Light-sensitive composition

• US 5,707,777 A
• Filed: 06/06/1995
• Issued: 01/13/1998
• Est. Priority Date: 10/01/1991
• Status: Expired due to Fees

• Current Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Kokubo, Tadayoshi, Aoai, Toshiaki
• Primary Examiner(s): Hamilton, Cynthia
• Application Number:
  US08/466,136
• Time in Patent Office: 952 Days
• Field of Search: 430/270.1, 430/909, 430/910, 430/921, 430/326, 430/281.1, 522/59, 522/54
• US Class Current: 430/270.1
• CPC Class Codes: G03F 7/0045 with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
• CPC Class Codes: G03F 7/0755 Non-macromolecular compounds containing Si-O, Si-C or Si-N bonds G03F7/0752 takes precedence
• CPC Class Codes: Y10S 430/11 Vinyl alcohol polymer or derivative
• CPC Class Codes: Y10S 430/111 Polymer of unsaturated acid or ester
• CPC Class Codes: Y10S 430/122 Sulfur compound containing

Abstract

A positive-working light-sensitive composition which comprises:

(a) 0.5 to 80% by weight of a compound which has at least one group capable of being decomposed by an acid and whose solubility in an alkaline developer is increased by an acid;

(b) 0.01 to 20% by weight of a disulfone compound represented by the following formula (I);

R.sup.1 --SO.sub.2 --SO.sub.2 --R.sup.2                    (I)

wherein R¹ and R² may be the same or different and represent a substituted or unsubstituted alkyl, alkenyl or aryl group; and

(c) 5 to 99.49% by weight of a resin insoluble in water and soluble in an alkaline water,

wherein the compound of the component (a) has a molecular weight of not more than 2,000 and a boiling point of not less than 150° C. and wherein a film of the composition having a thickness of 1 μm has an optical density determined at 248 nm of not more than 1.4 before exposure to light and the optical density of the composition determined at 248 nm is reduced by exposure to light of 248 nm.

Claims

1. A positive working photosensitive composition which comprises:

(a) 0.5 to 80% by weight, based on the total weight of solids in the composition, of a compound which has (i) at least one group capable of being decomposed by an acid, said group being selected from the group consisting of tertiary alkyl ether groups, tertiary alkyl ester groups and tertiary alkyl carbonate groups, (ii) a molecular weight of not more than 1,200, and (iii) a boiling point of not less than 150°

C.;

(b) 0.01 to 20% by weight, based on the total weight of solids in the composition, of a disulfone compound represented by the following formula (I);

space="preserve" listing-type="equation">R.sup.1 --SO.sub.2 --SO.sub.2 --R.sup.2 (I);

wherein R¹ and R² independently represent a substituted or unsubstituted alkyl, alkenyl or aryl group; and

(c) 5 to 99.49% by weight, based on the total weight of solids in the composition, of a resin insoluble in water and soluble in an alkaline water, wherein a film of the composition having a thickness of 1 μ

m has an optical density determined at 248 nm of not more than 1.4 before exposure to light and the optical density of the composition determined at 248 nm is reduced by exposure to light of 248 nm,

wherein the compound of the component (a) is selected from the following compounds;

##STR7## wherein A represents a hydrogen atom, ##STR8## and B represents a group A or --CO--O--A, provided that at least one of the groups A and B present in a single molecule is a group other than hydrogen.

2. A positive working photosensitive composition which comprises:

(a) 0.5 to 80% by weight, based on the total weight of solids in the composition, of a compound which has (i) at least one group capable of being decomposed by an acid, said group being selected from the group consisting of tertiary alkyl ether groups, tertiary alkyl ester groups and tertiary alkyl carbonate groups, (ii) a molecular weight of not more than 1,200, and (iii) a boiling point of not less than 150°

C.;

(b) 0.01 to 20% by weight, based on the total weight of solids in the composition, of a disulfone compound represented by the following formula (I);

space="preserve" listing-type="equation">R.sup.1 --SO.sub.2 --SO.sub.2 --R.sup.2 (I);

wherein R¹ and R² independently represent a substituted or unsubstituted alkyl, alkenyl or aryl group; and

(c) 5 to 99.49% by weight, based on the total weight of solids in the composition, of a resin insoluble in water and soluble in an alkaline water, wherein a film of the composition having a thickness of 1 μ

m has an optical density determined at 248 nm of not more than 1.4 before exposure to light and the optical density of the composition determined at 248 nm is reduced by exposure to light of 248 nm,

wherein said composition further comprises one or more components selected from the group consisting of cyclic acid anhydrides for improving sensitivity, printing out agents for obtaining a visible image immediately after imagewise exposure, and fillers.