Anti-static anti-reflection coating

• US 5,719,705 A
• Filed: 06/07/1995
• Issued: 02/17/1998
• Est. Priority Date: 06/07/1995
• Status: Expired due to Fees

• Current Assignee: Sola Optical USA, Inc.
• Original Assignee: Sola International, Inc. (Carl-Zeiss-Stiftung)
• Inventors: Machol, Steven N.
• Primary Examiner(s): Dzierzynski, Paul M.
• Assistant Examiner(s): Juba, Jr., John
• Application Number:
  US08/487,365
• Time in Patent Office: 986 Days
• Field of Search: 359/581, 359/582, 359/585, 359/507, 351/62, 427/164
• US Class Current: 359/581
• CPC Class Codes: B29D 11/00865 Applying coatings; tinting; colouring printing, marking or copying processes B41M; identification in general G09F3/00; producing decorative effects in general B44C; positioning or marking of lenses B24B13/0055
• CPC Class Codes: G02B 1/116 including electrically conducting layers
• CPC Class Codes: G02B 1/16 having an anti-static effect, e.g. electrically conducting coatings

Abstract

An anti-reflection coating that is soil resistant and easy to maintain is provided. The coating includes a multilayer film having alternating layers of high and low refractive index materials that comprise electrically conductive metal oxides. The film is formed by reacting metal with non-stoichiometric amounts of oxygen such that the coating has one or more layers of electrically conductive metal oxide material. The coating is particularly suited for ophthalmic applications.

Claims

1. A method of fabricating a high transmittance ophthalmic lens which comprises the steps of:

providing a transparent ophthalmic lens; and

forming, on a surface of said ophthalmic lens, a transparent, electrically conductive and substantially static resistant anti-reflection coating by reacting a metal with an effective non-stoichiometric amount of oxygen such that the coating comprises at least one layer of electrically conductive metal oxide material.

2. The method of claim 1 wherein the coating of the ophthalmic lens in the neutral state has an electric potential that is less than about 100 volts.

3. The method of claim 2 wherein the coating surface has an electric potential that is less than about 600 volts when measured immediately after being rubbed with a cloth.

4. The method of claim 3 wherein the coating surface has an electric potential that is less than about 100 volts within about 5 seconds of being rubbed by the cloth.

5. The method of claim 4 wherein the ophthalmic lens does not include a hydrophobic outer layer over the anti-reflection coating.

6. The method of claim 1 wherein said coating is formed by electron beam ion-assisted deposition.

7. A method of fabricating a high transmittance ophthalmic lens which comprises the steps of:

providing a transparent ophthalmic lens; and

forming, on a surface of said ophthalmic lens, a transparent, multilayer, substantially static resistant, anti-reflection coating wherein at least one layer is electrically conductive by reacting a metal with an effective non-stoichiometric amount of oxygen such that the coating comprises at least one layer of electrically conductive metal oxide material.

8. The method of claim 7 wherein each of the at least one electrically conductive layer is formed by electron beam evaporation whereby metal reacts with non-stoichiometric amounts of oxygen to form an electrically conductive metal oxide.

9. The method of claim 7 wherein each of the at least one electrically conductive layer is a high refractive index material that comprises niobium oxides.

10. The method of claim 7 wherein each of the at least one electrically conductive layer is a high refractive index material that comprises titanium oxides.

11. The method of claim 7 wherein the multilayer anti-reflection coating comprises alternating high and low refractive index materials such that each layer has a refractive index different from that of any adjoining layer, wherein the index of refraction of each low refractive index material is less than about 1.5 at a wavelength of about 550 nm, wherein the index of refraction of each high refractive index material is greater than about 2.0 at a wavelength of about 550 nm, and wherein at least one layer comprises an electrically conductive metal oxide material.

12. The method of claim 11 wherein the high refractive index material comprises titanium oxides and wherein the low refractive index material comprises silicon oxides.

13. The method of claim 11 wherein the high refractive index material comprises niobium oxides and wherein the low refractive index material comprises silicon oxides.

14. The method of claim 11 wherein the multilayer anti-reflection coating comprises:

(i) a first layer having an index of refraction from about 2.0 to about 2.55 and that is about 7 to about 15 nm thick;

(ii) a second layer having an index of refraction from about 1.38 to about 1.5 and that is about 15 to about 40 nm thick;

(iii) a third layer having an index of refraction from about 2.0 to about 2.55 and that is about 90 to about 130 nm thick; and

(iv) a fourth layer having an index of refraction from about 1.38 to about 1.5 and that is about 55 to about 105 nm thick, wherein the indices of refraction are measured at a reference wavelength of 550 nm.

15. The method of claim 14 wherein the third layer is electrically conductive.

16. The method of claim 11 further comprising the step of depositing an adhesion layer onto the ophthalmic lens surface prior to forming said multilayer anti-reflection coating thereon.

17. The method of claim 7 wherein the at least one electrically conductive layer is formed by reactive sputtering whereby metal reacts with non-stoichiometric amounts of oxygen.

18. The method of claim 7 wherein the coating has a thickness of about 200 to about 500 nm.

19. The method of claim 7 wherein the at least one conductive layer is formed by ion-assisted deposition.

20. The method of claim 7 wherein the at least one conductive layer is formed by electron beam ion-assisted deposition.

21. The method of claim 7 wherein the at least one conductive layer is formed by reactive sputtering.

22. A high transmittance ophthalmic lens comprising:

an ophthalmic lens substrate; and

a transparent, substantially static resistant multilayer film comprising alternating layers of high refractive index and low refractive index materials, wherein at least one layer of the multilayer film is electrically conductive wherein the multilayer film comprises alternating high and low refractive index materials such that each layer has a refractive index different from that of any adjoining layer, wherein the index of refraction of each low refractive index material is less than about 1.5 at a wavelength of about 550 nm, wherein the index of refraction of each high refractive index material is greater than about 2.0 at a wavelength of about 550 nm, and wherein said at least one electrically conductive layer comprise non-stoichiometric metal oxides.

23. The ophthalmic lens of claim 22 wherein the high refractive index material comprises niobium oxides.

24. The ophthalmic lens of claim 22 wherein the high refractive index material comprises titanium oxides.

25. The ophthalmic lens of claim 22 wherein the high refractive index material comprises titanium oxides and wherein the low refractive index material comprises silicon oxides.

26. The ophthalmic lens of claim 22 wherein the high refractive index material comprises niobium oxides and wherein the low refractive index material comprises silicon oxides.

27. The ophthalmic lens of claim 22 further comprises an adhesion layer interposed between the substrate and the multilayer film.

28. The ophthalmic lens of claim 22 wherein the multilayer film comprises:

(i) a first layer having an index of refraction from about 2.0 to about 2.55 and that is about 7 to about 15 nm thick;

(ii) a second layer having an index of refraction from about 1.38 to about 1.5 and that is about 15 to about 40 nm thick;

(iii) a third layer having an index of refraction from about 2.0 to about 2.55 and that is about 90 to about 130 nm thick; and

(iv) a fourth layer having an index of refraction from about 1.38 to about 1.5 and that is about 55 to about 105 nm thick, wherein the indices of refraction are measured at a reference wavelength of 550 nm.

29. The ophthalmic lens of claim 28 wherein the third layer is electrically conductive.

30. The ophthalmic lens of claim 28 further comprises an adhesion layer situated between the substrate surface and the multilayer film.

31. The ophthalmic lens of claim 28 wherein the multilayer film of the ophthalmic lens in the neutral state has an electric potential that is less than about 100 volts.

32. The ophthalmic lens of claim 31 wherein the multilayer film surface has an electric potential that is less than about 600 volts when measured immediately after being rubbed with a cloth.

33. The ophthalmic lens of claim 32 wherein the multilayer film surface has an electric potential that is less than about 100 volts within about 5 seconds of being rubbed by the cloth.

34. The ophthalmic lens of claim 33 wherein the ophthalmic lens does not include a hydrophobic outer layer over the multilayer film.

35. An ophthalmic lens fabricated by a process that comprises the steps of:

providing a transparent ophthalmic lens substrate; and

depositing, onto a surface of said substrate, a transparent, substantially static resistant multilayer anti-reflection coating wherein at least one layer is electrically conductive wherein the step of depositing said coating comprises reacting metal with an effective non-stoichiometric amount of oxygen to form a layer of electrically conductive metal oxide.

36. The lens of claim 35 wherein the layer of electrically conductive metal oxide is formed by electron beam evaporation.

37. The lens of claim 35 wherein the layer of electrically conductive metal oxide is formed by reactive sputtering.

38. The lens of claim 35 wherein the layer of electrically conductive metal oxide layer is formed by ion-assisted deposition.

39. The lens of claim 35 wherein the layer of electrically conductive metal oxide layer is formed by electron beam ion-assisted deposition.

40. An ophthalmic lens fabricated by a process that comprises the steps of:

providing a transparent ophthalmic lens substrate; and

depositing, onto a surface of said substrate, a transparent, substantially anti-static multilayer film comprising alternating layers of high refractive index and low refractive index materials wherein at least one layer is electrically conductive wherein the multilayer film comprises;

alternating high and low refractive index materials such that each layer has a refractive index different from that of any adjoining layer, wherein the index of refraction of each low refractive index material is less than about 1.5 at a wavelength of about 550 nm, wherein the index of refraction of each high refractive index material is greater than about 2.0 at a wavelength of about 550 nm.

41. The ophthalmic lens of claim 40 wherein the multilayer film of the ophthalmic lens in the neutral state has an electric potential that is less than about 100 volts.

42. The lens of claim 40 wherein the high refractive index material comprises titanium oxides and wherein the low refractive index material comprises silicon oxides.

43. The lens of claim 40 wherein the high refractive index material comprises niobium oxides and wherein the low refractive index material comprises silicon oxides.

44. The lens of claim 40 wherein the multilayer film comprises:

(i) a first layer having an index of refraction from about 2.0 to about 2.55 and that is about 7 to about 15 nm thick;

(ii) a second layer having an index of refraction from about 1.38 to about 1.5 and that is about 15 to about 40 nm thick;

(iii) a third layer having an index of refraction from about 2.0 to about 2.55 and that is about 90 to about 130 nm thick; and

(iv) a fourth layer having an index of refraction from about 1.38 to about 1.5 and that is about 55 to about 105 nm thick, wherein the indices of refraction are measured at a reference wavelength of 550 nm.

45. The lens of claim 44 wherein the third layer is electrically conductive.

46. The lens of claim 44 further comprising an adhesion layer situated between the substrate surface and the multilayer film.

47. The lens of claim 46 wherein the coating is formed by electron beam ion evaporation.