Non-aqueous secondary battery

• US 5,707,756 A
• Filed: 03/10/1997
• Issued: 01/13/1998
• Est. Priority Date: 11/29/1994
• Status: Expired due to Term

• Current Assignee: Xenogenic Development Limited Liability Company (Intellectual Ventures LLC)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Naito, Hideki, Kobayashi, Chuzo, Nagamachi, Toshiharu, Miyasaka, Tsutomu, Takahashi, Osamu, Matsufuji, Akihiro, Inoue, Noriyuki, Yasunami, Shoichiro, Maekawa, Yukio, Kagawa, Yoshikatsu, Goda, Kensuke
• Primary Examiner(s): NUZZOLILLO, MARIA
• Application Number:
  US08/814,961
• Time in Patent Office: 309 Days
• Field of Search: 429/53, 429/54, 429/57, 429/56, 429/59, 429/194, 429/218
• US Class Current: 429/57
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 2004/027 Negative electrodes
• CPC Class Codes: H01M 2200/106 PTC
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/485 of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy H01M4/505, H01M4/525 take precedence
• CPC Class Codes: H01M 4/581 Chalcogenides or intercalation compounds thereof
• CPC Class Codes: H01M 4/622 being polymers
• CPC Class Codes: H01M 4/624 Electric conductive fillers
• CPC Class Codes: H01M 50/342 Non-re-sealable arrangements
• CPC Class Codes: H01M 50/44 Fibrous material
• CPC Class Codes: H01M 50/578 in response to pressure
• CPC Class Codes: H01M 50/581 in response to temperature
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The present invention provides a non-aqueous secondary battery having an improved charge and discharge cycle property and high discharge voltage, high energy density, high capacity and increased stability as well as an excellent high electric current atitude by using a lithium-containing transition metal oxide as a positive electrode material and at least one of the specfified composite oxides as a negative electrode material. Accordingly, the feature of the present invention consists in that the negative electrode material mainly consists of at least one member selected from the group consisting of amorphous chalcogen compounds and amorphous oxides containing at least three atoms selected from the group consisting of Group 13, 14, 15 and 2 atoms of Periodic Table.

Claims

1. A sealed non-aqueous secondary battery, comprising an assembly composed of a positive electrode and a negative electrode, capable of intercalating and deintercalating a light metal, and a separator, the assembly being held by a bottomed battery can with a non-aqueous electrolyte, an insulating gasket provided on an inner circumference of an opening part of the can and a sealing structure fitted to and supported by the gasket, wherein said can additionally functions as a positive electrode or negative electrode terminal cap, the opening part of the can being sealed, and wherein the sealing structure comprises an explosion-proof valve being deformable in the opposite direction to the assembly with an increase in inner pressure of the battery, a sealing structure terminal cap having formed thereon a vent hole arranged at the opposite side to the assembly and an electric current cutoff element arranged between the explosion-proof valve and the sealing structure terminal cap, the explosion-proof valve being a dish-shaped body having a flat area projected toward the assembly from the vicinity of the outer circumference thereof, having groove-shaped thin wall parts and provided with, at the central part thereof, a projection part projected toward the opposite side to the assembly, in the form of one integrated unit;

wherein the groove-shaped thin wall parts are portions of the dish-shaped body which break to permit gas to be released.

2. The sealed non-aqueous secondary battery as claimed in claim 1, wherein the dish-shaped body of the explosion-proof valve is one that deforms

(a) at a first rate during an initial period of increasing inner pressure,

(b) at a second rate, which is higher than the first rate, during a period of increasing inner pressure which immediately follows the initial period, and

(c) at a third rate, which is lower that the second rate, during a final period of increasing inner pressure.

3. The sealed non-aqueous secondary battery as claimed in claim 1, wherein said explosion-proof valve consists of an aluminum or its alloy and at least a part of said groove-shaped thin wall parts is formed in a circumferential form.

4. The sealed non-aqueous secondary battery as claimed in claim 1, wherein the cross-section of the side wall of the recess part between the outer circumference and projected flat area is substantially Z-shaped.

5. The sealed non-aqueous secondary battery as claimed in claim 1, wherein said explosion-proof valve is formed by forging working.

6. The sealed non-aqueous secondary battery as claimed in claim 1, wherein the thickness of the side wall of the recess part between the outer circumference and projected flat area is larger than that of the projected flat area.

7. The sealed non-aqueous secondary battery as claimed in claim 1, wherein the negative electrode is formed of a material comprising an amorphous chalcogen compound or an amorphous oxide containing at least three atoms selected from the elements of Group 13, 14, 15 and 2 of the Periodic Table.

8. The sealed non-aqueous secondary battery as claimed in claim 1, wherein the negative electrode is formed of a material comprising an amorphous material capable of intercalating and deintercalating a light metal ion and is heat treated in a reducing atmosphere.

9. The sealed non-aqueous secondary battery as claimed in claim 1, wherein the negative electrode is formed of a negative electrode material comprising an amorphous material obtained by mixing and calcining an oxide or chalcogenide and silicon dioxide.

10. The sealed non-aqueous secondary battery as claimed in claim 1, wherein said negative electrode material is heat treated in a reducing atmosphere.

11. The sealed non-aqueous secondary battery as claimed in claim 1, wherein the negative electrode is formed of a material obtained by mixing and calcining an oxide or chalcogenide and silicon dioxide.

12. The sealed non-aqueous secondary battery as claimed in claim 1, wherein the thin wall parts have a thickness of from at least 0.05 mm to at most 2/3 of the thickness of the flat area projected toward the assembly.

13. The sealed non-aqueous secondary battery as claimed in claim 1, wherein the negative electrode is formed of a negative electrode material comprising a true density ρ

in a range of 2.5<

ρ

<

7.5.

14. The sealed non-aqueous secondary battery as claimed in claim 1, wherein the negative electrode is formed of a negative electrode material comprising at least one member selected from the group consisting of chalcogen compounds and oxides containing at least one atom selected from the group consisting of Group 13, 14, 15 and 2 metals of the Periodic Table, which are capable of intercalating and deintercalating a light metal and have a true density ρ

in a range of 2.5<

ρ

<

7.5.

15. The sealed non-aqueous secondary battery as claimed in claim 2, wherein said explosion-proof valve consists of an aluminum or its alloy and at least a part of said groove-shaped thin wall parts is formed in a circumferential form.