Electrodes for electrochemical cells and method of making same

• US 5,728,181 A
• Filed: 11/04/1996
• Issued: 03/17/1998
• Est. Priority Date: 11/04/1996
• Status: Expired due to Term

• Current Assignee: Amperex Technology Limited (TDK Corporation)
• Original Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Inventors: Wu, Han, Li, Changming, Lian, Ke Keryn, Jung, Richard H.
• Primary Examiner(s): NUZZOLILLO, MARIA
• Application Number:
  US08/743,610
• Time in Patent Office: 498 Days
• Field of Search: 429/127, 429/162, 429/215, 429/245, 429/212, 29/623.1, 29/623.5
• US Class Current: 29/623.5
• CPC Class Codes: H01G 9/042 characterised by the material H01G11/22 takes precedence
• CPC Class Codes: H01M 4/00 Electrodes
• CPC Class Codes: H01M 4/02 Electrodes composed of, or comprising, active material
• CPC Class Codes: H01M 4/66 Selection of materials
• CPC Class Codes: H01M 4/661 Metal or alloys, e.g. alloy coatings H01M4/669 take precedence
• CPC Class Codes: H01M 4/667 in the form of layers, e.g. coatings
• CPC Class Codes: H01M 4/668 Composites of electroconductive material and synthetic resins
• CPC Class Codes: H01M 4/669 Steels
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/49108 Electric battery cell making
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

An electrochemical cell is provided with a first and second electrode assemblies (10) (11), and an electrolyte (15) disposed therebetween. The electrodes may either be of the same or different materials and may be fabricated from ruthenium, iridium, cobalt, tungsten, vanadium, iron, molybdenum, nickel, silver, zinc, and combinations thereof. The electrode assemblies are fabricated by depositing a layer (16) of a conductive ink adhesive on a surface of a current collecting substrate (12). Thereafter, a layer of powdered active material (18) is impregnated onto the surface of the conductive ink layer.

Claims

1. An electrode for an electrochemical energy storage device comprising:

a current collecting substrate;

a layer of a conductive ink disposed on at least one major surface of said current collecting substrate, said conductive ink including a transference medium and a conducting medium; and

a layer of powdered electrode active material impregnated into the layer of conductive ink.

2. An electrode as in claim 1, wherein said current collecting substrate is fabricated of a material selected from the group of copper, nickel, silver, stainless steel, tin, lead, aluminum, and combinations thereof.

3. An electrode as in claim 1, wherein said transference medium is an adhesive conductive transference medium.

4. An electrode as in claim 1, wherein said transference medium is selected from the group of materials consisting of epoxy, polythiophene acrylate, phenol-formaldehyde, polyamides, and combinations thereof.

5. An electrode as in claim 1, wherein said conducting medium is loaded in said transference medium on the order of between 1 and 50 mg/cm².

6. An electrode as in claim 1, wherein said conducting medium is selected from the group of materials consisting of acetylene black, furnace black, ferrophosphide, metal carbides, metal oxides, metal sulfides, metal nitrides, and combinations thereof.

7. An electrode as in claim 1, wherein the electrode active material is selected from the group consisting of ruthenium, iridium, carbon platinum, cobalt, tungsten, vanadium, iron, nickel, molybdenum, silver, zinc, lead, manganese, alloys thereof, nitrides thereof, carbides thereof, sulfides thereof, oxides thereof, hydroxides thereof and combinations thereof.

8. An electrode as in claim 1, wherein the particle size of said powdered active material is between 1 and 100 μ

m.

9. An electrode as in claim 1, wherein said conductive ink layer is deposited on said substrate to a thickness of between 10 and 100 μ

m.

10. An electrode as in claim 1, wherein said conductive ink layer is deposited to a thickness of preferably between about 15 and 40 μ

m.

12. A method as in claim 10, wherein said current collecting substrate is fabricated of a material selected from the group of copper, nickel, silver, stainless steel, aluminum, lead, and combinations thereof.

13. A method as in claim 10, wherein said transference medium is an adhesive transference medium.

14. A method as in claim 10, wherein said transference medium is selected from the group of materials consisting of epoxy, polythiophene acrylate, phenol-formaldehyde, polyamides, and combinations thereof.

15. A method as in claim 10, wherein said conducting medium comprises between 1 and 50 mg/cm² weight percent of the conductive ink.

16. A method as in claim 10, wherein said conducting medium is selected from the group of materials consisting of acetylene black, furnace black, ferrophosphide, metal carbides, metal oxides, metal sulfides, metal nitrides, and combinations thereof.

17. A method as in claim 10, wherein the electrode active material is selected from the group consisting of ruthenium, iridium, platinum, cobalt, tungsten, vanadium, iron, nickel, molybdenum, silver, zinc, lead, manganese, alloys thereof, nitrides thereof, carbides thereof, sulfides thereof, oxides thereof, hydroxides thereof, and combinations thereof.

18. A method as in claim 10, wherein the particle size of said powdered active material is between 1 and 100 μ

m.

19. A method as in claim 10, wherein said conductive ink layer is deposited on said substrate to a thickness of between thickness of between 10 and 100 μ

m.

20. A method as in claim 10, wherein said conductive ink layer is deposited to a thickness of preferably between about 15 and 40 μ

m.

11. A method of fabricating an electrode for an electrochemical cell, said method comprising the steps of:

providing a current collecting substrate;

depositing a layer of a conductive ink on said current collecting substrate, said conductive ink including a transference medium and a conducting medium; and

impregnating said layer of conductive ink with a powdered electrode active material.