Stable microdispersions and microgels based on acrylic polymers, method for obtaining them and compositions, particularly cosmetic compositions, containing them

• US 5,711,940 A
• Filed: 06/12/1996
• Issued: 01/27/1998
• Est. Priority Date: 10/01/1993
• Status: Expired due to Fees

• Current Assignee: Lvmh Recherche
• Original Assignee: Lvmh Recherche
• Inventors: Tranchant, Jean-Fran.cedilla.ois, Kuentz, Annie, Meybeck, Alain, Riess, Henri-Gerard
• Primary Examiner(s): Webman, Edward J.
• Application Number:
  US08/619,751
• Time in Patent Office: 594 Days
• Field of Search: 424/61, 424/487, 424/501, 528/402, 525/94, 525/221, 525/227, 525/301, 525/302, 252/315.4
• US Class Current: 424/61
• CPC Class Codes: A61K 8/042 Gels
• CPC Class Codes: A61K 8/044 Suspensions
• CPC Class Codes: A61K 8/90 Block copolymers A61K8/89 takes precedence
• CPC Class Codes: A61Q 3/02 Nail coatings
• CPC Class Codes: C08F 2/08 with the aid of dispersing agents for the polymer
• CPC Class Codes: C08F 220/00 Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
• CPC Class Codes: C08F 287/00 Macromolecular compounds obtained by polymerising monomers on to block polymers
• CPC Class Codes: C09D 151/006 grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds

Abstract

The invention relates to a process for the preparation of a stable microdispersion of particles comprised of acrylic polymers in an organic solvent used as reaction medium in the presence of a stabilizing agent comprised of a block copolymer, characterized in that said acrylic polymer is obtained by radical polymerization of at least one acrylic monomer in the presence of a block copolymer based on polymethyl methacrylate (PMMA) and polytert-butyl acrylate (PtBuA). It also relates to microdispersions which may be obtained by said process as well as to microgels produced from said microdispersions and compositions, particularly cosmetic compositions such as nail varnish.

Claims

1. In a method of preparing a stable microdispersion of particles of acrylic polymers in an organic solvent in the presence of a stabilizer the improvement comprising:

forming said acrylic polymer by a free-radical polymerization of at least one acrylic monomer in the presence of a block copolymer as said stabilizer, wherein said block copolymer is a copolymer of polymethyl methacrylate (PMMA) and polytert-butyl acrylate (PtBuA) and said solvent solubilizes said PtBuA chain of said copolymer and precipitates both said PMMA chain of said copolymer and said acrylic polymer.

2. The method according to claim 1 wherein said block copolymer has a molecular weight between 20,000 and 500,000.

3. The method according to claim 1 wherein the block copolymer is a two-block copolymer and PtBuA represents 10 to 90% by weight of said block copolymer.

4. The method according to claim 1 wherein said block copolymer is a three-block copolymer of PtBuA-b-PMMA-b-PtBuA.

5. The method according to claim 1 wherein said acrylic monomer is an alkyl acrylate or an alkyl methacrylate, said alkyls being linear or branched C₁ to C₁₈ alkyls, or a mixture of said monomers.

6. The method according to claim 1 wherein the acrylic polymer is a copolymer of at least one acrylic monomer and a difunctional monomer.

7. The method according to claim 6 wherein the difunctional monomer is butanediol dimethacrylate (BDMA).

8. The method according to claim 1 wherein the block copolymer is present in an amount between 1 and 50% by weight based on the monomer.

9. The method according to claim 1 wherein the solvent is an alcohol, a mixture of alcohols, or an alcohol-rich medium.

10. The method according to claim 9 wherein said solvent is ethanol.

11. The method according to claim 1 wherein said free-radical polymerization is carried out in the presence of an initiator belonging to the family of azo compounds and peroxides.

12. The method according to claim 11 wherein said initiator is azobisisobutyronitrile or benzoyl peroxide.

13. The method according to claim 1 wherein said polymerization comprises sequential steps of preparing a seed followed by gradually adding the remaining reactants.

14. A microdispersion of acrylic particles obtained by the method according to claim 1.

15. A method for making a microgel comprising the steps of:

drying or concentrating a microdispersion obtained by the method of claim 1; and

then combining the dried or concentrated microdispersion with a solvent for PMMA to form a microgel.

20. A cosmetic composition comprising a microdispersion of acrylic particles obtained by the method according to claim 1.

23. A nail polish composition comprising a microdispersion of acrylic particles obtained by the method according to claim 1.

16. A microgel made by a process comprising the steps of:

(a) forming a stable microdispersion of particles of acrylic polymers in an organic solvent wherein said acrylic polymer is formed by a free-radical polymerization of at least one acrylic monomer in the presence of a block copolymer, said block copolymer being a copolymer of polymethyl methacrylate (PMMA) and polytert-butyl acrylate (PtBuA);

(b) drying or concentrating said stable microdispersion of particles, and then transferring said dried or concentrated stable microdispersion of particles to a solvent for PMMA to form a microgel; and

(c) recovering said microgel.

17. The microgels according to claim 16 wherein said solvent for PMMA is selected from the group comprising aromatic solvents, chlorinated solvents such as chloroform or methylene chloride, ketones and esters such as a C₂ to C₄ alkyl acetate.

18. The microgels according to claim 16 wherein said solvent for PMMA is butyl acetate or ethyl acetate.

19. The microgels according to claim 16 wherein the concentration by weight of polymer in the solvent for PMMA is less than 30%.

21. A cosmetic composition comprising a microgel according to claim 16.

22. The composition according to claim 21 wherein it contains less than 30% by weight of said microgel.

24. A nail polish composition comprising a microgel according to claim 16.