Cement compositions

• US 5,711,801 A
• Filed: 09/25/1996
• Issued: 01/27/1998
• Est. Priority Date: 10/31/1995
• Status: Expired due to Term

• Current Assignee: Bobby J. King, James E. Griffith, Jiten Chatterji, Patty L. Totten
• Original Assignee: Bobby J. King, James E. Griffith, Jiten Chatterji, Patty L. Totten
• Inventors: Chatterji, Jiten, King, Bobby J., Griffith, James E., Totten, Patty L.
• Primary Examiner(s): MARCHESCHI, MICHAEL A
• Application Number:
  US08/719,377
• Time in Patent Office: 489 Days
• Field of Search: 106/789, 106/790, 106/791, 106/823, 106/714, 106/819, 405/266, 405/267, 166/293, 166/294, 166/309
• US Class Current: 106/789
• CPC Class Codes: C04B 12/04 Alkali metal or ammonium silicate cements ; Alkyl silicate cements; Silica sol cements; Soluble silicate cements alkali metal silicates per se, their preparation C01B33/32; ammonium silicates per se, their preparation C01C1/00
• CPC Class Codes: C04B 2103/0005 Organic ammonium compounds
• CPC Class Codes: C04B 2103/40 Surface-active agents, dispersants
• CPC Class Codes: C04B 2103/48 Foam stabilisers
• CPC Class Codes: C04B 22/0026 Salt water, e.g. seawater
• CPC Class Codes: C04B 22/062 of the alkali or alkaline-earth metals
• CPC Class Codes: C04B 24/124 Amides
• CPC Class Codes: C04B 24/16 Sulfur-containing compounds
• CPC Class Codes: C04B 24/32 Polyethers, e.g. alkylphenol polyglycolether
• CPC Class Codes: C04B 28/08 Slag cements
• CPC Class Codes: C04B 38/10 by using foaming agents C04B38/02 takes precedenceor by using mechanical means, e.g. adding preformed foam
• CPC Class Codes: C04B 7/02 Portland cement
• CPC Class Codes: C09K 8/46 containing inorganic binders, e.g. Portland cement
• CPC Class Codes: C09K 8/473 Density reducing additives, e.g. for obtaining foamed cement compositions
• CPC Class Codes: E21B 33/13 Methods or devices for cementing, for plugging holes, crevices or the like

Abstract

The present invention provides lightweight, fast setting cement compositions and methods which can be utilized in performing a variety of well cementing operations. The cement compositions are basically comprised of slag cement, water sufficient to form a pumpable slurry, a gas sufficient to foam the slurry and a foaming agent.

Claims

1. A foamed cement composition comprising:

a slag cement;

a water-based fluid present in the range of from about 20% to about 180% by weight of said slag cement;

a gas present in an amount in the range of from about 5% to about 75% by volume of the foamed composition; and

a foaming agent present in an amount in the range of from about 0.5% to about 10% by weight of fluid in the composition.

2. The composition of claim 1 wherein said slag cement has a Blaine fineness in the range of from about 5,000 to about 7,000 square centimeters per gram.

3. The composition of claim 1 wherein said slag cement has a Blaine fineness of about 5,900 square centimeters per gram, and wherein the composition further comprises an activator present in an amount in the range of from about 0.5% to about 10% by weight of said slag cement and a dispersant present in an amount of about 1.4% by weight of said slag cement.

4. The composition of claim 1 wherein said water-based fluid is selected from the group comprising fresh water, salt water, brines or seawater.

5. The composition of claim 1 wherein said gas is selected from the group consisting of nitrogen and air.

6. The composition of claim 1 wherein the foamed cement composition has a density in the range of from about 6 to about 16 pounds per gallon.

7. The composition of claim 1 wherein said foaming agent is a surfactant having a general formula selected from the group consisting of:

space="preserve" listing-type="equation">H(CH.sub.2).sub.a (OC.sub.2 H.sub.4).sub.b OSO.sub.3 X.sup.+(a)

wherein;

a is an integer in the range of from about 5 to about 15,

b is an integer in the range of from about 1 to about 10, and

X is a cation;

space="preserve" listing-type="equation">H(CH.sub.2).sub.a (OC.sub.2 H.sub.4).sub.3 OSO.sub.3 Na.sup.+(b)

wherein;

a is an integer in the range of from about 6 to about 10;

space="preserve" listing-type="equation">H(CH.sub.2).sub.a (OC.sub.2 H.sub.4).sub.b OSO.sub.3 NH.sub.4.sup.+(c)

wherein;

a is an integer in the range of from about 5 to about 15, and

b is an integer in the range of from about 1 to about 10;

space="preserve" listing-type="equation">H(CH.sub.2).sub.a (OC.sub.2 H.sub.4).sub.b OH (d)

wherein;

a is an integer in the range of from about 10 to about 18, and

b is an integer in the range of from about 6 to about 15;

(e) a compound comprising a mixture of the following formulas;

space="preserve" listing-type="equation">X H(CH.sub.2).sub.n --C═

C--(CH.sub.2).sub.m SO.sub.3 Na.sup.+ !

and

space="preserve" listing-type="equation">Y H(CH.sub.2).sub.p --COH--(CH.sub.2).sub.q SO.sub.3 Na.sup.+ !

wherein;

n and m are integers in the range of from about 6 to about 16,

p and q are integers in the range of from about 7 to about 17, and

X and Y are fractions and the sum of X and Y is 1; and

space="preserve" listing-type="equation">H(CH.sub.2).sub.a (OC.sub.2 H.sub.4).sub.b SO.sub.3 NH.sub.4.sup.+(f)

wherein;

a is an integer in the range of from about 6 to about 10, and

b is an integer in the range of from about 3 to about 10.

8. The composition of claim 7 wherein said foaming agent is present in an amount in the range of from about 2% to about 4% by weight of fluid in the composition.

9. The composition of claim 1 further comprising a dispersant present in an amount of about 1.4% by weight of said slag cement.

10. The composition of claim 1 further comprising an activator selected from the group consisting of hydrated lime, Ca(OH)₂, sodium hydroxide, sodium sulfate, sodium carbonate, sodium silicate and Portland cement.

11. The composition of claim 10 wherein said activator is present in an amount in the range of from about 0.5% to about 10% by weight of said slag cement.

12. The composition of claim 1 further comprising a foam stabilizing agent present in an amount in the range of from about 0.25% to about 5% by weight of fluid in the composition.

13. The composition of claim 12 wherein said foam stabilizing agent has a formula selected from the group consisting of:

##STR2## wherein;

R is hydrogen or a methyl radical, and

n is an integer in the range of from about 20 to about 200;

space="preserve" listing-type="equation">CH.sub.3 O(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 OH (b)

wherein;

n is in the range of from about 100 to about 150;

space="preserve" listing-type="equation">R--CONHCH.sub.2 CH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.2 CH.sub.2 CO.sub.2 -- (c)

wherein;

R is a C₁₀ to C₁₈ saturated aliphatic hydrocarbon group or an oleyl group or a linoleyl group; and

space="preserve" listing-type="equation">R--CONHCH.sub.2 CH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.2 CH.sub.2 CO.sub.2 -- (d)

wherein;

R is a COCO radical.

14. The composition of claim 13 wherein said foam stabilizing agent is present in an amount in the range of from about 1% to about 2% by weight of fluid in the composition.

15. A foamed cement composition consisting essentially of:

slag cement;

a water-based fluid present in the range of from about 20% to about 180% by weight of said slag cement in the composition;

a gas present in an amount in the range of from about 5% to about 75% by volume of the resulting foamed composition; and

a foaming agent present in an amount in the range of from about 0.5% to about 10% by weight of fluid in the composition.

16. The composition of claim 15 wherein said slag cement comprises particulate slag having a Blaine fineness in the range of from about 5,000 to about 7,000 square centimeters per gram.

17. The composition of claim 15 wherein said slag cement further comprises an activator present in an amount in the range of from about 0.5% to about 10% by weight of said slag cement.

18. The composition of claim 15 wherein said slag cement further comprises a dispersant present in an amount of about 1.4% by weight of said slag cement.

19. The composition of claim 15 wherein said water-based fluid is selected from the group comprising fresh water, salt water, brines or seawater.

20. The composition of claim 15 wherein said gas is selected from the group consisting of nitrogen and air.

21. The composition of claim 15 wherein the composition has a density in the range of from about 6 to about 16 pounds per gallon.

22. The composition of claim 15 wherein said foaming agent is a surfactant having a formula selected from the group consisting of:

space="preserve" listing-type="equation">H(CH.sub.2).sub.a (OC.sub.2 H.sub.4).sub.b OSO.sub.2 X.sup.+(a)

wherein;

a is an integer in the range of from about 5 to about 15,

b is an integer in the range of from about 1 to about 10, and

X is a cation;

space="preserve" listing-type="equation">H(CH.sub.2).sub.a (OC.sub.2 H.sub.4).sub.3 OSO.sub.3 Na.sup.+(b)

wherein;

a is an integer in the range of from about 6 to about 10;

space="preserve" listing-type="equation">H(CH.sub.2).sub.a (OC.sub.2 H.sub.4).sub.b OSO.sub.3 NH.sub.4.sup.+(c)

wherein;

a is an integer in the range of from about 5 to about 15, and

b is an integer in the range of from about 1 to about 10;

space="preserve" listing-type="equation">H(CH.sub.2).sub.a (OC.sub.2 H.sub.4).sub.b OH (d)

wherein;

a is an integer in the range of from about 10 to about 18, and

b is an integer in the range of from about 6 to about 15;

(e) a compound comprising a mixture of the following formulas;

space="preserve" listing-type="equation">X H(CH.sub.2).sub.n --C═

C--(CH.sub.2).sub.m SO.sub.3 Na.sup.+ !

and

space="preserve" listing-type="equation">Y H(CH.sub.2).sub.p --COH--(CH.sub.2).sub.q SO.sub.3 Na.sup.+ !

wherein;

n and m are integers in the range of from about 6 to about 16,

p and q are integers in the range of from about 7 to about 17, and

X and Y are fractions and the sum of X and Y is 1; and

space="preserve" listing-type="equation">H(CH.sub.2).sub.a (OC.sub.2 H.sub.4).sub.b SO.sub.3 NH.sub.4.sup.+(f)

wherein;

a is an integer in the range of from about 6 to about 10, and

b is an integer in the range of from about 3 to about 10.

23. The composition of claim 22 wherein said foaming agent is present in an amount in the range of from about 2% to about 4% by weight of fluid in the composition.

24. The composition of claim 15 wherein the composition further comprises a foam stabilizing agent present in an amount in the range of from about 0.25% to about 5% by weight of fluid in the composition.

25. The composition of claim 24 wherein said foam stabilizing agent has a general formula selected from the group consisting of:

##STR3## wherein;

R is hydrogen or a methyl radical,

n is an integer in the range of from about 20 to about 200;

space="preserve" listing-type="equation">CH.sub.3 O(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 OH (b)

wherein;

n is in the range of from about 100 to about 150;

space="preserve" listing-type="equation">R--CONHCH.sub.2 CH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.2 CH.sub.2 CO.sub.2 -- (c)

wherein;

R is a C₁₀ to C₁₈ saturated aliphatic hydrocarbon group or an oleyl group or a linoleyl group; and

space="preserve" listing-type="equation">R--CONHCH.sub.2 CH.sub.2 CH.sub.2 N.sup.+ (CH.sub.3).sub.2 CH.sub.2 CO.sub.2(d)

wherein;

R is a COCO radical.