymers of ethene with aliphatic 1-olefins
• CPC Class Codes: C08L 23/0876 Neutralised polymers, i.e. ionomers
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 2314/06 : Metallocene or single site catalysts
• CPC Class Codes: C08L 2666/04 : Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: H04B 1/005 : adapting radio receivers, transmitters andtransceivers for operation on two or more bands, i.e. frequency ranges
• CPC Class Codes: H04B 1/006 : using switches for selecting the desired band H04B1/0057 takes precedence
• CPC Class Codes: Y10S 273/22 : Ionomer

Abstract

The disclosed invention provides novel golf ball compositions which contain olefinic based ionomers and non-ionic olefinic copolymers produced by use of metallocene catalysts. These compositions exhibit improved mechanical properties such as tensile and flexural properties. Golf balls which employ these blends provide ball properties and performance similar to and in some cases better than the state of the art ionomer based golf balls.

Claims

1. A golf ball comprising a cover and a core wherein the cover comprises an at least partially miscible blend of at least one ionomer and at least one metallocene catalyzed polymer having the formula:

##STR3## wherein R₁ is hydrogen;

R₂ is hydrogen or lower alkyl selected from the group consisting of CH₃, C₂ H₅, C₃ H₇, C₄ H₉, and C₅ H₁₁ ;

R₃ is hydrogen or lower alkyl selected from the group consisting of CH₃, C₂ H₅, C₃ H₇, C₄ H₉, and C₅ H₁₁ ;

R₄ is selected from the group consisting of CH₃, C₂ H₅, C₃ H₇, C₄ H₉, C₅ H₁₁, C₆ H₁₃, C₇ H₁₅, C₉ H₁₉, C₁₀ H₂₁, and phenyl, in which from 0 to 5 H within R₄ can be replaced by substituents selected from the group consisting of COOH, SO₃ H, NH₂, F, Cl, Br, I, OH, SH, silicone, lower alkyl esters and lower alkyl ethers, with the proviso that R₃ and R₄ can be combined to form a bicyclic ring;

R₅ is hydrogen, lower alkyl including C₁ -C₅, carbocyclic, aromatic or heterocyclic;

R₆ is hydrogen, lower alkyl including C₁ -C₅, carbocyclic, aromatic or heterocyclic; and

wherein x ranges from 99 to 50 weight per cent of the polymer, y ranges from 1 to 50 weight per cent of the polymer and z ranges from 0 to 49 weight per cent of the polymer.

2. A golf ball comprising a core and a cover according to claim 1 wherein R₂ is hydrogen.

3. A golf ball composing a cover and a core according to claim 1 wherein the golf ball core has a diameter of about 1.58 inches.

4. A golf ball comprising a cover and a core according to claim 1 wherein the golf ball has a diameter of from about 1.68 to about 1.80 inches.

5. A golf ball comprising a cover and a core according to claim 1 wherein the golf ball has a diameter of from about 1.710 to about 1.730 inches.

6. A golf ball comprising a cover and a core according to claim 1 wherein the core is a single piece of material.

7. A golf ball comprising a cover and a core according to claim 1 wherein the core is a solid or liquid center at least partially covered with a wound thread.

24. The golf ball according to claim 1, wherein the ionomer comprises ethylene and methacrylic or acrylic acid.

25. The golf ball according to claim 24, wherein the ionomer is a terpolymer.

8. A golf ball having a core and a cover, said cover comprising a blend of two or more ionomer resins with one or more non-ionic copolymers of an olefin with attached lower alkyl groups having from about 1 to about 18 carbon atoms said olefin comonomer produced using a metallocene catalyst.

9. A golf ball according to claim 8 having multiple cover or core layers.

26. The golf ball according to claim 8, wherein the ionomers comprise ethylene and methacrylic or acrylic acid.

27. The golf ball according to claim 26, wherein the ionomer is a terpolymer.

10. A golf ball having a core and a cover wherein said cover comprises one or more ionomer resins having a flexural modulus of from about 50 psi to about 150,000 psi and a non-ionic metallocene catalyzed copolymer of an olefin having a flexural modulus of from about 500 psi to 200,000 psi.

11. A golf ball having a core and a cover wherein said cover comprises an at least partially miscible blend of at least one ionomer resin and at least one polyolefin resin, wherein the polyolefin resin is formed with a metallocene catalyst.

28. The golf ball according to claim 11, wherein the ionomer comprises ethylene and methacrylic or acrylic acid.

29. The golf ball according to claim 28, wherein the ionomer is a terpolymer.

12. A golf ball having a core and a cover wherein said cover comprises from about 99 to 1 phr of at least one ionomer resin chosen from the group consisting of ethylene-methacrylic acid and ethylene-acrylic acid copolymers neutralized by mono, di or tri-valent metallic derivatives;

and from about 1 to 99 phr of at least one non-ionic metallocene catalyzed copolymer of an olefin with a lower alkyl substituent having from about 1 to about 18 carbon atoms.

14. A golf ball according to claim 12 wherein the cover comprises from about 95-30 percent ionomer and from about 5-70 percent metallocene catalyzed copolymer.

15. A golf ball according to claim 12 wherein the cover comprises from about 95-50 percent ionomer and from about 5-50 percent metallocene catalyzed copolymer.

16. A golf ball according to claim 12 wherein the olefin has a flexural modulus between about 500 psi and about 150,000 psi.

17. A golf ball according to claim 12 wherein the olefinic polymer is a copolymer in which the monomers are selected from the group consisting of butene, hexene, and octene.

18. A golf ball according to claim 12 wherein the olefinic polymer is a copolymer of butene, hexene, or norbornene.

19. A golf ball according to claim 12 wherein the olefinic polymer is a copolymer of ethylene and butene.

20. A golf ball according to claim 12 wherein the olefinic polymer is a copolymer of butene and hexene.

21. A golf ball according to claim 12 wherein the olefinic polymer is a copolymer of ethylene and octene.

13. A golf ball having improved spin comprising a core and a cover wherein said cover comprises from about 95 to 5 phr of at least one ionomer resin chosen from the group consisting of ethylene-methacrylic acid and ethylene-acrylic acid copolymers neutralized by mono, di or tri-valent metallic derivatives;

and from about 5 to 95 phr of at least one non-ionic metallocene catalyzed copolymer of an olefin with a lower alkyl substituent having from about 1 to about 18 carbon atoms.

22. A golf ball according to claim 13 wherein the olefinic polymer is a copolymer of ethylene and norbornene.

23. A golf ball according to claim 13 wherein the olefinic polymer is a polymer of ethylene and propylene and diene monomer.