Resolution of immixtures of stereoisomeric alcohols
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1. A process for the resolution of immixture of stereoisomeric alcohols, comprising selectively enzymatically acylating one of the stereoisomers thereof, in the presence of a hydrolase, in a biphasic hydroorganic reaction medium, and thence separating the alcohol stereoisomer from the ester stereoisomer thus formed.
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Abstract
Immixture of stereoisomeric alcohols is resolved by selectively enzymatically acylating one of the stereoisomers thereof, in the presence of a catalytically effective amount of a hydrolase, for example a lipase, esterase or acylase, in a biphasic hydroorganic reaction medium, and thence separating the alcohol stereoisomer from the ester stereoisomer thus formed.
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31 Claims
- 1. A process for the resolution of immixture of stereoisomeric alcohols, comprising selectively enzymatically acylating one of the stereoisomers thereof, in the presence of a hydrolase, in a biphasic hydroorganic reaction medium, and thence separating the alcohol stereoisomer from the ester stereoisomer thus formed.
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