Process for the production of a two-coat finish on a substrate surface

• US 5,716,678 A
• Filed: 11/17/1995
• Issued: 02/10/1998
• Est. Priority Date: 03/31/1993
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Bartelt, Angelika, Stubbe, Wilfried, Rockrath, Ulrike, Betz, Peter, Wigger, Georg, Bartol, Fritz
• Primary Examiner(s): DUDASH, DIANA L
• Application Number:
  US08/525,631
• Time in Patent Office: 816 Days
• Field of Search: 427/379, 427/407.1, 427/409, 524/548, 524/561, 524/590, 524/839, 525/127, 525/440, 525/457, 525/458, 528/45, 528/66
• US Class Current: 427/407.1
• CPC Class Codes: B05D 7/532 the two layers being cured or baked together, i.e. wet on wet
• CPC Class Codes: C08L 61/20 Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen with aminophenols C08L61/04
• CPC Class Codes: C09D 133/066 containing -OH groups

Abstract

A process is disclosed for producing a double-layered covering lacquer by using a transparent covering lacquer containing a hydroxyl group-containing polyacrylate resin produced by polymerizing (a) 10 to 51% by weight 4-hydroxy-n-butylacrylate or 4-hydroxy-n-butylmethacrylate or a mixture of 4-hydroxy-n-butylacrylate and 4-hydroxy-n-butylmethacrylate; (b) 0 to 36% by weight of a hydroxyl group-containing ester of acrylic acid different from (a) or a hydroxyl group-containing ester of methacrylic acid or a mixture of such monomers; (c) 28 to 85% by weight of an aliphatic or cycloaliphatic ester of methacrylic acid different from (a) and (b) with at least 4 C atoms in the alcohol residue or a mixture of such monomers; (d) 0 to 3% by weight of an ethylenically unsaturated carboxylic acid or a mixture of ethylenically unsaturated carboxylic acids and (e) 0 to 20% by weight of an ethylenically unsaturated monomer different from (a), (b), (c) and (d) or a mixture of such monomers, into a polyacrylate resin with a hydroxyl number from 60 to 200, an acid number from 0 to 35 and a number average molecular weight from 1,500 to 10,000. The sum of the parts by weight of components (a), (b), (c), (d) and (e) is always 100% by weight and the composition of the component (c) is selected so that when said component (c) is polymerized alone, a polymethacrylate resin having a glass transition temperature from +10° to +10° C. is obtained.

Claims

1. A process for the production of a two-coat finish on a substrate surface, comprising the steps of:

(1) applying a pigmented basecoat to the substrate surface,

(2) drying the basecoat film applied in step (1),

(3) applying to the basecoat film dried in step (2) a nonaqueous, transparent topcoat comprising

(A) a hydroxyl group-containing polyacrylate resin and

(B) a crosslinking agent, wherein the crosslinking agent is a mixture of at least one amino resin and a member selected from the group consisting of blocked polyisocyanates, unblocked polyisocyanates, and mixtures thereof, and

(4) baking and curing the basecoat and the topcoat together, wherein the hydroxyl group-containing polyacrylate resin of the nonaqueous, transparent topcoat is obtained by polymerizing

(a) from 10 to 51% by weight of a compound selected from the group consisting of 4-hydroxy-n-butyl acrylate, 4-hydroxy-n-butyl methacrylate, and mixtures thereof,

(b) from 0 to 36% by weight of a compound selected from the group consisting of hydroxyl group-containing esters of acrylic acid, hydroxyl group-containing esters of methacrylic acid, and mixtures thereof, wherein the compound is different from (a),

(c) from 28 to 85% by weight of a compound selected from the group consisting of aliphatic esters of methacrylic acid, cycloaliphatic esters of methacrylic acid, and mixtures thereof, wherein the compound is different from (a) and (b) and has at least 4 carbon atoms in the alcohol radical,

(d) from 0 to 3% by weight of a compound selected from the group consisting of ethylenically unsaturated carboxylic acids and mixtures thereof, and

(e) from 0 to 20% by weight of a compound selected from the group consisting of ethylenically unsaturated monomers which are different from (a), (b), (c) and (d), and mixtures thereof,

to give a polyacrylate resin having a hydroxyl number of from 60 to 200, an acid number of from 0 to 35, and a number-average molecular weight of from 1500 to 10,000, the sum of the proportions by weight of components (a), (b), (c), (d), and (e) always being 100% by weight, and the composition of component (c) being selected such that the polymethacrylate resin resulting from homopolymerization of component (c) has a glass transition temperature of from +10°

to +100°

C.

3. A process according to claim 1, wherein component (e) is selected such that the polymer resulting from homopolymerization of component (e) has a glass transition temperature of from +70°

to +120°

C.

4. A process according to claim 1 wherein the hydroxyl group-containing polyacrylate resin is obtained by polymerizing from 25 to 41% by weight of component (a), from 0 to 20% by weight of component (b), from 40 to 70% by weight of component (c), from 0 to 2% by weight of component (d), and from 5 to 15% by weight of component (e) to give a polyacrylate resin having a hydroxyl number of from 100 to 160, an acid number of from 0 to 25, and a number-average molecular weight of from 2500 to 5000, the composition of component (c) being chosen such that the polymethacrylate resin resulting from homopolymerization of component (c) has a glass transition temperature of from +20°

to +60°

C., and component (e) being selected such that the polymer resulting from homopolymerization of component (e) has a glass transition temperature of from +80°

to +100°

C.

2. A nonaqueous coating composition comprising

(A) a hydroxyl group-containing polyacrylate resin and

(B) a crosslinking agent, wherein the crosslinking agent is a mixture of at least one amino resin and a member selected from the group consisting of blocked polyisocyanates, unblocked polyisocyanates, and mixtures thereof,

wherein component (A) is a hydroxyl group-containing polyacrylate resin that is obtained by polymerizing

(a) from 10 to 51% by weight of a compound selected from the group consisting of 4-hydroxy-n-butyl acrylate, 4-hydroxy-n-butyl methacrylate, and mixtures thereof,

(b) from 0 to 36% by weight of a compound selected from the group consisting of a hydroxyl group-containing ester of acrylic acid, hydroxyl group-containing ester of methacrylic acid, and mixtures thereof, wherein the compound is different from (a),

(c) from 28 to 85% by weight of a compound selected from the group consisting of an aliphatic ester of methacrylic acid, a cycloaliphatic ester of methacrylic acid, and mixtures thereof, wherein the compound is different from (a) and (b) and has at least 4 carbon atoms in the alcohol radical,

(d) from 0 to 3% by weight of a compound selected from the group consisting of ethylenically unsaturated carboxylic acids and mixtures thereof, and

(e) from 0 to 20% by weight of a compound selected from the group consisting of ethylenically unsaturated monomers which are different from (a), (b), (c), and (d), and mixtures thereof, to give a polyacrylate resin having a hydroxyl number of from 60 to 200, an acid number of from 0 to 35, and a number-average molecular weight of from 1500 to 10,000, the sum of the proportions by weight of components (a), (b), (c), (d), and (e) always being 100% by weight, and the composition of component (c) being selected such that the polymethacrylate resin resulting from homopolymerization of component (c) has a glass transition temperature of from +10°

to +100°

C.

5. A coating composition according to claim 2, wherein component (e) is selected such that the polymer resulting from homopolymerization of component (e) has a glass transition temperature of from +70°

to +120°

C.

6. A coating composition according to claim 2, wherein the hydroxyl group-containing polyacrylate resin is obtained by polymerizing from 25 to 41% by weight of component (a), from 0 to 20% by weight of component (b), from 40 to 70% by weight of component (c), from 0 to 2% by weight of component (d), and from 5 to 15% by weight of component (e) to give a polyacrylate resin having a hydroxyl number of from 100 to 160, an acid number of from 0 to 25, and a number-average molecular weight of from 2500 to 5000, the composition of component (c) being chosen such that the polymethacrylate resin resulting from homopolymerization of component (c) has a glass transition temperature of from +20°

to +60°

C., and component (e) being selected such that the polymer resulting from homopolymerization of component (e) has a glass transition temperature of from +80°

to +100°

C.