Method and material for the detection of ionizing radiation

• US 5,712,166 A
• Filed: 05/28/1996
• Issued: 01/27/1998
• Est. Priority Date: 12/10/1993
• Status: Expired due to Fees

• Current Assignee: Nuclear Decommissioning Authority
• Original Assignee: British Nuclear Technology
• Inventors: Broan, Christopher J.
• Primary Examiner(s): SNAY, JEFFREY R
• Application Number:
  US08/647,991
• Time in Patent Office: 609 Days
• Field of Search: 436/57, 436/58, 436/171, 436/172, 436/902, 250/370.07, 250/390.03, 250/484.5, 422/82.08
• US Class Current: 436/58
• CPC Class Codes: G01T 1/04 Chemical dosimeters G01T1/06, G01T1/08 take precedence
• CPC Class Codes: G01T 1/204 the detector being a liquid
• CPC Class Codes: Y10S 436/902 Dosimeter

Abstract

A method and materials are described for the monitoring of ionizing radiation in a location or on a person. The method comprises providing a fluorescent organic sensor material in the location where monitoring is required, the fluorescent organic sensor material having a molecular structure comprising at least one pair of fluorophore units, the units being held together by a spacer unit such that they are capable of interacting to produce a distinct fluorescence spectrum different from those of the individual fluorophore units; exposing the sensor material to the radiation; and determining any change in the fluorescence spectrum of the sensor material after exposure.

Claims

1. A method of detecting ionizing radiation, the method comprising the steps of providing a fluorescent organic sensor material in the location where detecting is required, the fluorescent organic sensor material having a molecular structure comprising at least one pair of fluorophore units, the fluorophore units being held together by a spacer unit such that they are capable of interacting to produce a distinct fluorescence spectrum different from those of the individual fluorophore units, said distinct spectrum being responsive to said ionizing radiation;

exposing said fluorescent organic sensor material to said radiation; and

determining any change in the fluorescence spectrum of said fluorescent organic sensor material after said exposure.

2. A method according to claim 1 wherein the fluorescent sensor material is employed in a form chosen from the group consisting of a solid film, a solution, and a gel.

3. A method according to claim 1 wherein the fluorescent sensor material is provided in the form of a personal dosimeter.

4. A method according to claim 1 wherein the fluorescent sensor material is used for the classification of radioactive waste into low, medium or high level.

5. A method according to claim 4 wherein the radioactive waste is immersed in the sensor material.

6. A method according to claim 1 wherein the fluorescent sensor material is used for the determination of position and degree of surface contamination during decommissioning.

7. A method according to claim 1 wherein the fluorescent sensor material is used to verify an applied radiation dose.

8. A method according to claim 7 wherein the dose verification is in radiosterilization of medical equipment or preparation of irradiated foodstuffs.

9. A method according to claim 1 wherein the fluorescent sensor material is used as a neutron detector.

10. A synthesized organic fluorescent sensor material for use in the detection of ionizing radiation, the organic fluorescent material having a molecular structure comprising at least one pair of fluorophore unit molecules, the fluorophore units being held together by a spacer unit molecule such that the fluorophore unit molecules are capable of interacting to produce a distinct fluorescence spectrum different from that of the individual fluorophore units, said sensor material being susceptible to damage from ionizing radiation.

11. An organic sensor material according to claim 10 wherein said fluorophore units are the same.

12. An organic sensor material according to claim 10 wherein the fluorophore unit molecules are dyestuffs.

13. An organic sensor material according to claim 10 wherein the spacer unit molecule possesses one or more chemical bonds particularly prone to damage by radiation.

14. An organic sensor material according to claim 10 wherein the sensor material molecule comprises two pairs of fluorophore units in each molecule, each pair being bonded to a common spacer unit.

15. An organic sensor material according to claim 10 wherein the fluorophore unit is chosen from the group consisting of pyrene, anthracene, anthraquinone, napthalene and derivatives thereof.

16. An organic sensor material according to claim 10 wherein the fluorophore units are heterocyclic compounds.

17. An organic sensor material according to claim 16 wherein the fluorophore units are selected from the group consisting of acridine, napthylimide or diimide, dibenzofuran, xanthene, carbazole, phenoxazole, phenothiazine and coumarin.

18. An organic sensor material according to claim 10 wherein the spacer unit is chosen from the group consisting of 4, 5-disubstituted xanthenes, cis-1, 3-disubstituted cyclohexanes and compounds derived therefrom.

19. An organic sensor material according to claim 10 wherein the fluorophores are linked by two or more flexible chains.

20. An organic sensor material according to claim 19 wherein the flexible chains are catenanes.

21. An organic sensor material according to claim 10 wherein the spacer unit holds the fluorophore units in a substantially constant relative orientation.

22. An organic sensor material according to claim 10 wherein the sensor material is contained in a solvent medium to produce a solution or a gel.

23. An organic sensor material according to claim 10 wherein the molecule further includes an element having a high neutron capture cross section.

24. An organic sensor material according to claim 22 wherein the medium in which the sensor material is contained includes an element having a high neutron capture cross section.

25. An organic sensor material according to claim 23 wherein the element is either boron or gadolinium.