Extraction of metals using supercritical fluid and chelate forming legand
First Claim
1. A method for extracting a metalloid or metal species from a solid or liquid, comprising exposing the solid or liquid to a supercritical carbon dioxide fluid solvent and a halogenated β
- -diketone chelating agent for a sufficient period of time to form chelates between the agent and species that are solubilized in the supercritical fluid solvent.
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Accused Products
Abstract
A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent is described. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated β-diketone. In especially preferred embodiments the extraction solvent is supercritical carbon dioxide, and the chelating agent comprises a fluorinated β-diketone and a trialkyl phosphate, or a fluorinated β-diketone and a trialkylphosphine oxide. Although a trialkyl phosphate can extract lanthanides and actinides from acidic solutions, a binary mixture comprising a fluorinated β-diketone and a trialkyl phosphate or a trialkylphosphine oxide tends to enhance the extraction efficiencies for actinides and lanthanides. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The method is particularly useful for extracting actinides and lanthanides from acidic solutions. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.
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Citations
45 Claims
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1. A method for extracting a metalloid or metal species from a solid or liquid, comprising exposing the solid or liquid to a supercritical carbon dioxide fluid solvent and a halogenated β
- -diketone chelating agent for a sufficient period of time to form chelates between the agent and species that are solubilized in the supercritical fluid solvent.
- View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11)
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12. A method for extracting a metalloid or metal species from a solid or liquid, comprising exposing the solid or liquid to a supercritical fluid solvent containing a β
- -diketone chelating agent and a trialkyl phosphate or a trialkylphosphine oxide for a sufficient period of time to form chelates between the agent and species that are solubilized in the supercritical fluid solvent.
- View Dependent Claims (13, 14, 15, 16, 17, 18)
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19. A method for extracting metalloid or metal species from a solid or liquid comprising exposing the solid or liquid to supercritical carbon dioxide and ligand selected from the group consisting of fluorinated β
- -diketones, trialkyl phosphates, trialkylphosphine oxides, and mixtures thereof, the ligand forming chelates with the metal or metalloid species, the chelates being soluble in the carbon dioxide.
- View Dependent Claims (20, 21, 22, 23, 24, 25, 26, 27, 28, 29)
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30. A method for extracting metals or metalloids from an acidic aqueous solution comprising exposing the acidic aqueous solution to carbon dioxide and ligand selected from the group consisting of fluorinated β
- -diketones, trialkyl phosphates, trialkylphosphine oxides, and mixtures thereof, the ligand forming chelates with the species, the chelates being soluble in the carbon dioxide.
- View Dependent Claims (31, 32, 33, 34, 35, 36)
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37. An extraction solvent comprising a supercritical fluid and a halogenated β
- -diketone chelating agent.
- View Dependent Claims (38, 39, 40, 41, 42)
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43. A method for treating acidic waste material containing metalloid and metal waste species, comprising the steps of:
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providing a container of the acidic waste material; exposing the waste material in the container to carbon dioxide and a ligand selected from the group consisting of fluorinated β
-diketones, trialkyl phosphates, trialkylphosphine oxides and mixtures thereof, the waste species being soluble in the carbon dioxide such that the carbon dioxide solubilizes the waste species; andremoving the carbon dioxide and solubilized waste species from the container. - View Dependent Claims (45)
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44. The method according to 43 wherein the carbon dioxide is subcritical.
Specification