Method of using a bipolar electrochemical storage device

• US 5,705,259 A
• Filed: 10/25/1995
• Issued: 01/06/1998
• Est. Priority Date: 11/17/1994
• Status: Expired due to Fees

• Current Assignee: Johnson Controls Technology Company (Johnson Controls International plc)
• Original Assignee: Globe-Union Inc.
• Inventors: Reichman, Benjamin, Mrotek, Edward N.
• Primary Examiner(s): RYAN, PATRICK J
• Application Number:
  US08/547,833
• Time in Patent Office: 804 Days
• Field of Search: 428/220, 428/209, 428/408, 428/457, 428/323, 428/901, 429/210, 429/234, 429/245, 204/280
• US Class Current: 428/209
• CPC Class Codes: H01M 2300/0011 Sulfuric acid-based
• CPC Class Codes: H01M 4/02 Electrodes composed of, or comprising, active material
• CPC Class Codes: H01M 4/14 Electrodes for lead-acid accumulators
• CPC Class Codes: H01M 4/68 for use in lead-acid accumulators
• CPC Class Codes: H01M 6/48 with bipolar electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10S 428/901 Printed circuit
• CPC Class Codes: Y10T 428/24917 including metal layer
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

A double layer structure for use as a capacitor or battery electrode, for use in other electrochemical systems, includes in one embodiment a first layer containing conductive transition metal oxides and a second layer which includes conductive carbon embedded in a suitable binder. For capacitor and lead-acid battery applications the transition metal containing material is used as the negative terminal substrate. Another embodiment includes a carbon layer on an electrode surface, the electrode being made from the transition metal oxide in a binder. The last mentioned carbon layer is thin, inexpensive and more conductive than a laminate layer in which the carbon is imbedded in a self-supporting binder.

Claims

1. A method of using a bipolar electrode element, which element comprises a laminated substrate including a first layer comprising a particulate conductive metal oxide dispersed in a resin binder, and a second layer comprising particulate carbon material dispersed in a resin binder, the metal oxide being selected from the group consisting of barium metaplumbate and the conductive oxides of titanium, tungsten, vanadium, niobium and molybdenum, a negative electrode material applied to the first layer, and a positive electrode material applied to the second layer, which method comprises:

employing the first layer at the negative side of a bipolar electrical element;

employing the second layer at the positive side of the bipolar electrical element.

2. The method of claim 1, wherein the thickness of the first layer is between about 0.005-0.1 inch.

3. The method of claim 1, wherein the thickness of the second layer is between about 0.001-0.02 inch.

4. The method of claim 2, wherein the thickness of the second layer is between about 0.001-0.02 inch.

5. The method of claim 1, wherein the conductive metal oxide consists essentially of barium metaplumbate.

6. The method of claim 1, wherein the resin binder is a polyolefin.

7. The method of claim 1, wherein the particle size of the conductive metal oxide is in the range of 0.1 to 300 microns.

8. The method of claim 7, wherein the particle size of the conductive metal oxide is in the range of 0.1 to 40 microns.

9. The method of claim 1, wherein the first layer comprises 10-95 parts by volume of the conductive oxide and 90-5 parts by volume of the binder.

10. The method of claim 1, wherein the second layer comprises 10-95 parts by volume of the conductive oxide and 90-5 parts by volume of the binder.

11. The method of claim 1, wherein the particle size of the carbon is in the range of 0.1 to 300 microns.

12. The method of claim 11, wherein the carbon has an average particle size in the range of 0.1 to 40 microns.

13. The method of claim 1, wherein the second layer is thinner than the first layer.

14. The method of claim 13, wherein the electrode element is formed by coating the conductive oxide layer with a liquid or paste containing the binder and the particulate carbon.

15. The method of claim 14, wherein the second layer binder comprises a synthetic rubber.

16. The method of claim 1, wherein the electrode element is formed by coating the conductive oxide layer with a liquid or paste containing the binder and the particulate carbon.

17. The method of claim 16, wherein the second layer binder comprises a synthetic rubber.

18. The method of claim 1, wherein the electrode element is a double-layered capacitor.

19. The method of claim 1, wherein the electrode element is a bipolar lead-acid battery electrode.