Method for capturing nitrogen from air using gas separation membrane

• US 5,730,780 A
• Filed: 10/15/1993
• Issued: 03/24/1998
• Est. Priority Date: 10/15/1993
• Status: Expired due to Fees

• Current Assignee: Lineboar, Inc.
• Original Assignee: Opus Services, Inc.
• Inventors: Booth, Ronald Earl III
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US08/137,633
• Time in Patent Office: 1,621 Days
• Field of Search: 95/45, 95/49-54, 96/7-14
• US Class Current: 95/51
• CPC Class Codes: B01D 2313/18 Specific valves
• CPC Class Codes: B01D 53/22 by diffusion manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00
• CPC Class Codes: B01D 63/02 Hollow fibre modules

Abstract

This invention comprises an improved process for generating Nitrogen from air in which a vacuum is placed on the permeate side of a gas separation membrane, usually of the polysulfone type, resulting in highly enhanced flow rates and nitrogen purity sufficient for oil and gas pipeline repair use and for use in grain silos.

Claims

1. A process for producing nitrogen gas from air at an enhanced flow rate wherein the oxygen content of the produced gas is 8% or less using a membrane separator, the process comprising:

(a) moving compressed air at a pressure from about 40 psig to about 120 psig into a membrane separator containing a plurality of hollow fiber membranes confined in a container, the separator being adapted to permit selectively the passage therethrough of oxygen, carbon dioxide and water vapor while restraining the passage of nitrogen;

(b) applying a vacuum to the permeate side of the separator of from about 3.4 psia to about 13.2 psia to provide an enhanced flow rate of nitrogen wherein the flow rate of nitrogen is at least twofold higher to fourfold higher than is observed without applied vacuum;

(c) collecting under pressure the resultant non-permeate gas from the membrane separator.

2. A process of claim 1 wherein the hollow fiber membrane separator is constructed of polysulfone polymer.

3. A process of claim 2 wherein the polysulfone polymer is coated with a silicone.

4. A process of claim 1 wherein the nitrogen content of the produced gas is 92% to 99%.