Image forming process and printed article

• US 5,718,793 A
• Filed: 02/26/1996
• Issued: 02/17/1998
• Est. Priority Date: 02/28/1995
• Status: Expired due to Term

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Koike, Shoji, Inamoto, Tadayoshi, Ohta, Tokuya
• Primary Examiner(s): Hess, Bruce H.
• Application Number:
  US08/606,846
• Time in Patent Office: 722 Days
• Field of Search: 8/471, 428/195, 428/913, 428/914, 428/209-211, 428/423.1, 503/227, 503/201, 156/235, 347/105
• US Class Current: 156/235
• CPC Class Codes: B41J 2/01 Ink jet
• CPC Class Codes: B41M 5/0256 the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means
• CPC Class Codes: B41M 5/508 Supports
• CPC Class Codes: B41M 5/52 Macromolecular coatings
• CPC Class Codes: B41M 5/5281 Polyurethanes or polyureas
• CPC Class Codes: B41M 5/529 characterised by the use of fluorine- or silicon-containing organic compounds
• CPC Class Codes: B41M 7/0027 using protective coatings or layers by lamination or by fusion of the coatings or layers
• CPC Class Codes: B41M 7/0045 using protective coatings or film forming compositions cured by mechanical wave energy, e.g. ultrasonics, cured by electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams, or cured by magnetic or electric fields, e.g. electric discharge, plasma
• CPC Class Codes: B41M 7/0054 using protective coatings or film forming compositions cured by thermal means, e.g. infrared radiation, heat
• CPC Class Codes: B41M 7/0081 using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10S 428/914 Transfer or decalcomania
• CPC Class Codes: Y10T 428/24917 including metal layer
• CPC Class Codes: Y10T 428/24926 including ceramic, glass, porcelain or quartz layer
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

Abstract

Disclosed herein is an image forming process, comprising the steps of:

ejecting droplets of a liquid ink containing a disperse dye according to predetermined information to form an image on an ink-absorbent printing sheet;

bringing the printing sheet into close contact under heat with an ink-nonabsorbent base material having a receiving layer for receiving the disperse dye to diffuse the disperse dye into the receiving layer; and

separating the printing sheet from the base material,

wherein the receiving layer comprises a resin having a pencil hardness of H or harder as determined by the pencil hardness test in accordance with JIS K 5400.

Claims

1. An image forming process, comprising the steps of:

ejecting droplets of a liquid ink containing a disperse dye according to predetermined information to form an image on an ink-absorbent printing sheet;

bringing the printing sheet into close contact under heat with an ink-nonabsorbent base material having a receiving layer for receiving the disperse dye to diffuse the disperse dye into the receiving layer; and

separating the printing sheet from the base material,

wherein the receiving layer comprises a resin having a pencil hardness of H or harder as determined by the pencil hardness test in accordance with JIS K 5400.

2. The image forming process according to claim 1, wherein the resin is a reaction product of a polyisocyanate compound with a compound having active hydrogen in a molecule.

3. The image forming process according to claim 2, wherein the resin is a reaction product of a polyisocyanate compound with a polyhydroxy compound or an amino group-containing compound.

4. The image forming process according to any one of claims 1 to 3, wherein the receiving layer is formed on the base material under heating conditions of 100°

C. or lower for from 5 minutes to 2 hours and then of from 100°

to 250°

C. for from 5 minutes to 3 hours.

5. The image forming process according to claim 1, wherein the receiving layer contains a silane coupling agent in an amount ranging from 0.1 to 30% by weight based on the whole resin.

6. The image forming process according to claim 1, wherein the means for ejecting droplets of the liquid ink containing a disperse dye according to predetermined information is an ink-jet printing method.

7. The image forming process according to claim 6, wherein the ink-jet printing method is of a type that thermal energy is applied to ink to form ink droplets.

8. The image forming process according to claim 1, wherein the printing sheet is paper.

9. The image forming process according to claim 1, wherein the liquid ink is a water-based ink.

10. An image forming process, comprising the steps of:

ejecting droplets of a liquid ink containing a disperse dye according to predetermined information to form an image on an ink-absorbent printing sheet;

bringing the printing sheet into close contact under heat with an ink-nonabsorbent base material having a receiving layer for receiving the disperse dye to diffuse the disperse dye into the receiving layer; and

separating the printing sheet from the base material,

wherein the receiving layer comprises a resin the pencil hardness of which turns H or harder as determined by the pencil hardness test in accordance with JIS K 5400 by the step of the close contact under heat.

11. The image forming process according to claim 10, wherein the resin is a reaction product of a polyisocyanate compound with a compound having active hydrogen in a molecule.

12. The image forming process according to claim 11, wherein the resin is a reaction product of a polyisocyanate compound with a polyhydroxy compound or an amino group-containing compound.

13. The image forming process according to any one of claims 10 to 12, wherein the receiving layer is formed on the base material under heating conditions of 100°

C. or lower for from 5 minutes to 2 hours and then of from 100°

to 250°

C. for from 5 minutes to 3 hours.

14. The image forming process according to claim 10, wherein the receiving layer contains a silane coupling agent in an amount ranging from 0.1 to 30% by weight based on the whole resin.

15. The image forming process according to claim 10, wherein the means for ejecting droplets of the liquid ink containing a disperse dye according to predetermined information is an ink-jet printing method.

16. The image forming process according to claim 15, wherein the ink-jet printing method is of a type that thermal energy is applied to ink to form ink droplets.

17. The image forming process according to claim 10, wherein the printing sheet is paper.

18. The image forming process according to claim 10, wherein the liquid ink is a water-based ink.

19. An image forming material, comprising a base material selected from the group consisting of pottery, glass, ceramics and metals;

and a receiving layer provided on the base material comprising a resin having a pencil hardness of H or harder as determined by the pencil hardness test in accordance with JIS K 5400.

20. A printed article, comprising a base material selected from the group consisting of pottery, glass, ceramics and metals, on which a receiving layer comprising a resin having a pencil hardness of H or harder as determined by the pencil hardness test in accordance with JIS K 5400 is provided;

and an image formed with a disperse dye on the receiving layer.

21. A process for forming an image with an ink on a printing medium, comprising the steps of:

ejecting droplets of an ink containing a disperse dye according to predetermined information to form an image on an ink-absorbent printing medium;

bringing the printing medium into close contact under heat with an ink-nonabsorbent base material having a receiving layer for receiving the disperse dye, the pencil hardness of the receiving layer being H or harder, to transfer and diffuse the disperse dye to and into the receiving layer;

separating the printing medium from the base material;

overcoating at least a part of the receiving layer of the image formed article obtained by the preceding steps with a substantially transparent resin; and

then

curing the transparent resin.

22. The image forming process according to claim 21, wherein the means for ejecting droplets of the ink containing a disperse dye according to predetermined information is an ink-jet printing method.

23. The image forming process according to claim 22, wherein the ink-jet printing method is of a type that thermal energy is applied to ink to form ink droplets.

24. The image forming process according to claim 21, wherein the printing medium is paper.

25. The image forming process according to claim 21, wherein the ink is a water-based ink.

26. The image forming process according to claim 21, wherein the overcoating resin cured has a pencil hardness of 2H or harder as determined by the pencil hardness test in accordance with JIS K 5400.

27. The image forming process according to claim 21, wherein the overcoating resin has such transparency that rise in optical density after the application of the resin is 0.5 or lower.

28. The image forming process according to claim 21, wherein the layer of the overcoating resin has a thickness ranging from 0.1 to 50 μ

m.

29. The image forming process according to claim 21, wherein the method of curing the overcoat layer is a method by heating.

30. The image forming process according to claim 29, wherein the heat curing temperature is lower than a temperature at which the printing medium is heated to transfer and diffuse the disperse dye to and into the receiving layer.

31. The image forming process according to claim 21, wherein the method of curing the overcoat layer is a method by radiation exposure.

32. The image forming process according to claim 21, wherein the overcoat layer contains at least one adhesive selected from the group consisting of ultraviolet absorbents, ultraviolet screening agents and mildew-proofing agents.

33. A process for forming an image with an ink on a printing medium, comprising the steps of:

ejecting droplets of an ink containing a disperse dye according to predetermined information to form an image on an ink-absorbent printing medium;

bringing the printing medium into close contact under heat with an ink-nonabsorbent base material having a receiving layer for receiving the disperse dye, the pencil hardness of the receiving layer being H or harder, to transfer and diffuse the disperse dye to and into the receiving layer;

separating the printing medium from the base material;

subjecting the receiving layer of the image formed article obtained by the preceding steps to a surface treatment;

overcoating at least a part of the receiving layer thus surface-treated with a substantially transparent resin; and

then

curing the transparent resin.

34. The image forming process according to claim 33, wherein the means for ejecting droplets of the ink containing a disperse dye according to predetermined information is an ink-jet printing method.

35. The image forming process according to claim 34, wherein the ink-jet printing method is of a type that thermal energy is applied to ink to form ink droplets.

36. The image forming process according to claim 33, wherein the printing medium is paper.

37. The image forming process according to claim 33, wherein the ink is a water-based ink.

38. The image forming process according to claim 33, wherein the surface treatment of the receiving layer of the image formed article is a treatment by oxygen plasma.

39. The image forming process according to claim 33, wherein the surface treatment of the receiving layer of the image formed article is a treatment with ozone generated by ultraviolet-light irradiation in an oxygen-containing gas.

40. The image forming process according to claim 33, wherein the overcoating resin cured has a pencil hardness of 2H or harder as determined by the pencil hardness test in accordance with JIS K 5400.

41. The image forming process according to claim 33, wherein the overcoating resin has such transparency that rise in optical density after the application of the resin is 0.5 or lower.

42. The image forming process according to claim 33, wherein the layer of the overcoating resin has a thickness ranging from 0.1 to 50 μ

m.

43. The image forming process according to claim 33, wherein the method of curing the overcoat layer is a method by heating.

44. The image forming process according to claim 43, wherein the heat curing temperature is lower than a temperature at which the printing medium is heated to transfer and diffuse the disperse dye to and into the receiving layer.

45. The image forming process according to claim 33, wherein the method of curing the overcoat layer is a method by radiation exposure.

46. The image forming process according to claim 33, wherein the overcoat layer contains at least one adhesive selected from the group consisting of ultraviolet absorbents and ultraviolet screening agents.