Laser-inscribable polymer moulding compositions

• US 5,717,018 A
• Filed: 09/12/1996
• Issued: 02/10/1998
• Est. Priority Date: 09/21/1995
• Status: Expired due to Term

• Current Assignee: Lanxess Deutschland GmbH (Lanxess AG)
• Original Assignee: Bayer AG
• Inventors: Gerling, Frank, Magerstedt, Herbert, El-Sayed, Aziz
• Primary Examiner(s): Hoke, Veronica P.
• Application Number:
  US08/713,242
• Time in Patent Office: 516 Days
• Field of Search: 524/413, 524/417, 524/414, 524/418, 524/406, 524/606, 524/412, 523/136, 523/135, 523/137, 523/138
• US Class Current: 524/413
• CPC Class Codes: B41M 5/267 Marking of plastic artifacts, e.g. with laser
• CPC Class Codes: C08K 3/30 Sulfur-, selenium- or tellurium-containing compounds
• CPC Class Codes: C08K 3/32 Phosphorus-containing compounds

Abstract

A thermoplastic molding composition, containing

A) 99.95 to 30 parts by weight of thermoplastic polymer,

B) 0 to 3 parts by weight of copper pyrophosphate hydrate,

C) 0 to 3 parts by weight of copper(II) hydroxide phosphate,

D) 0 to 3 parts by weight of manganese sulphate hydrate,

E) 0 to 50 parts by weight of fillers and reinforcing materials,

F) 0 to 60 parts by weight of flame retardant additives,

G) 0 to 30 parts by weight of elastomeric modifiers,

H) 0 to 8 parts by weight of antimony trioxide,

wherein at least one of the components B) or D) is contained in the mixture.

Claims

1. A thermoplastic molding composition, comprising

A) 99.95 to 30 parts by weight of thermoplastic polymer,

B) 0.05 to 2.5 parts by weight of copper pyrophosphate hydrate,

C) 0 to 3 parts by weight of copper (II) hydroxide phosphate,

E) 0 to 50 parts by weight of fillers and reinforcing materials,

F) 0 to 60 parts by weight of flame retardant additives,

G) 0 to 30 parts by weight of elastomeric modifiers,

H) 0 to 8 parts by weight of antimony trioxide,

wherein component A) comprises at least one polymer or copolymer selected from the group consisting of a polyalkylene terephthalate, an aromatic polyester, a polyamide, a polycarbonate, a polyacrylate. a polymethacrylate, an ABS graft polymer, a polyolefine, a polystyrene, a polyoxymethylene, a polyimide, a polyether and a polyether ketone.

2. A thermoplastic molding composition according to claim 1, wherein component F) comprises at least one compound selected from the group consisting of magnesium hydroxide, calcium magnesium carbonate hydrate, one or more halogenated compounds, and antimony oxide.

3. A thermoplastic molding composition according to claim 2, wherein said one or more halogenated compounds are selected from the group consisting of ethylene-1,2-bistetrabromophthalimide, epoxidised tetrabromobisphenol A resin, tetrabromobisphenol A oligocarbonate, tetrachlorobisphenol A oligocarbonate, pentabromopolyacrylate, brominated polystyrene and one or more organic phosphorus compounds.

4. A method of using the molding composition according to claim 1, comprising the step of inserting the molding composition into a mold to produce a molded body.

5. Moldings produced from the thermoplastic molding composition according to claim 1.

6. A thermoplastic molding composition according to claim 1, wherein component A) is a polyolefin.

7. A thermoplastic molding composition according to claim 6, wherein component A) is polyethylene or polypropylene.

8. A thermoplastic molding composition according to claim 1, wherein component A) is thermoplastic polymer based on a polyalkylene terephthalate.

9. A thermoplastic molding composition according to claim 8, wherein component A) is polybutylene terephthalate.

10. A thermoplastic molding composition according to claim 1, wherein the amount of component B) in said composition is 0.5 to 2.5 parts by weight.

11. A thermoplastic molding composition, comprising 99.95 to 30 parts by weight of thermoplastic polymer, 0.05 to 2.5 parts by weight of copper pyrophosphate hydrate, 0 to 3 parts by weight of copper (II) hydroxide phosphate, 0 to 50 parts by weight of fillers and reinforcing materials, 0 to 60 parts by weight of flame retardant additives, 0 to 30 parts by weight of elastomeric modifiers, and 0 to 8 parts by weight of antimony trioxide, wherein the thermoplastic polymer is a blend of at least two polymers or copolymers selected from the group consisting of a polyalkylene terephthalate, an aromatic polyester, a polyamide, a polycarbonate, a polyacrylate, a polymethacrylate, an ABS graft polymer, a polyolefine, a polystyrene, a polyoxymethylene, a polyimide, a polyether and a polyether ketone.

12. A thermoplastic molding composition according to claim 11, wherein the amount of copper pyrophosphate hydrate in said composition is 0.5 to 2.5 parts by weight.

13. A thermoplastic molding composition, comprising

A) 99.95 to 30 parts by weight of thermoplastic polymer,

B) 1 to 3 parts by weight of copper pyrophosphate hydrate,

C) 0 to 3 parts by weight of copper (II) hydroxide phosphate,

E) 0 to 50 parts by weight of fillers and reinforcing materials,

F) 0 to 60 parts by weight of flame retardant additives,

G) 0 to 30 parts by weight of elastomeric modifiers,

H) 0 to 8 parts by weight of antimony trioxide,

wherein component A) comprises at least one polymer or copolymer selected from the group consisting of a polyalkylene terephthalate, an aromatic polyester, a polyamide, a polycarbonate, a polyacrylate, a polymethacrylate, an ABS graft polymer, a polyolefine, a polystyrene, a polyoxymethylene, a polyimide, a polyether and a polyether ketone.

14. A thermoplastic molding composition according to claim 13, wherein component A) comprises a blend of at least two polymers or copolymers selected from the group consisting of a polyalkylene terephthalate, an aromatic polyester, a polyamide, a polycarbonate, a polyacrylate, a polymethacrylate, an ABS graft polymer, a polyolefine, a polystyrene, a polyoxymethylene, a polyimide, a polyether and a polyether ketone.