Glass pane with reflectance reducing coating

• US 5,733,660 A
• Filed: 05/19/1995
• Issued: 03/31/1998
• Est. Priority Date: 05/20/1994
• Status: Expired due to Fees

• Current Assignee: Central Glass Company Limited
• Original Assignee: Central Glass Company Limited
• Inventors: Takamatsu, Atsushi, Makita, Kensuke
• Primary Examiner(s): SPEER, TIMOTHY M
• Application Number:
  US08/445,138
• Time in Patent Office: 1,047 Days
• Field of Search: 428/426, 428/428, 428/432, 428/216, 428/34, 359/586, 359/587, 359/590, 296/84.1
• US Class Current: 428/426
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 17/42 at least one coating of an organic material and at least one non-metal coating
• CPC Class Codes: C03C 2218/365 Coating different sides of a glass substrate
• CPC Class Codes: G02B 1/111 using layers comprising organic materials
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick

Abstract

The invention relates to a reflectance-reducing glass pane which may be a laminated glass pane such as an automobile front windshield. The invention provides a reflectance-reducing glass pane including: a transparent glass substrate having first and second major surfaces opposed to each other; a first reflectance-reducing coating formed on the first major surface of the glass substrate; and a second reflectance-reducing coating formed on the second major surface of the glass substrate. The first coating has at least two metal-oxide layers which are different in refractive index. The second coating has a refractive index of up to 1.50 and is made of one selected from the group consisting of SiO₂ and a mixture of SiO₂ and another metal oxide. The reflectance-reducing glass pane optionally further includes a third water-repellent coating which is formed on the second coating. The third coating comprises a silane compound containing a polyfluoroalkyl group. The reflectance of the glass pane is substantially low, with respect to a visible light incident on the glass pane from a side of the first coating at an incidence angle within a range from 40 to 80 degrees.

Claims

1. A reflectance-reducing glass pane comprising:

a transparent glass substrate having first and second major surfaces opposed to each other;

a first reflectance-reducing coating formed directly on the first major surface of said glass substrate, said first coating having at least two metal-oxide layers which are different in refractive index; and

a surface reflectance-reducing coating formed directly on the second major surface of said glass substrate, said second coating having a refractive index within a range from 1.43 to 1.47 and a thickness within a range from 105-130 nm, and being made of a member selected from the group consisting of SiO₂ and a mixture of SiO₂ and another metal oxide.

2. A glass pane according to claim 1, wherein said second coating is a single layer.

3. A glass pane according to claim 1, wherein said glass substrate has a pair of glass plates which are bonded together with an interlayer film therebetween.

4. A glass pane according to claim 3, wherein the glass pane is a front windshield of an automobile, and wherein said first coating is on an interior side of the automobile and said second coating is on an exterior side of the automobile.

5. A glass pane according to claim 1, wherein said first coating is constructed such that, with respect to a visible light incident on the glass pane from a side of said first coating at a particular incidence angle, a reflectance of the glass pane is reduced.

6. A glass pane according to claim 5, wherein the particular incidence angle is within a range from 40 to 80 degrees, and wherein the reflectance of the glass pane is lower than a reflectance of the glass substrate without the first and second coatings, by 4.5-7.0%.

7. A glass pane according to claim 1, wherein said first and second coating are prepared by a sol-gel process using a solution containing at least one organic metal compound.

8. A glass pane according to claim 1, wherein the another metal oxide is at least one selected from TiO₂, ZrO₂, Al₂ O₃, B₂ O₃, SnO₂, In₂ O₃, Ta₂ O₃ and mixtures thereof.

9. A glass pane according to claim 1, wherein said first coating has first and second metal-oxide layers.

10. A glass pane according to claim 1, wherein said first coating has first, second and third metal-oxide layers.

11. A glass pane according to 1, wherein material of a top layer of said first coating is the same as material of said second coating.

12. A glass pane according to claim 1, further comprising a third water-repellent coating formed on the second coating, the third coating comprising a silane compound containing a polyfluoroalkyl group.

13. A reflectance-reducing glass pane comprising:

a transparent glass substrate having first and second major surfaces opposed to each other;

a first reflectance-reducing coating formed directly on the first major surface of said glass substrate, said first coating having at least two metal-oxide layers which are different in refractive index;

a second reflectance-reducing coating formed directly on the second major surface of said glass substrate, said second coating having a refractive index within a range from 1.43 to 1.47 and a thickness within a range from 105-130 nm, and being made of a member selected from the group consisting of SiO₂ and a mixture of SiO₂ and another metal oxide; and

a third water-repellent coating formed directly on the second coating, the third coating comprising a silane compound containing a polyfluoroalkyl group.

14. A glass pane according to claim 13, wherein the third coating has a thickness within a range from a thickness of monomolecular layer of the silane compound to a thickness of one hundred molecules of the silane compound.

15. A glass pane according to claim 13, wherein the second coating has a minutely rough surface having numerous micro-pits thereon.