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Mediators to oxidoreductase enzymes

  • US 5,710,011 A
  • Filed: 03/06/1995
  • Issued: 01/20/1998
  • Est. Priority Date: 06/05/1992
  • Status: Expired due to Term
First Claim
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1. A process of mediating electron transfer between an electrode and an oxidoreductase enzyme or other electron transfer redox protein using a mediator compound, wherein said mediator compound is a half-sandwich complex of a transition metal, said complex having only a single π

  • -ligand with delocalised π

    bonding and having the general formula;

    
    
    space="preserve" listing-type="equation">(π

    -ligand)M(not-π

    -ligand).sub.nwherein the complex may be charged or neutral, π

    -ligand represents the single π

    -bonded ligand, M represents the transition metal atom, n is the number of ligands which are not π

    -ligands, and the n not-π

    -ligands are the same or different, are univalent or multivalent, and serve to satisfy the valency of the transition metal M.

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