Process and device for liquefying and for processing a natural gas

• US 5,718,126 A
• Filed: 10/08/1996
• Issued: 02/17/1998
• Est. Priority Date: 10/11/1995
• Status: Expired due to Term

• Current Assignee: Institut Francais Du Petrole (IFP Energies Nouvelles)
• Original Assignee: Institut Francais Du Petrole (IFP Energies Nouvelles)
• Inventors: Rojey, Alexandre, Capron, Pierre
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US08/727,778
• Time in Patent Office: 497 Days
• Field of Search: 62/613, 62/614
• US Class Current: 62/613
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0035 by gas expansion with extraction of work
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/0042 by liquid expansion with extraction of work
• CPC Class Codes: F25J 1/0052 by vaporising a liquid refrigerant stream
• CPC Class Codes: F25J 1/0055 originating from an incorporated cascade
• CPC Class Codes: F25J 1/0212 as a single flow MCR cycle
• CPC Class Codes: F25J 1/0214 as a dual level refrigeration cascade with at least one MCR cycle
• CPC Class Codes: F25J 1/0219 in combination with an internal quasi-closed refrigeration loop, e.g. using a deep flash recycle loop
• CPC Class Codes: F25J 1/0262 Details of the cold heat exchange system constructional details F25J5/00, construction of cold-exchangers in general F28
• CPC Class Codes: F25J 1/0292 Refrigerant compression by cold or cryogenic suction of the refrigerant gas
• CPC Class Codes: F25J 2200/80 using integrated mass and heat exchange, i.e. non-adiabatic rectification in a reflux exchanger or dephlegmator
• CPC Class Codes: F25J 2205/50 using absorption, i.e. with selective solvents or lean oil, heavier CnHm and including generally a regeneration step for the solvent or lean oil
• CPC Class Codes: F25J 2220/64 Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
• CPC Class Codes: F25J 2220/68 Separating water or hydrates
• CPC Class Codes: F25J 2230/60 the fluid being hydrocarbons or a mixture of hydrocarbons
• CPC Class Codes: F25J 2245/02 Recycle of a stream in general, e.g. a by-pass stream
• CPC Class Codes: F25J 2290/44 Particular materials used, e.g. copper, steel or alloys thereof or surface treatments used, e.g. enhanced surface
• CPC Class Codes: F25J 5/007 combined with mass exchange, i.e. in a so-called dephlegmator

Abstract

A fluid consisting at least partly of a mixture of hydrocarbons is liquefied by means of the following stages:

the mixture under pressure is cooled so as to condense it at least partly to produce a liquid phase and a gas phase, and bringing into contact of at least a fraction of each of said phases is simultaneously achieved at least partly in a countercurrent flow so as to obtain, by matter transfer, a gas phase enriched in light hydrocarbons and a first liquid phase enriched in heavy hydrocarbons, and

the two phases obtained thereby are separated and the gas phase enriched in light hydrocarbons is sent to a second cooling stage in order to obtain a second liquid phase enriched in light hydrocarbons.

Claims

1. A process for liquefying a fluid consisting at least partly of a mixture of hydrocarbons, comprising:

introducing said mixture into a first zone;

cooling said mixture in said first zone under pressure to condense said mixture at least partly to produce a liquid phase and a gas phase, bringing into contact at least a fraction of said liquid phase and gas phase in a countercurrent flow in said first zone so as to obtain, by matter transfer, a gas phase enriched in light hydrocarbons and a first liquid phase enriched in heavy hydrocarbons; and

sending the gas phase enriched in light hydrocarbons to a second cooling stage and cooling the gas phase enriched in light hydrocarbons so as to obtain a second liquid phase enriched in light hydrocarbons.

2. A process as claimed in claim 1, wherein, in said first zone, the gas phase ascends and is contacted with the liquid phase which descends.

3. A process as claimed in claim 1, wherein the cooling performed in the first zone is provided by an at least partly continuous countercurrent heat exchange over at least part of the zone of contact.

4. A process as claimed in claim 1, wherein in the first zone, at least two different liquid fractions are separated at different levels.

5. A process as claimed in claim 1, wherein the cooling in the first zone and in the second cooling stage are performed by means of two different cooling cycles operating each with a cooling mixture.

6. A process as claimed in claim 1, wherein the cooling in the first zone and in the second cooling stage are performed by means of a single cooling cycle operating with a cooling mixture.

7. A process as claimed in claim 1, further comprising introducing a solvent into the first zone.

8. A process as claimed in claim 1, wherein the mixture comprises natural gas.

9. A process for liquefying a natural gas as claimed in claim 8, wherein the cooling required for liquefying the natural gas is obtained at least partly by vaporization of at least a liquid fraction of a mixture of hydrocarbons resulting from a liquefaction stage.

10. A plant for liquefying a fluid comprising at least partly a mixture of hydrocarbons, comprising:

a. precooler for at least partly condensing the fluid and for separating the fluid into a gas phase enriched in light hydrocarbons and a liquid phase enriched in heavy hydrocarbons, the precooler comprising at least one first passage having an inlet, a gas phase outlet and a liquid phase outlet, and at least one second passage in heat transfer relationship with the at least one first passage, wherein the at least one second passage, the at least one first passage and the inlet, gas phase outlet and liquid phase outlet thereof are arranged to at least partially condense the fluid in the at least one first passage and to provide direct contact in countercurrent flow between the gas phase and the condensed liquid phase;

at least one line for delivering the fluid to the inlet of the at least one first passage;

a source of cooling fluid connected to the inlet of the at least one second passage; and

a second cooling stage connected to the gas phase outlet of the at least one first passage for liquefying the gas phase enriched in light hydrocarbons.

11. A plant as claimed in claim 10, wherein said precooler comprises at least one draw-off means for drawing off liquid hydrocarbon fractions.

12. A plant as claimed in claim 11, comprising stabilization means for stabilizing said condensed liquid hydrocarbon fractions, said stabilization means being connected to said draw-off means.

13. A plant as claimed in claim 10, wherein said precooler comprises at least one injection means allowing injection of at least one fluid other than gas into said at least one first passage.

14. A plant as claimed in claims 10, wherein the precooler comprises a vertical plate exchanger in which the ascending gas to be processed and a liquid fraction flowing downwards by gravity are contacted.

15. A plant as claimed in claim 10, wherein the precooler comprises a brazed aluminum plate exchanger and the second cooling stage comprises a stainless steel plate exchanger.