Electrochemical sensors for gas detection

• US 5,716,506 A
• Filed: 10/06/1995
• Issued: 02/10/1998
• Est. Priority Date: 10/06/1995
• Status: Expired due to Fees

• Current Assignee: Board of Trustees of The University of Illinois
• Original Assignee: Board of Trustees of The University of Illinois
• Inventors: Keyvani, Darioush, Lee, Sung B., Maclay, G. Jordan
• Primary Examiner(s): Tung, T.
• Application Number:
  US08/540,005
• Time in Patent Office: 858 Days
• Field of Search: 204/421-429
• US Class Current: 204/424
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors
• CPC Class Codes: G01N 27/4045 for gases other than oxygen

Abstract

Amperometric electrochemical sensors for detection of an analyte gas in air are disclosed. The sensors can be used in a gas detector to detect the analyte gas and to compensate for the relative humidity and temperature of the air. In addition, an electrochemical sensor having high surface area electrodes, and an increased sensitivity, is disclosed.

Claims

1. An electrochemical sensor to detect the presence and concentration of carbon monoxide in air, said sensor comprising:

(a) a substrate;

(b) a working electrode deposited on a surface of the substrate;

(c) a counter electrode deposited on a surface of the substrate; and

(d) a film of a polymer electrolyte applied over the working and counter electrodes, wherein the sensor is free of a reference electrode and wherein the working electrode comprises a first layer of gold, platinum, or carbon in contact with the substrate, said first layer having a thickness of about 250 to about 5000 Å

, and a second high surface area layer of platinum in contact with the first layer.

2. The sensor of claim 1 wherein the substrate comprises silicon dioxide, alumina, or a polymer.

3. The sensor of claim 1 wherein the second high surface area layer is electrodeposited on the first layer.

4. The sensor of claim 1 wherein the film of polymer electrolyte is about 0.1 to about 5 micrometers thick.

5. The sensor of claim 1 having a sensitivity to carbon monoxide up to about 40 times greater than a sensor containing two low surface area working and counter electrodes.

6. The sensor of claim 1 wherein the counter electrode is a high surface area electrode.