Multi-gas sensor systems for automotive emissions measurement

• US 5,731,510 A
• Filed: 06/18/1996
• Issued: 03/24/1998
• Est. Priority Date: 06/24/1995
• Status: Expired due to Fees

• Current Assignee: Sun Electric UK Limited (Snap-On Incorporated)
• Original Assignee: Sun Electric UK Limited (Snap-On Incorporated)
• Inventors: Jones, Barbara L., Wylie, Thomas F., Peter, Kenneth W.
• Primary Examiner(s): Dombroske, George M.
• Application Number:
  US08/667,964
• Time in Patent Office: 644 Days
• Field of Search: 73/23.31, 73/23.32, 73/31.05, 73/31.06, 73/116, 73/117.2, 73/117.3, 73/118.1
• US Class Current: 73/23.31
• CPC Class Codes: G01N 2291/0217 Smoke, combustion gases
• CPC Class Codes: G01N 2291/0256 Adsorption, desorption, surface mass change, e.g. on biosensors
• CPC Class Codes: G01N 2291/0423 Surface waves, e.g. Rayleigh waves, Love waves
• CPC Class Codes: G01N 2291/0426 Bulk waves, e.g. quartz crystal microbalance, torsional waves
• CPC Class Codes: G01N 2291/106 one or more transducer arrays
• CPC Class Codes: G01N 29/022 Fluid sensors based on microsensors, e.g. quartz crystal-microbalance [QCM], surface acoustic wave [SAW] devices, tuning forks, cantilevers, flexural plate wave [FPW] devices microdevices per se B81B
• CPC Class Codes: G01N 29/228 related to high temperature conditions
• CPC Class Codes: G01N 33/0016 by regulating a physical variable, e.g. pressure or temperature
• CPC Class Codes: G01N 33/0031 comprising two or more sensors, e.g. a sensor array

Abstract

Gas analysis apparatus particularly applicable to the quantitative monitoring of individual gas components in automotive exhausts, and providing this function in a rapid-response and hand-held, low power consumption format, comprises an array of electrically responsive solid-state sensors to which the mixture of automotive gases to be analyzed is simultaneously fed. Monitoring the electrical response of the sensors enables a substantially instantaneous determination of the quantitative presence of individual components of the gas mixture.

Claims

1. Automotive emissions measurement apparatus for the analysis of a gas mixture comprising multiple gas components from an automotive internal combustion engine, the apparatus comprising:

(a) an array of individual electrically responsive non-electrolytic solid state sensor elements each responsive to contact with one of said gas components of said mixture, each of said sensor elements being adapted to respond to its one of said gas components by an electrically detectable change in an gas components by an electrically detectable change in an electrical or other physical parameter of said element enabling a quantitative determination of the presence of said component each of said sensor elements including a substrate selected from the group comprising quartz crystal and alumina and silica, said substrate having a gas-responsive coating thereon;

(b) electrical output means coupled to said array to enable the display of quantitative data derived from said sensor elements relating to said multiple gas components; and

(c) gas input and output means mounted in relation to said array for receiving said gas mixture and discharging it from the apparatus so that an input flow of said gas mixture is passed substantially simultaneously over all of said sensor elements in direct contact with each.

2. Apparatus according to claim 1, wherein said coating includes a polymer or a metal oxide or a metal or a fluorophore.

3. Apparatus according to claim 1, wherein said sensor elements are adapted to respond to their respective gas components by a change in conductance or resistance.

4. Apparatus according to claim 1, and further comprising at least one Peltier effect cooling element adapted to effect cooling of said apparatus and/or the gas mixture supplied to said sensor elements.

5. Apparatus according to claim 1, and further comprising a gas flow meter located upstream of said sensor elements and adapted to monitor the flow rate of gas supplied thereto, whereby constant volume sampling may be achieved.

6. A method for the analysis of a gas mixture including multiple gas components from an automotive internal combustion engine, the method comprising the steps of:

providing multiple non-electrolytic gas sensor elements respectively for said multiple gas components, each of said sensor elements including a substrate selected from the group comprising quartz crystal and alumina and silica, said substrate having a gas-responsive coating thereon, feeding said gas mixture substantially simultaneously into contact with all of said sensor elements, and determining the electrical response of individual ones of said sensor elements to their corresponding gas components to obtain quantitative data relating to said multiple gas components.