Anti-fouling self-polishable paints

• US 5,717,007 A
• Filed: 01/19/1996
• Issued: 02/10/1998
• Est. Priority Date: 01/26/1995
• Status: Expired due to Term

• Current Assignee: ETAT Francais As Represented By The Delegue General Pour L'Armement
• Original Assignee: ETAT Francais As Represented By The Delegue General Pour L'Armement
• Inventors: Cambon, Christian
• Primary Examiner(s): MERRIAM, ANDREW EDWIN
• Application Number:
  US08/588,886
• Time in Patent Office: 753 Days
• Field of Search: 524/398, 524/399, 524/248, 524/249, 524/174, 524/176, 524/520, 524/523, 523/122, 523/177
• US Class Current: 523/122
• CPC Class Codes: C09D 5/1625 organic
• CPC Class Codes: C09D 5/1668 Vinyl-type polymers

Abstract

The invention relates to anti-fouling self-polishable paints intended to bepplied on an object at least partially submersed, notably on surface ships or submarine hulls, and containing standard constituents of the paints such as organic solvents, coloring pigment, wetting agents, dispersing agents or neutralizing agents.

These paints are characterized in that they comprise:

mass 5 to 60% of at least two polymers or copolymers (I) of the alkyl polyacrylates or alkyl polymethacrylate family comprising carboxylic functions, having molecular weights ranging from 15,000 to 100,000 g.mol^-1, each polymer having a very different acid index,

mass 0.1 to 50% of at least one polyaminated compound (II) reacting to polymers (I),

mass 0.1 to 60% of at least one organometallic compound derived from zinc, iron, manganese or cobalt, with a biocide character (III).

mass 0 to 30% of powdered hydrophobe polymers (IV).

Claims

1. Anti-fouling self-polishable paints intended to be applied on an object at least partially submersed, comprising at least one of organic solvents, colouring pigment, wetting agents, dispersing agents and neutralising agents, the paints further comprising:

mass 5 to 60% of at least two polymers (I) of an alkyl polyacrylate or alkyl polymethacrylate family, each of the at least two polymers (I) comprising carboxylic functions and having a very different acid index;

mass 0.1 to 50% of at least one polyaminated compound (II), the compound (II) being chemically linked with the at least two polymers (I);

mass 0.1 to 60% of at least one organometallic compound (III) comprising at least one of zinc, iron, manganese or cobalt, the organometallic compound (III) having a biocide character; and

mass 0 to 30% of powdered hydrophobe polymers (IV).

2. Anti-fouling self-polishable paints according to claim 1, wherein a first polyacrylate or polymethacrylate of the at least two polymers (I) has an acid index higher than 50, and a second polyacrylate or polymethacrylate of the at least two polymers (I) has an acid index ranging from 2 to 50.

3. Anti-fouling self-polishable paints according to claim 1, wherein an ester function of the at least two polymers (I) has a carbon number of between 1 and 4.

4. Anti-fouling self-polishable paints according to claim 3, wherein the ester function of the at least two polymers (I) is a linear alkyl.

5. Anti-fouling self-polishable paints according to claim 1, wherein the compound (II) has a boiling temperature higher than 100°

C.

6. Anti-fouling self-polishable paints according to claim 1, wherein the compound (II) has a chemical structure of the following type:

##STR2## where R1 to R6 are alkyls and n is a positive whole number.

7. Anti-fouling self-polishable paints according to claim 6, wherein the compound (II) is Tri-(DiMethylaminoMethyl)-2, 4, 6-phenol, R1 to R6 are methyl groups and n 1.

8. Anti-fouling self-polishable paints according to claim 1, wherein the compound (II) has a cycloaliphatic chemical structure of the following type:

##STR3## where R1 to R6 are alkyls and n is a positive whole number.

9. Anti-fouling self-polishable paints according to claim 1, wherein the hydrophobe polymers are fluorated polyolefines.

11. Anti-fouling self-polishable paints according to claim 2, wherein a third polyacrylate or polymethacrylate of the at least two polymers (I) has an acid index ranging from 0 to 2.

12. Anti-fouling self-polishable paints according to claim 6, wherein at least one of R1 to R6 is methyl.

13. Anti-fouling self-polishable paints according to claim 6, wherein at least one of R1 to R6 is ethyl.

14. Anti-fouling self-polishable paints according to claim 8, wherein at least one of R1 to R6 is methyl.

15. Anti-fouling self-polishable paints according to claim 8, wherein at least one of R1 to R6 is ethyl.

10. Anti-fouling self-polishable paints intended to be applied on an object at least partially submersed, comprising at least one of organic solvents, colouring pigments, wetting agents, dispersing agents and neutralising agents, the paints being in a form of dry film after application on a surface and further comprising:

mass 10 to 90% of at least two polymers (I) of an alkyl polyacrylate or alkyl polymethacrylate family, each polymer of the at least two polymers (I) comprising carboxylic functions and having a very different acid index;

mass 1 to 50% of at least one polyaminated compound (II), the compound (II) being chemically linked with the at least two polymers (I);

mass 1 to 60% of at least one organometallic compound (III) comprising at least one of zinc, iron, manganese or cobalt, the organometallic compound (III) having a biocide character; and

mass 0 to 20% of powdered hydrophobe polymers (IV).