Hair cosmetic containing a cationic surfactant, fat and oil and an alkyl saccharide surfactant

• US 5,714,136 A
• Filed: 02/06/1995
• Issued: 02/03/1998
• Est. Priority Date: 10/22/1991
• Status: Expired due to Term

• Current Assignee: KAO Corporation
• Original Assignee: KAO Corporation
• Inventors: Tashiro, Kazuhiro, Eshita, Yoshiyuki, Sazanami, Fumiko, Ohtomo, Tsuyoshi, Yahagi, Kazuyuki, Kamegai, Jun, Koyama, Takashi
• Primary Examiner(s): LANE, SALLY GARDNER
• Application Number:
  US08/384,802
• Time in Patent Office: 1,093 Days
• Field of Search: 424/70.19, 424/70.28, 424/70.31, 424/70.12, 424/70.1, 424/70.122
• US Class Current: 424/70.19
• CPC Class Codes: A61K 2800/412 Microsized, i.e. having sizes between 0.1 and 100 microns
• CPC Class Codes: A61K 2800/596 Mixtures of surface active compounds
• CPC Class Codes: A61K 8/31 Hydrocarbons
• CPC Class Codes: A61K 8/342 Alcohols having more than seven atoms in an unbroken chain
• CPC Class Codes: A61K 8/375 the alcohol moiety containing more than one hydroxy group
• CPC Class Codes: A61K 8/416 Quaternary ammonium compounds A61K8/35 takes precedence
• CPC Class Codes: A61K 8/604 Alkylpolyglycosides; Derivatives thereof, e.g. esters
• CPC Class Codes: A61Q 5/006 Antidandruff preparations
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners

Abstract

A hair cosmetic is disclosed which comprises the following components (A), (B) and (C):

(A) a cationic surfactant;

(B) a fat and/or an oil; and

(C) an alkyl saccharide surfactant represented by the following formula (1):

R.sup.1 --O--(R.sup.2 O).sub.m --G.sub.n                   (1)

wherein the weight ratio of (A)/(C) is from 1 to 20. A hair cosmetic which further comprises fine particles of an average particle size of 100 μm or below as the component (D) is also disclosed. The hair cosmetic of the present invention gives a good smoothness, a good elasticity and an oil-free feel to the hair without imparting any sticky feel or dry and loose feel thereto.

Claims

1. A hair cosmetic, consisting essentially of the following components (A), (B), and (C):

(A) 0.1 to 20% by weight, based on the total weight of said composition, of a quaternary ammonium salt having the formula (2) or (3);

##STR19## wherein at least one of R³, R⁴, R⁵ and R⁶ represents an alkyl or alkenyl group having 8 to 28 carbon atoms in total and which is unsubstituted or substituted by an alkoxyl, alkenyloxy, alkanoylamino or alkenoylamino group, and the others each represent a benzyl group or an alkyl or hydroxyalkyl group having 1 to 5 carbon atoms;

R⁷ represents an alkylene group having 2 or 3 carbon atoms;

X₁^- and X₂^- each represents a halogen ion or an organic ion;

v and v'"'"' each represents an integer of from 1 to 20; and

at least one of R⁸ and R⁹ represents an alkyl or alkenyl group having 8 to 28 carbon atoms in total and which is unsubstituted or substituted by an alkoxyl, alkenyloxy, alkanoylamino or alkenoylamino group, and each of the others represents a benzyl group or an alkyl or hydroxyalkyl group having 1 to 5 carbon atoms;

(B) 0.5 to 20% by weight, based on the total weight of said composition, of a fat or oil or both in combination, selected from the group consisting Of fatty alcohols, hydrocarbon oils, lanolin, lanolin fatty acids, fatty acid esters, fatty acids, alkyl or alkenylamide amines and mixtures thereof; and

(C) an alkyl saccharide surfactant represented by the following formula (1);

space="preserve" listing-type="equation">R.sup.1 --O--(R.sup.2 O).sub.m --G.sub.n (

     1)

wherein

R¹ represents a straight chain or branched chain alkyl, alkenyl or alkylphenyl group having 8 to 18 carbon atoms;

R² represents an alkylene group having 2 to 4 carbon atoms;

m represents a number of 0 to 4;

G represents a reducing sugar having 5 or 6 carbon atoms; and

n represents a number of 1 to 10;

wherein the weight ratio of component (A) to (C) is from 1 to 20.

2. The hair cosmetic of claim 1, which further comprises the following component (D):

(D) fine particles of an average particle size of 100 μ

m or below,

wherein the weight ratio of component (A) to component (D) is from 1 to 20.

3. The hair cosmetic of claim 1, wherein said quaternary ammonium salt is selected from the group consisting of dialkyldimethylammonium chlorides having an alkyl group of 8 to 16 carbon atoms and having a branching ration of 10 to 50% by mol.

4. The hair cosmetic of claim 1, wherein said quaternary ammonium salt is selected from the group consisting of 2-decyltetradecyltrimethylammonium chloride, 2-dodecylhexadecyltrimethylammonium chloride, di-2-hexyldecyldimethylammonium chloride and di-2-octyldodecyldimethylammonium chloride.

5. The hair cosmetic of claim 1, wherein said quaternary ammonium salt has the formula:

##STR20## wherein R¹⁸ represents a group of the formula;

##STR21## wherein s represents an integer of from 2 to 14, and t represents an integer of from 3 to 11, and wherein the sum of s and t is 15;

or an alkyl group of 1 to 3 carbon atoms; and

R¹⁹ and R²⁰ each represents a benzyl group or an alkyl or hydroxyalkyl group having 1 to 3 carbon atoms; and

X₅^- represents a halogen ion or an organic ion.

6. The hair cosmetic of claim 1, wherein said fat or oil is selected from the group consisting of monoglycerides of saturated and unsaturated, straight-chain or branched fatty acids having 12 to 24 carbon atoms, higher alcohols having straight-chain and branched alkyl and alkenyl group(s) having 12 to 26 carbon atoms.

7. The hair cosmetic of claim 1, wherein for said alkyl saccharide surfactant, R¹ represents an alkyl group having 8 to 12 carbon atoms;

and G is selected from the group consisting of glucose, galactose and fructose.

8. The hair cosmetic of claim 2, wherein said particles of (D) are made of material selected from the group consisting of nylon, polyethylene, polyester, polypropylene, polystyrene, polyurethane, polyamide, epoxy resins, urea resins, acryl polymers, silicone resins, talc, kaolin, mica, bentonite, sericite, selenium desulfide and zinc pyrithione.

9. The hair cosmetic of claim 1, which further comprises the following component (E):

(E) 0.05 to 20% by weight, based on the total weight of said composition, of a silicone compound selected from the group consisting of;

(a) compounds of the following formula (7);

space="preserve" listing-type="equation">(CH.sub.3).sub.3 SiO (CH.sub.3).sub.2 SiO!.sub.n1 Si(CH.sub.3).sub.3(

     7)

wherein n1 is an integer of 3 to 9,000;

(b) compounds of the following formula (8);

##STR22## wherein a, b and c are numbers the sum of which exceeds 1, provided that c is not 0 when b is 0 and b is not 0 when c is 0, and further provided that the sum of a, b and c is 20,000 or less;

(c) compounds of the following formula (9);

space="preserve" listing-type="equation">(R'"'"'.sub.d A.sub.(3-d))--Si--(OSi(A).sub.2).sub.n2 -- OSi(A.sub.e R'"'"'.sub.(2-e))!.sub.n3 --OSi(R'"'"'.sub.d A.sub.(3-d)) (9)

wherein

A represents a hydrogen atom or a group selected from the group consisting of a phenyl group, a hydroxyl group and an alkyl group having 1 to 8 carbon atoms;

d is an integer of from 0 to 3;

e is 0 or 1;

n2 is an integer of from 0 to 1,999;

n3 is an integer of from 1 to 2,000, provided that the sum of n2 and n3 is an integer of from 1 to 2,000; and

R'"'"' is a group --C_f H_2f L, wherein f is an integer of from 2 to 8; and

L is selected from the group consisting of;

##STR23## wherein Z represents a hydrogen atom or a group selected from the group consisting of a phenyl group, a benzyl group and an alkyl group having 1 to 20 carbon atoms; and

B^- represents Cl^-, Br^-, I^- or F^- ;

(d) compounds of the following formula (10);

##STR24## wherein g, h and i are each a number of from 1 to 350;

j is a number of from 0 to 10; and

R²² represents an alkyl group having 9 to 21 carbon atoms;

(e) compounds of the following formulae (11-a) or (11-b);

##STR25## wherein k is a number of from 1 to 500; and

R²³ and R^23'"'"' represent each a single bond or an alkylene group having 1 to 4 carbon atoms;

(f) compounds of the following formula (12);

##STR26## wherein m1, o and q1 are each a number the sum of which is from 1 to 300;

r is a number of from 0 to 5; and

R²⁴ represents an alkyl group having 4 to 22 carbon atoms;

(g) compounds of the following formulae (13) to (16);

##STR27## wherein R²⁵ represents a group --(CH₂)_z1 --O--(C₂ H₄ O)_x1 --(C₃ H₆ O)_y1 --A₁, wherein A₁ represents an alkyl group having 1 to 12 carbon atoms or a hydrogen atom;

x1 is a number of from 0 to 50;

y1 is a number of from 0 to 50, provided that the sum of x1 and y1 is 1 or above;

z1 is a number of from 0 to 10;

m2 is a number of from 1 to 2,000; and

n4 is a number of from 1 to 1,000;

(h) compounds of the following formula (17);

##STR28## wherein α

is a number of from 1 to 500;

β

is a number of from 1 to 50; and

R²⁶ is an alkylene group having 1 to 3 carbon atoms;

(i) compounds of the following formula (18);

##STR29## wherein γ

is a number of from 1 to 400;

(j) compounds of the following formula (19);

##STR30## wherein δ

is a number of from 3 to 8; and

R²⁷ represents an alkyl group having 1 to 3 carbon atoms; and

(k) compounds of the following formulae (20-a) or (20-b);

##STR31## wherein ε and

ζ

are each a number of from 1 to 500;

R²⁸ represents an alkyl group having 2 to 18 carbon atoms;

R²⁹ represents a single bond or an alkylene group having 1 to 4 carbon atoms; and

R³⁰ represents an alkyl group having 10 to 16 carbon atoms.

10. The hair cosmetic of claim 2, which further comprises the following component (E):

(E) 0.05 to 20% by weight, based on the total weight of said composition, of a silicone compound selected from the group consisting of;

(a) compounds of the following formula (7);

space="preserve" listing-type="equation">(CH.sub.3).sub.3 SiO (CH.sub.3).sub.2 SiO!.sub.n1 Si(CH.sub.3).sub.3(

     7)

wherein n1 is an integer of 3 to 9,000;

(b) compounds of the following formula (8);

##STR32## wherein a, b and c are numbers the sum of which exceeds 1, provided that c is not 0 when b is 0 and b is not 0 when c is 0, and further provided that the sum of a, b and c is 20,000 or less;

(c) compounds of the following formula (9);

space="preserve" listing-type="equation">(R'"'"'.sub.d A.sub.(3-d))--Si--(OSi(A).sub.2).sub.n2 -- OSi(A.sub.e R'"'"'.sub.(2-e))!.sub.n3 --OSi(R'"'"'.sub.d A.sub.(3-d)) (9)

wherein

A represents a hydrogen atom or a group selected from the group consisting of a phenyl group, a hydroxyl group and an alkyl group having 1 to 8 carbon atoms;

d is an integer of from 0 to 3;

e is 0 or 1;

n2 is an integer of from 0 to 1,999;

n3 is an integer of from 1 to 2,000, provided that the sum of n2 and n3 is an integer of from 1 to 2,000; and

R'"'"' is a group --C_f H_2f L, wherein f is an integer of from 2 to 8; and

L is selected from the group consisting of;

##STR33## wherein Z represents a hydrogen atom or a group selected from among a phenyl group, a benzyl group and an alkyl group having 1 to 20 carbon atoms; and

B^- represents Cl^-, Br^-, I^- or F^- ;

(d) compounds of the following formula (10);

##STR34## wherein g, h and i are each a number of from 1 to 350;

j is a number of from 0 to 10; and

R²² represents an alkyl group having 9 to 21 carbon atoms;

(e) compounds of the following formulae (11-a) or (11-b);

##STR35## wherein k is a number of from 1 to 500; and

R²³ and R^23'"'"' represent each a single bond or an alkylene group having 1 to 4 carbon atoms;

(f) compounds of the following formula (12);

##STR36## wherein m1, o and q1 are each a number the sum of which is from 1 to 300;

r is a number of from 0 to 5; and

R²⁴ represents an alkyl group having 4 to 22 carbon atoms;

(g) compounds of the following formulae (13) to (16);

##STR37## wherein R²⁵ represents a group --(CH₂)_z1 --O--(C₂ H₄ O)_x1 --(C₃ H₆ O)_y1 --A₁, wherein A₁ represents an alkyl group having 1 to 12 carbon atoms or a hydrogen atom;

x1 is a number of from 0 to 50;

y1 is a number of from 0 to 50, provided that the sum of x1 and y1 is 1 or above;

z1 is a number of from 0 to 10;

m2 is a number of from 1 to 2,000; and

n4 is a number of from 1 to 1,000;

(h) compounds of the following formula (17);

##STR38## wherein α

is a number of from 1 to 500;

β

is a number of from 1 to 50; and

R²⁶ is an alkylene group having 1 to 3 carbon atoms;

(i) compounds of the following formula (18);

##STR39## wherein γ

is a number of from 1 to 400;

(j) compounds of the following formula (19);

##STR40## wherein δ

is a number of from 3 to 8; and

R²⁷ represents an alkyl group having 1 to 3 carbon atoms; and

(k) compounds of the following formulae (20-a) or (20-b);

##STR41## wherein ε and

ζ

are each a number of from 1 to 500;

R²⁸ represents an alkyl group having 2 to 18 carbon atoms;

R²⁹ represents a single bond or an alkylene group having 1 to 4 carbon atoms; and

R³⁰ represents an alkyl group having 10 to 16 carbon atoms.