Thermoplastic three-dimensional fiber network

• US 5,731,062 A
• Filed: 12/22/1995
• Issued: 03/24/1998
• Est. Priority Date: 12/22/1995
• Status: Expired due to Term

• Current Assignee: North Carolina State University (University of North Carolina System)
• Original Assignee: Hoechst Celanese Corporation (Sanofi )
• Inventors: Kim, Dai W., Bessey, William Edward, Haas, Joseph Steven Wiley
• Primary Examiner(s): Loney, Donald
• Application Number:
  US08/577,655
• Time in Patent Office: 823 Days
• Field of Search: 428/174, 428/175, 428/166, 428/128, 428/212, 264/257, 264/258, 264/177, 442/181, 442/182, 442/189, 442/197, 442/304, 442/308
• US Class Current: 428/175
• CPC Class Codes: B29C 51/004 Textile or other fibrous material made from plastics fibres combined with plastic layers B29C51/145; compression moulding of reinforced plastic articles in matched moulds B29C70/46; using pressure difference B29C70/44
• CPC Class Codes: D04B 1/18 elastic threads
• CPC Class Codes: D04H 3/07 otherwise than in a plane, e.g. in a tubular way
• CPC Class Codes: D10B 2503/041 Carpet backings
• CPC Class Codes: D10B 2503/06 Bed linen
• CPC Class Codes: D10B 2505/08 Upholstery, mattresses
• CPC Class Codes: D10B 2505/10 Packaging, e.g. bags
• CPC Class Codes: Y10T 428/2457 Parallel ribs and/or grooves
• CPC Class Codes: Y10T 428/24636 Embodying mechanically interengaged strand[s], strand-portion[s] or strand-like strip[s] [e.g., weave, knit, etc.]
• CPC Class Codes: Y10T 428/24661 Forming, or cooperating to form cells
• CPC Class Codes: Y10T 442/3008 Woven fabric has an elastic quality
• CPC Class Codes: Y10T 442/3065 Including strand which is of specific structural definition
• CPC Class Codes: Y10T 442/313 Strand material formed of individual filaments having different chemical compositions
• CPC Class Codes: Y10T 442/425 Including strand which is of specific structural definition

Abstract

Three dimensional fiber networks which are semi-rigid and dimensionally stable are made from textile fabrics that have projections and optional depressions which are compressible and return to their original shape after being compressed. The fiber networks are made by the thermo-mechanical deformation of textile fabrics that are in turn made from thermoplastic fibers. The fiber networks have particular utility as cushioning and impact absorbing materials.

Claims

1. A three-dimensional fiber network consisting of a textile fabric having a multiplicity of compressible projections having a shape selected from the group consisting of cones, truncated cones, pyramids having polygonal bases, truncated pyramids having polygonal bases, cylinders, prisms, spherical elements, and mixtures thereof which return substantially to their original shape after being compressed by 50%, said textile fabric comprising thermoplastic filaments, said filaments having a diameter of at least about 0.1 mm, said filaments in said fabric crossing over one another at intersections, said filaments at said intersections not being bonded, wherein said textile fabric is selected from the group consisting of knit and woven fabrics.

2. The fiber network recited in claim 1, said projections having apex points or flat tops, wherein said apex points or flat tops define a surface.

3. The fiber network recited in claim 1, wherein said thermoplastic filaments are monofils.

4. The fiber network recited in claim 1, wherein said thermoplastic filaments consist essentially of a thermoplastic polymer having a melting temperature in the range of about 80°

C. to about 375°

C.

5. The fiber network recited in claim 1, wherein the apparent density of said fiber network is less than about 10% of the density of said thermoplastic fiber.

6. The fiber network recited in claim 4, wherein said thermoplastic polymer is selected from the group consisting of polyesters, polyamides, thermoplastic copolyetherester elastomers, poly(arylene sulfides), polyolefins, aliphatic-aromatic polyamides, polyacrylates, and thermoplastic liquid crystalline polymers.

7. The fiber network recited in claim 4, wherein said thermoplastic polymer is a thermoplastic copolyetherester elastomer comprising long chain ether ester units and short chain ester units joined head-to-tail through ester linkages.

8. The fiber network recited in claim 7 wherein said long chain ether ester units consist essentially of the residues of poly(tetramethylene oxide) glycol and terephthalic acid and said short chain ester units consist essentially of the residues of 1,4-butanediol and terephthalic acid.

9. The fiber network recited in claim 4, wherein said thermoplastic polymer is poly(ethylene terephthalate).

10. The fiber network recited in claim 4, wherein said thermoplastic polymer is selected from polypropylene, nylon 6, or nylon 66.

11. The fiber network recited in claim 1, wherein said network also comprises depressions.

12. The fiber network recited in claim 11, said depressions having apex points or flat tops, wherein said apex points or flat tops define a surface.

13. The fiber network recited in claim 1, said filaments having a diameter in the range of about 0.15 mm to about 0.7 mm.

14. The fiber network recited in claim 4, wherein said thermoplastic polymer contains a flame retardant.

15. The fiber network recited in claim 9, wherein said poly(ethylene terephthalate) comprises up to about 5% of monomer units that contain phosphorous.

16. The fiber network as recited in claim 1, wherein said thermoplastic filaments comprise multifilament yarns that have coalesced to form said thermoplastic filaments.

17. The fiber network as recited in claim 1, wherein said thermoplastic filaments do not include a thermoset resin.