Rugged fiber optic probe for raman measurement

• US 5,710,626 A
• Filed: 11/15/1996
• Issued: 01/20/1998
• Est. Priority Date: 11/15/1996
• Status: Expired due to Fees

• Current Assignee: Westinghouse Savannah River Company
• Original Assignee: Westinghouse Savannah River Company
• Inventors: Nave, Stanley E., Toole, William R. Jr., O'Rourke, Patrick E.
• Primary Examiner(s): Font, Frank G.
• Assistant Examiner(s): Smith, Zandra V.
• Application Number:
  US08/746,711
• Time in Patent Office: 431 Days
• Field of Search: 356/301, 356/342, 356/442, 385/12, 385/13
• US Class Current: 356/301
• CPC Class Codes: G01J 3/44 Raman spectrometry; Scattering spectrometry ; Fluorescence spectrometry

Abstract

An optical probe for conducting light scattering analysis is disclosed. The probe comprises a hollow housing and a probe tip. A fiber assembly made up of a transmitting fiber and a receiving bundle is inserted in the tip. A filter assembly is inserted in the housing and connected to the fiber assembly. A signal line from the light source and to the spectrometer also is connected to the filter assembly and communicates with the fiber assembly. By using a spring-loaded assembly to hold the fiber connectors together with the in-line filters, complex and sensitive alignment procedures are avoided. The close proximity of the filter assembly to the probe tip eliminates or minimizes self-scattering generated by the optical fiber. Also, because the probe can contact the sample directly, sensitive optics can be eliminated.

Claims

1. An optical probe for use in light scattering analysis of a sample comprising:

a) a housing having a proximal end, a distal end and defining a first cavity;

b) a filter assembly positioned within the first cavity;

c) a probe tip positioned at the distal end of the housing and defining a second cavity which communicates with the first cavity;

d) a fiber assembly positioned within the second cavity and communicating with the filter assembly;

e) a transmitting/receiving line positioned in the first cavity and communicating with the filter assembly; and

f) at least one spring urging the fiber assembly and the transmitting receiving line together thereby holding the filter assembly therebetween.

2. The probe of claim 1 in which the fiber assembly comprises:

a) a transmitting fiber having a proximal end and a distal end;

b) a receiving bundle having a proximal end and a distal end; and

c) an epoxy matrix in which distal ends of the transmitting fiber and the receiving bundle are embedded.

3. The probe of claim 1 in which the probe tip comprises a housing having an end and a window affixed to the end in which the fiber assembly abuts the window.

4. The probe of claim 2 in which the transmitting fiber comprises at least one optical fiber.

5. The probe of claim 2 in which the receiving bundle comprises at least one optical fiber.

6. The probe of claim 2 in which the receiving bundle comprises a plurality of optical fibers.

7. The probe of claim 2 in which the receiving bundle comprises six optical fibers.

8. The probe of claim 2 in which the transmitting fiber comprises a silica core fiber optic cable with doped silica cladding having a low OH and a polyimide buffer.

9. The probe of claim 2 in which the receiving bundle comprises at least one silica core fiber optic cable with doped silica cladding having a low OH and a polyimide buffer.

10. The probe of claim 2 in which the receiving bundle comprises a plurality of silica core fiber optic cables with doped silica cladding having a low OH and a polyimide buffer.

11. The probe of claim 2 in which the receiving bundle comprises six silica core fiber optic cables with doped silica cladding having a low OH and a polyimide buffer.

12. The probe of claim 2 in which the fiber assembly further comprises:

a) a first connector attached to the proximal end of the transmitting fiber; and

b) a second connector attached to the proximal end of the receiving bundle.

13. The probe of claim 12 in which the transmitting/receiving line comprises:

a) a transmitting line having a proximal end and a distal end, the proximal end connected to a light source and the distal end affixed to a third connector; and

b) a receiving line having a proximal end and a distal end, the proximal end connected to a spectrometer and the distal end affixed to a fourth connector.

14. The probe of claim 13 in which the transmitting line comprises at least one optical fiber.

15. The probe of claim 13 in which the transmitting line comprises at least one silica core fiber optic cable with doped silica cladding having a low OH and a polyimide buffer.

16. The probe of claim 13 in which the receiving line comprises at least one optical fiber.

17. The probe of claim 13 in which the receiving line comprises at least one silica core fiber optic cable with doped silica cladding having a low OH and a polyimide buffer.

18. The probe of claim 13 in which the receiving line comprises a plurality of optical fibers.

19. The probe of claim 13 in which the receiving line comprises a plurality of silica core fiber optic cables with doped silica cladding having a low OH and a polyimide buffer.

20. The probe of claim 13 in which the filter assembly comprises:

a) a cylinder having a first bore and a second bore;

b) an input filter disposed in the first bore; and

c) an output filter disposed in the second bore.

21. The probe of claim 20 in which the first connector and the third connector are positioned in the first bore with the input filter disposed therebetween.

22. The probe of claim 21 in which the second connector and the fourth connector are positioned in the second bore with the output filter disposed therebetween.

23. The probe of claim 22 in which the first, second, third and fourth connectors are held in position by at least one spring positioned within the first cavity such that the spring urges the first and third connectors together and the second and fourth connectors together.

24. The probe of claim 20 in which the first, second, third and fourth connectors are conventional SMA connectors with the hoods removed.

25. The probe of claim 20 in which the light source is a laser having a laser line.

26. The probe of claim 25 in which the input filter is a laser pass dielectric filter having greater than seventy-five percent transmission at the laser line with a half-width corresponding to five-hundred cm-1.

27. The probe of claim 26 in which the output filter is a long-pass dielectric filter with forty decibel or greater blocking at the laser line but greater than seventy-five percent transmission for wavelengths about five-hundred cm-1 or more away from the laser line.

28. An optical probe for use in light scattering analysis of a sample comprising:

a) a housing;

b) first carrying means, positioned within the housing, for carrying first and second test signals in which the first test signal is delivered to a sample and the second test signal is received from the sample;

c) second carrying means, positioned within the housing and communicating with the first carrying means, for carrying the first and second test signals;

d) means, interposed between the first and second carrying means, for filtering the first test signal;

e) means, interposed between the first and second carrying means, for filtering the second test signal; and

f) means for urging the first and second carrying means together thereby holding the first and second test signal filtering means therebetween.

29. The optical probe of claim 28 in which the first carrying means comprises:

a) a transmitting fiber having a proximal end, which is affixed within a first SMA connector, and a distal end, which is affixed in a matrix; and

b) a receiving bundle having a proximal end, which is affixed within a second SMA connector, and a distal end, which is affixed in the matrix proximate the transmitting fiber.

30. The optical probe of claim 29 in which the second carrying means comprises:

a) a transmitting line having a distal end, which is affixed within a third SMA connector, and a proximal end, which communicates with a light source; and

b) a receiving line having a distal end, which is affixed within a fourth SMA connector, and a proximal end, which communicates with a detector.

31. The optical probe of claim 30 in which:

a) the first test signal filtering means comprises an input filter disposed between the transmitting line and the transmitting fiber; and

b) the second test signal filtering means comprises an output filter disposed between the receiving line and the receiving bundle.

32. The optical probe of claim 31 in which the urging means comprises at least one coil spring.