Prehydrolysis of lignocellulose

• US 5,705,369 A
• Filed: 05/18/1995
• Issued: 01/06/1998
• Est. Priority Date: 12/27/1994
• Status: Expired due to Term

• Current Assignee: Alliance For Sustainable Energy LLC
• Original Assignee: Midwest Research Institute
• Inventors: Kadam, Kiran L., Philippidis, George P., Hsu, Teh-An, Wyman, Charles E., Torget, Robert W.
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US08/443,693
• Time in Patent Office: 964 Days
• Field of Search: 435/101, 435/99, 435/105, 435/136, 435/148, 435/157, 435/163, 435/201, 536/1.11, 536/57, 536/124, 536/56, 127/1, 127/37
• US Class Current: 435/105
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: C12P 19/02 Monosaccharides 2-ketogulonic acid C12P7/60
• CPC Class Codes: D21C 1/00 Pretreatment of the finely-divided materials before digesting of waste paper D21C5/02

Abstract

The invention relates to the prehydrolysis of lignocellulose by passing an acidic or alkaline solution through solid lignocellulosic particles with removal of soluble components as they are formed. The technique permits a less severe combination of pH, temperature and time than conventional prehydrolysis. Furthermore, greater extraction of both hemicellulose and lignin occurs simultaneously in the same reactor and under the same conditions.

Claims

1. A process for prehydrolyzing lignocellulosic material comprising:

placing solid lignocellulosic material in a prehydrolysis reactor;

adding an acidic liquid to said solid lignocellulosic material to make a mixture;

heating the mixture to reaction temperature;

maintaining reaction temperature for time sufficient to fractionate the lignocellulosic material into a solubilized portion containing at least 20% of the lignin from the lignocellulosic material and a solid fraction containing cellulose;

removing said solubilized portion from the solid fraction while at or near reaction temperature wherein said cellulose in the solid fraction is rendered more amenable to enzymatic digestion;

and recovering said solubilized portion.

2. The process according to claim 1, wherein said reaction temperature is about 120°

C. to about 240°

C. and the solubilized portion has a pH of about 1 to about 5.5.

3. The process according to claim 1, wherein said acidic liquid is continuously added throughout said prehydrolysis.

4. The process according to claim 1, wherein at least one condition of the prehydrolysis is changed during the prehydrolysis.

5. The process according to claim 4, further comprising passing the acidic liquid into and through said prehydrolysis reactor before or during a change in at least one condition.

6. The process according to claim 1, wherein the prehydrolysis reactor is a flow-through reactor.

7. The process according to claim 1, wherein said solubilized portion comprises pentose, oligomers of pentose and a significant amount of lignin, said solid material contains cellulose, substantially no hemicellulose and a significantly reduced amount of lignin compared to said lignocellulosic material.

8. The process according to claim 1, further comprising removing the solid material from said prehydrolysis reactor.

9. A process for producing sugar from lignocellulosic material comprising;

placing solid lignocellulosic material in a prehydrolysis reactor;

adding an acidic liquid to said lignocellulosic material to make a mixture;

heating the mixture to reaction temperature;

maintaining reaction temperature for time sufficient to solubilize a sufficient portion of lignocellulosic material to render the cellulose therein enzymatically digestible;

removing solubilized portion from the solid material while at or near reaction temperature;

recovering said solubilized portion;

hydrolyzing sugar contained in the solubilized portion;

removing the solid material from the prehydrolysis reactor;

allowing the solid material to cool to enzymatically digestible temperature;

adding at least one enzyme capable of digesting cellulose to glucose to the solid material; and

digesting cellulose in the solid material with the enzyme to produce glucose;

recovering the glucose.

10. The process according to claim 9, wherein said reaction temperature is about 120°

C. to about 240°

C. and the solubilized portion has a pH of about 1 to about 5.5.

11. The process according to claim 9, wherein said acidic liquid is continuously added throughout said prehydrolysis.

12. The process according to claim 9, wherein at least one condition of the prehydrolysis is changed during the prehydrolysis.

13. The process according to claim 9, further comprising passing the acidic liquid into and through said prehydrolysis reactor before or during a change in at least one condition.

14. The process according to claim 9, wherein the prehydrolysis reactor is a flow-through reactor.