Glass substrates covered with a stack of thin coatings, application to glazings having properties of reflecting in the infrared and/or properties in the field of solar radiation

• US 5,718,980 A
• Filed: 11/04/1996
• Issued: 02/17/1998
• Est. Priority Date: 02/11/1993
• Status: Expired due to Fees

• Current Assignee: Saint-Gobain Vitrage International
• Original Assignee: Saint-Gobain Vitrage International
• Inventors: Rondeau, Veronique, Koch, Stephanie, Guiselin, Olivier, Brochot, Jean-Pierre
• Primary Examiner(s): SPEER, TIMOTHY M
• Application Number:
  US08/742,691
• Time in Patent Office: 470 Days
• Field of Search: 428/432, 428/433, 428/434, 428/469, 428/472, 428/216, 428/428, 428/698, 428/699, 428/701, 428/702, 428/913, 359/360, 359/585, 359/589
• US Class Current: 428/428
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3613 Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3626 one layer at least containing a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant

Abstract

A transparent substrate provided with a covering multi-layer stack of thin coatings of which at least one is a metal coating (5) having low emissivity characteristics in the infrared positioned between two layers of the multi-layer stack, which are formed of a dielectric material, said multi-layer stack having at least one wetting layer below the metal coating (5), which wetting layer is based on tantalum oxide or niobium oxide.

Claims

1. A transparent coated substrate, comprising:

a) a transparent substrate;

b) a first thin layer of a metal oxide or metal nitride coating the substrate;

c) a wetting layer having a thickness of from 5 to 20 nm comprising a niobium oxide layer coating the metal oxide or metal nitride coating; and

d) a thin layer of a functional metal coating on the wetting layer, wherein said functional metal coating has low infrared emissivity.

2. The transparent coated substrate of claim 1, wherein the metal oxide or metal nitride is tin oxide, titanium oxide, silicon nitride, or combinations thereof.

3. The transparent coated substrate of claim 1, wherein said wetting layer further comprises a first metal or metal alloy coating on the niobium oxide layer.

4. The transparent coated substrate of claim 3, wherein the first metal or metal alloy coating is tin or nickel chromium alloy and has a thickness of from 0.3 to 4 nm.

5. The transparent coated substrate of claim 1, wherein the functional metal coating is a silver coating.

6. The transparent coated substrate of claim 1, wherein the functional metal coating is coated with a sacrificial coating of a second metal or metal alloy coating having a thickness of from 0.3 to 8 nm.

7. The transparent coated substrate of claim 6, wherein the sacrificial coating is a nickel-chromium alloy.

8. The transparent coated substrate of claim 6, wherein the sacrificial coating has a thickness of from 1 to 3 nm.

9. The transparent coated substrate of claim 1, wherein the functional metal coating has a thickness of from 7 to 12 nm.

10. The transparent coated substrate of claim 1, wherein the total thickness of the coatings between the substrate and the functional metal coating is from 30 to 60 nm.

11. The transparent coated substrate of claim 1, wherein the wetting layer has a thickness of from 5 to 30 nm.

12. The transparent coated substrate of claim 1, wherein the wetting layer has a thickness of about 10 nm.

13. The transparent coated substrate of claim 1, wherein the total thickness of the coatings above the functional metal coating is from 30 to 60 nm.

14. The transparent coated substrate of claim 1, comprising two functional metal coatings having low infrared emissivity.

15. The transparent coated substrate of claim 1, wherein the substrate is a glass substrate.

16. A transparent coated substrate, comprising:

a) a transparent substrate;

b) a first thin layer of a metal oxide or a metal nitride coating the substrate;

c) a wetting layer comprising a tantalum oxide layer coating the first thin layer; and

d) a thin layer of a functional metal coating on the wetting layer, wherein said functional metal coating has low infrared emissivity.

17. The transparent coated substrate of claim 16, wherein said wetting layer further comprises a tin or nickel chromium alloy coating on the tantalum oxide layer.

18. The transparent coated substrate of claim 16, wherein the first thin layer of a metal oxide or a metal nitride is a coating of tin oxide, titanium oxide, silicon nitride, or combinations thereof.

19. The transparent coated substrate of claim 16, comprising a coating of tin oxide and a coating of titanium oxide, silicon nitride, or combinations thereof, or a combination thereof, on the functional metal layer, or on a sacrificial coating that is coated on the functional metal layer.

20. The transparent coated substrate of claim 16, wherein the functional metal coating has a thickness of from 7 to 12 nm.

21. The transparent coated substrate of claim 16, wherein the functional metal coating is a silver coating.