Nonaggregating hydrocolloid microparticulates, intermediates therefor, and processes for their preparation

• US 5,718,969 A
• Filed: 08/25/1993
• Issued: 02/17/1998
• Est. Priority Date: 08/25/1993
• Status: Expired due to Term

• Current Assignee: FMC Corporation
• Original Assignee: FMC Corporation
• Inventors: Riley, Peter J., Sewall, Christopher J., Crosby, Guy A., Thomas, William R., Renn, Donald W., Dumont, Lisa E.
• Primary Examiner(s): LE, HOA T
• Application Number:
  US08/111,800
• Time in Patent Office: 1,637 Days
• Field of Search: 428/304.4, 428/306.6, 428/308.4, 428/402, 428/403, 428/407, 426/93, 426/96, 426/573, 426/574, 426/575, 426/577, 426/578, 426/655, 426/656, 426/804 D, 252/315.01, 252/315.1, 252/315.2, 252/91, 252/304, 106/169, 106/197.2
• US Class Current: 428/304.4
• CPC Class Codes: A23D 7/0056 Spread compositions
• CPC Class Codes: A23D 7/015 Reducing calorie content; Reducing fat content , e.g. "halvarines"
• CPC Class Codes: A23D 7/05 characterised by essential cooling
• CPC Class Codes: A23D 9/007 characterised by ingredients other than fatty acid triglycerides
• CPC Class Codes: A23L 19/115 Konjak; Konntaku
• CPC Class Codes: A23L 27/72 Encapsulation
• CPC Class Codes: A23L 29/212 Starch; Modified starch; Starch derivatives, e.g. esters or ethers containing starch hydrolysates, e.g. dextrin, A23L29/30
• CPC Class Codes: A23L 29/256 from seaweeds, e.g. alginates, agar or carrageenan
• CPC Class Codes: A23L 29/262 Cellulose; Derivatives thereof, e.g. ethers
• CPC Class Codes: A23P 10/30 Encapsulation of particles, e.g. foodstuff additives
• CPC Class Codes: A23P 10/35 with oils, lipids, monoglycerides or diglycerides
• CPC Class Codes: A23P 10/40 free-flowing powder or instant powder, i.e. powder which is reconstituted rapidly when liquid is added A23P10/20, A23P10/30 take precedence
• CPC Class Codes: Y10S 426/804 Low calorie, low sodium or hypoallergic
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]
• CPC Class Codes: Y10T 428/249955 Void-containing component partially impregnated with adjacent component
• CPC Class Codes: Y10T 428/249958 Void-containing component is synthetic resin or natural rubbers
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer

Abstract

Substantially dry, rehydratable, water-dispersible, gel-forming, porous hydrocolloid micro-particulates containing internally or internally and externally at least one water-soluble, non-gelling, hydration enhancing hydrocolloid, processes and intermediates for their preparation, and their uses.

Claims

1. Substantially dry, rehydratable, water-dispersible, gel-forming, porous hydrocolloid microparticulates comprising:

A) a gel-forming hydrocolloid which comprises the matrix of the porous microparticulates; and

B) at least one water-soluble, non-gelling, hydration-enhancing hydrocolloid;

wherein the component A) matrix contains component B) internally within its porous structure, and wherein component B) can also be present as a full or partial coating on the outer surfaces of the microparticulates.

2. The microparticulates of claim 1 in which the microparticulates when rehydrated have an average particle size diameter in the range of from about 0.1 to about 150 microns.

3. The microparticulates of claim 2 wherein the average particle size is from about 1 to about 50 microns.

4. The microparticulates of claim 2 wherein the average particle size is from about 10 to about 30 microns.

5. The microparticulates of claim 1 wherein the microparticulates are substantially spheroidal in shape.

6. The microparticulates of claim 1 wherein the gel-forming hydrocolloid is at least one of agar, agarose, algin, low methoxyl pectin, gellan, K-carrageenan, ι

-carrageenan, furcellaran, β

-carrageenan, curdlan, konjac glucomannan and derivatives thereof, chitosan, cellulose derivatives, starch, and gel-forming mixtures of the following;

xanthan/locust bean gum, locust bean gum/agar, cassia/agar, cassia/xanthan, carrageenan/locust bean gum, konjac/xanthan, konjac/carrageenan, or konjac/starch.

7. The microparticulates of claim 1 wherein the water-soluble, non-gelling, hydration enhancing hydrocolloid is at least one water-soluble form of a galactomannan, a glucomannan, a starch, a cellulose derivative, λ

-carrageenan, algin, pectin, xanthan, or a synthetic polymer.

8. The microparticulates of claim 7 wherein said water-soluble hydrocolloid is sodium carboxymethylcellulose.

9. The microparticulates of claim 1 wherein the gel-forming hydrocolloid is heat stable cold-melt konjac.

10. The microparticulates of claim 1 which also contain encapsulated therein at least one of a food additive, natural flavoring agent, antioxidant, acidulant, colorant, odorant, enzyme, fungicide, antibiotic, antibacterial agent, biocide, nutrient, hormone, cell, chromatography medium, agglutination medium for diagnostics, nephelometric enhancer, pharmaceutical active, immobilization matrix, herbicide, insecticide, pesticide, animal feed supplement, fertilizer, surfactant, detergent, or immunoassay reagent.

11. The microparticulates of claim 1 wherein the microparticulates also contain a food additive encapsulated therein.

12. A fat substitute composition comprising microparticulates of claim 1 in which the microparticulates are rehydrated.

13. In a comestible composition in which a water-in-oil or oil-in-water emulsion is present, the improvement wherein the microparticulates of claim 1 are rehydrated and are used partially or completely in place of the oil to reduce the fat content of the comestible.

14. The composition of claim 12 or 13 wherein the rehydrated microparticulates have an average particle size diameter in the range of from about 0.1 to about 150 microns.

15. The composition of claim 14 wherein the average particle size of the rehydrated microparticlulates is from about 1 to about 50 microns.

16. The composition of claim 12 or 13 wherein the gel-forming hydrocolloid of the microparticulates is at least one of agar, agarose, algin, low methoxyl pectin, gellan, K-carrageenan, ι

-carrageenan, furcellaran, β

-carrageenan, curdlan, konjac glucomannan and derivatives thereof, chitosan, cellulose derivatives, starch, and gel-forming mixtures of the following;

xanthan/locust bean gum, locust bean gum/agar, cassia/agar, cassia/xanthan, carrageenan/locust bean gum, konjac/xanthan, konjac/carrageenan, or konjac/starch.

17. A reduced fat or no fat comestible composition comprising microparticulates of claim 1 in which the microparticulates are rehydrated.

18. The composition of claim 12 or 17 wherein the rehydrated microparticulates have an average particle size of from about 10 to about 30 microns.

19. The composition of claim 12 or 17 wherein the water-soluble, non-gelling, hydration enhancing hydrocolloid of the microparticulates is at least one water-soluble form of a galactomannan, a glucomannan, a starch, a cellulose derivative, λ

-carrageenan, algin, pectin, xanthan, or a synthetic polymer.

20. The composition of claim 19 wherein said water-soluble hydrocolloid of the microparticulates is sodium carboxymethylcellulose.

21. The composition of claim 20 wherein the gel-forming hydrocolloid of the microparticulate is heat stable cold-melt konjac.

22. A method of reducing the fat content of a foodstuff comprising the steps of

(I) rehydrating dry microparticulates of claim 1, and

(II) adding the rehydrated microparticulates to the foodstuff in place of part or all of the fat content thereof to obtain a lower or no fat foodstuff.