Emulsifiable suspension concentrate compositions of imidazolinyl benzoic acids, esters and salts thereof, and dinitroaniline herbicides

• US 5,707,928 A
• Filed: 04/21/1995
• Issued: 01/13/1998
• Est. Priority Date: 09/28/1993
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: American Colloid Company (Minerals Technologies Incorporated)
• Inventors: Baker, Ivor Philip
• Primary Examiner(s): CLARDY, S
• Application Number:
  US08/426,537
• Time in Patent Office: 998 Days
• Field of Search: 504/116, 504/139, 504/130, 504/148, 71/DIG. 1
• US Class Current: 504/139
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 43/50 1,3-Diazoles; Hydrogenated 1,3-diazoles

Abstract

The present invention provides herbicidal emulsifiable suspension concentrate compositions of imidazolinyl benzoic acids, or esters or salts thereof, and dinitroaniline herbicides. Such compositions have improved low temperature stability.

Claims

1. A herbicidal emulsifiable suspension concentrate composition comprising about 5% to 20% by weight of a imidazolinyl benzoic acid, or ester or salt thereof, about 10% to 30% by weight of a dinitroaniline herbicide, about 0.5% to 10% by weight of a mixture of an alkylarylsulfonate and an alkylarylsulfonic acid, about 5% to 15% by weight of a nonionic surfactant or mixture of nonionic surfactants, about 1% to 10% by weight of a suspending agent, up to about 1% by weight if an antifoaming agent, and an aromatic solvent or mixture of aromatic solvents.

2. The composition according to claim 1 wherein the imidazolinyl benzoic acid, or ester or salt thereof, comprises imazamethabenz-methyl.

3. The composition of claim 1 wherein the ratio of the alkylarylsulfonate to the alkylarylsulfonic acid is about 0.1:

1 to 8;

1 and the ratio of the mixture of the alkylarylsulfonate and the alkylarylsulfonic acid to imazamethabenz-methyl is about 0.1;

1 to 0.6;

1.

4. The composition according to claim 3 which comprises about 10% to 15% by weight imazamethabenz-methyl, about 15% to 25% by weight of a dinitroaniline herbicide, about 2% to 6% by weight of a mixture of an alkylarylsulfonate and an alkylarylsulfonic acid, about 5% to 10% by weight of a polyoxyethylene phenyl ether, about 0.5% to 2% by weight of a polyalkylene glycol ether, about 1% to 6% by weight of a clay, up to about 1% by weight of an antifoaming agent, up to about 2% by weight xylene, and an aromatic hydrocarbon solvent having a distillation range of from about 135°

C. to 305°

C., wherein the ratio of the alkylarylsulfonate to the alkylarylsulfonic acid is about 0.1;

1 to 8;

1 and the ratio of the mixture of the alkylarylsulfonate and the alkylarylsulfonic acid to imazamethabenz-methyl is about 0.1;

1 to 0.6;

1.

5. The composition according to claim 1 wherein the dinitroaniline herbicide is selected from the group consisting of pendimethalin, trifluralin, benfluralin, isopropalin, ethalfluralin and oryzalin.

6. The composition according to claim 5 wherein the dinitroaniline herbicide is pendimethalin.

7. The composition according to claim 1 wherein the alkylarylsulfonate is a C₈ -C₁₈ alkylbenzenesulfonate, the alkylarylsulfonic acid is a C₈ -C₁₈ alkylbenzenesulfonic acid, the nonionic surfactant is a mixture of a polyoxyethylene phenyl ether and a polyalkylene glycol ether and the suspending agent is a clay.

8. The composition according to claim 7 wherein the C₈ -C₁₈ alkylbenzenesulfonate is calcium dodecylbenzenesulfonate, the C₈ -C₁₈ alkylbenzenesulfonic acid is dodecylbenzenesulfonic acid, the polyoxyethylene phenyl ether is a polyoxyethylene nonylphenyl ether with about 11 moles of ethylene oxide per molecule, the polyalkylene glycol ether is a butoxypolypropylenoxy polyethylenoxyethanol and the clay is an attapulgite clay.

9. The composition according to claim 1 wherein the aromatic solvent is a mixture of xylene and an aromatic hydrocarbon solvent having a distillation range of from about 135°

C. to 305°

C.

10. The composition according to claim 9 wherein the aromatic hydrocarbon solvent has a distillation range of from about 183°

C. to 290°

C.

11. The composition according to claim 1 wherein the aromatic solvent is an aromatic hydrocarbon solvent having a distillation range of from about 135°

C. to 305°

C.

12. The composition according to claim 11 wherein the aromatic hydrocarbon solvent has a distillation range of from about 183°

C. to 290°

C.