Soy protein-based thermoplastic composition for foamed articles

• US 5,710,190 A
• Filed: 06/07/1995
• Issued: 01/20/1998
• Est. Priority Date: 06/07/1995
• Status: Expired due to Term

• Current Assignee: Iowa State University Research Foundation Incorporated (Iowa State University)
• Original Assignee: Iowa State University Research Foundation Incorporated (Iowa State University)
• Inventors: Jane, Jay-lin, Zhang, Su She
• Primary Examiner(s): SERGENT, RABON A
• Application Number:
  US08/487,047
• Time in Patent Office: 958 Days
• Field of Search: 521/84.1, 521/88, 521/92, 521/94, 521/95, 521/97, 521/102, 521/109.1, 521/116, 521/117, 521/118, 521/125, 521/128, 521/130, 521/134, 521/151, 521/120, 426/564, 426/656, 426/440, 426/442, 426/445
• US Class Current: 521/102
• CPC Class Codes: C08J 2389/00 Characterised by the use of proteins; Derivatives thereof
• CPC Class Codes: C08J 9/104 Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof
• CPC Class Codes: C08K 5/0008 Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
• CPC Class Codes: C08L 89/00 Compositions of proteins; Compositions of derivatives thereof foodstuff preparations A23J3/00

Abstract

The invention provides a biodegradable thermoplastic composition made of soy protein, a plasticizing agent, a foaming agent, and water, that can be molded into biodegradable articles that have a foamed structure and are water-resistant with a high level of physical strength and/or thermal insulating properties.

Claims

1. A biodegradable, soy protein-based thermoplastic composition, comprising the reaction mixture of:

(a) about 50-100 parts by weight soy protein;

(b) about 0.1-10 parts by weight of a sulfonylhydrazide foaming agent;

(c) about 5-60 parts by weight organic plasticizing agent; and

(d) about 5-20 parts by weight water;

the composition being a moldable, biodegradable thermoplastic composition having a foamed, cellular structure when molded into an article.

2. The thermoplastic composition according to claim 1, wherein the soy protein is a soy protein concentrate, soy protein isolate, or a combination thereof.

3. The thermoplastic composition according to claim 1, wherein the sulfonylhydrazide foaming agent is a compound selected from the group consisting of benzosulfonylhydrazide, p-toluenesulfonylhydrazide, 4,4'"'"'-oxybis(benzenesulfonylhydrazide), bis(hydrozosulfonyl)benzene, 4,4'"'"'-bis(hydrozosulfonyl) biphenylhydrazide, and diphenylsulfone-3,3-disulfonyl-hydrazide.

4. The thermoplastic composition according to claim 1, wherein the plasticizing agent is selected from the group consisting of glycerol, ethylene glycol, propylene glycol, 1,4-butanediol, diethylene glycol, triethylene glycol, polyethylene glycol, polypropylene glycol, polyethylene-propylene glycol, sodium cellulose glycolate, sodium diethylsuccinate, triethyl citrate, polyethylene glycol fatty acid esters, glycerol monoacetate, diglycerol, glycerol diacetate or triacetate, diacetin sorbitol, sorbitan, mannitol, maltitol, polyvinyl alcohol, cellulose methyl ether, sodium alginate, sodium diethylsuccinate, 1,2,6-hexanetriol, and triethanolamine.

5. The thermoplastic composition according to claim 1, further comprising a protein additive selected from the group consisting of gluten, zein, hordein, kafirin, avenin, cotton seed, peanut, rapeseed, and sunflower seed.

6. The thermoplastic composition according to claim 1, further comprising a protein additive selected from the group consisting of collagen, casein, albumin, gelatin, and keratin.

7. The thermoplastic composition according to claim 1, further comprising a filler, lubricant, colorant, bleaching/whitening agent, or a combination thereof.

8. The thermoplastic composition according to claim 7, wherein the filler is a polysaccharide material selected from the group consisting of native starch, chemically-modified starch, physically-modified starch, gum, and cellulosic extender.

9. The thermoplastic composition according to claim 7, wherein the filler is a synthetic polymer selected from the group consisting of poly(acrylic acid), poly(methacrylic acid), poly(vinyl acetate), poly(vinyl alcohol), poly(vinyl acetate phthalate), ethylene/vinyl acetate copolymer, ethylene/vinyl alcohol copolymer, and polyhydroxybutylate.

10. A biodegradable article formed from the thermoplastic composition according to claim 1, the article having a foamed, cellular structure.

11. The article according to claim 10, having a density of about 0.1-0.5 g/cm³.

12. The article according to claim 10, wherein the cell structure is about 90-95% closed cell, and the average cell diameter is about 40-80 μ

m.

13. The article according to claim 12, having a thermal conductivity of about 0.2-0.5 BTU-inch/hour-ft² -°

F.

14. The article according to claim 10, wherein the article when submerged in water has a 24-hour water absorption at about 25°

C. wherein the article expands by about 90-250 wt %.

15. A method of making a biodegradable, thermoplastic article, comprising:

(a) combining together to form a reaction mixture;

(i) about 50-100 parts by weight soy-based protein;

(ii) about 0.1-20 parts by weight of a sulfonylhydrazide foaming agent;

(iii) about 5-60 parts by weight plasticizing agent; and

(iv) about 5-20 parts by weight water;

(b) processing the mixture to form a molded article having a foamed, cellular structure.

16. The method according to claim 15, wherein the mixture is processed at a molding temperature of about 80°

-190°

C., for about 1-7 minutes, at a pressure of about 6-65 Mpa.

17. The method according to claim 16, wherein the mixture is processed by compression molding, injection molding, expanded foam molding, or extrusion molding.

18. A thermoplastic article formed according to the method of claim 15.