Method of analysis for aqueous fluids

• US 5,710,372 A
• Filed: 12/17/1996
• Issued: 01/20/1998
• Est. Priority Date: 12/17/1996
• Status: Expired due to Fees

• Current Assignee: Valenite USA Inc (Sandvik AB)
• Original Assignee: Cincinnati Milacron Incorporated (Milacron Incorporated)
• Inventors: Becket, Giles J. P.
• Primary Examiner(s): Williams, Hezron E.
• Assistant Examiner(s): WIGGINS, JOHN DAVID
• Application Number:
  US08/768,190
• Time in Patent Office: 399 Days
• Field of Search: 73/53.01, 73/61.54, 73/61.41, 73/61.71, 73/53.06, 73/61.52, 422/55, 422/56, 436/162, 436/167
• US Class Current: 73/53.01
• CPC Class Codes: G01N 31/22 using chemical indicators G01N31/02 takes precedence
• CPC Class Codes: G01N 31/221 for investigating pH value

Abstract

A simple, convenient method is provided for measuring the concentration of a constituent of an aqueous fluid composition (e.g. aqueous machining fluid composition) and for measuring total alkalinity thereof. The method comprises the steps of a) contacting a solid state test device with the aqueous fluid wherein the solid state test device comprises a plurality of individual spaced apart test regions on an inert support, each test region comprising an inert matrix impregnated with a reagent selectively interactive with the constituent and a color indicator that produces a change in color in response to changes in the test region resulting from interaction between the reagent and the constituent and wherein the amount of reagent in each test region differs in a predetermined manner from the amount of reagent in adjacent test regions, and b) comparing the solid state test device after contact with the aqueous fluid to a constituent concentration color calibration scale for the same reagent, color indicator and constituent.

Claims

1. In a method of measuring the concentration of a constituent of an aqueous fluid composition the steps comprising a) contacting a solid state test device with the aqueous fluid composition, the solid state test device comprising an inert support and a plurality of individual spaced apart test regions on the support, wherein each test region comprises an inert matrix impregnated with a reagent selectively interactive with the constituent and a color indicator that produces a change in color in response to changes in the test region resulting from interaction between the reagent and the constituent and wherein the amount of the reagent in each test region differs in a predetermined manner from the amount of reagent in adjacent test regions, and b) comparing the solid state test device after contact with the aqueous fluid to a constituent concentration color calibration scale, whereby correspondence is determined between a pattern of resultant colors of the test regions and a constituent concentration represented by the constituent concentration color calibration scale.

2. The method of claim 1 wherein the constituent color calibration scale is specific to the reagent, the color indicator and the constituent.

3. The method of claim 1 wherein the constituent concentration is such that after contact with the aqueous fluid, a color change is produced in at least one but not all of the test regions.

4. The method of claim 1 wherein the reagent is a solid.

5. The method of claim 1 wherein the contacting of the solid state test device with the aqueous fluid composition is by immersing the solid state test device in the aqueous fluid composition.

6. The method of claim 1 wherein the reagent is also the color indicator.

7. The method of claim 1 wherein the interaction between reagent and constituent alters the pH in the test region and the color indicator is a pH color indicator.

8. The method of claim 7 wherein the reagent is chosen such that relatively large changes of pH are effected by relatively small changes in the proportions of reagent and constituent and the pH color indicator is chosen such that the band of pH over which its color changes is relatively narrow.

9. The method of claim 1 wherein the step of comparing the solid state test device after contact with the aqueous fluid composition to a constituent concentration color calibration scale is a step of visually comparing the solid state test device to a constituent concentration color calibration scale.

10. In a method of measuring the concentration of a constituent of an aqueous machining fluid composition, the steps comprising a) contacting a solid state test device with the aqueous machining fluid composition, the solid state test device comprising an inert support and a plurality of individual spaced apart test regions on the support, wherein each test region comprises an inert matrix impregnated with a reagent selectively interactive with the constituent and a color indicator that produces a color change in response to the changes in the test region resulting from interaction between the reagent and the constituent and wherein the amount of reagent in each test region differs in a predetermined manner from the amount of reagent in adjacent test regions and b) comparing the solid state test device after contact with the aqueous machining fluid to a constituent concentration color calibration scale, whereby correspondence is determined between a pattern of the resultant colors of the test regions and a constituent concentration represented by the constituent concentration color calibration scale.

11. The method of claim 10 wherein the interaction between reagent and constituent alters the pH in the test region and the color indicator is a pH color indicator.

12. The method of claim 11 wherein the reagent is chosen such that relatively large changes of pH are effected by relatively small changes in the proportions of reagent and constituent and the pH color indicator is chosen such that the band of pH over which its color changes is relatively narrow.

13. The method of claim 10 wherein the constituent concentration color calibration scale is specific to the reagent, the color indicator and the constituent.

14. The method of claim 10 wherein the constituent concentration is such that after contact with the aqueous machining fluid, a color change is produced in at least one but not all of the test regions.

15. The method of claim 10 wherein the step of comparing the solid state test device after contact with the aqueous machining fluid composition to a constituent concentration color calibration scale is a step of visually comparing the solid state test device to a constituent concentration color calibration scale.

16. In a method of measuring the total alkalinity of an aqueous machining fluid composition the steps comprising a) contacting a solid state test device with the aqueous machining fluid composition, the solid state test device comprising an inert support and a plurality of individual spaced apart test regions on the support, wherein each test region comprises an inert matrix impregnated with an acid reagent selectively interactive with the alkaline constituents of the aqueous machining fluid and an acid-base color indicator that produces a color change in response to the changes in the test region resulting from interaction between the acid reagent and the alkaline constituents of the aqueous machining fluid and wherein the amount of the acid reagent in each test region differs in a predetermined manner from the amount of acid reagent in adjacent test regions and b) comparing the solid state test device after contact with the aqueous machining fluid to a total alkalinity color calibration scale, whereby correspondence is determined between a pattern of the resultant colors of the test regions and a total alkalinity represented by the total alkalinity color calibration scale.

17. The method of claim 16 wherein the acid reagent is chosen such that relatively large changes of pH are effected by relatively small changes in the proportions of acid reagent and alkaline constituents of the aqueous machining fluid and the acid-base color indicator is chosen such that its color changes over a relatively narrow band of pH.

18. The method of claim 16 wherein the total alkalinity color calibration scale is specific to the acid reagent, the acid-base color indicator and the total alkalinity of the aqueous machining fluid composition.

19. The method of claim 16 wherein the total alkalinity of the aqueous machining fluid composition is such that after contact, a change in color is produced in at least one but not all of the test regions.

20. The method of claim 16 wherein the step of comparing the solid state test device after contact with the aqueous machining fluid composition to a total alkalinity constituent concentration color calibration scale is a step of visually comparing the solid state test device to a total alkalinity constituent concentration color calibration scale.