Cleaning compositions including derivatized guar gum composition including nonionic and cationic groups which demonstrate excellent solution clarity properties

• US 5,733,854 A
• Filed: 10/25/1996
• Issued: 03/31/1998
• Est. Priority Date: 10/25/1996
• Status: Expired due to Term

• Current Assignee: Rhodia Operations (Solvac SA)
• Original Assignee: Rhone-Poulenc Inc. (Sanofi )
• Inventors: Chowdhary, Manjit Singh, Robinson, Fred
• Primary Examiner(s): Howard, Jacqueline V.
• Application Number:
  US08/736,866
• Time in Patent Office: 522 Days
• Field of Search: 510/121, 510/130, 510/221, 510/237, 510/337, 510/470, 424/70.13, 424/70.19
• US Class Current: 510/121
• CPC Class Codes: A61K 2800/5426 cationic
• CPC Class Codes: A61K 8/20 Halogens; Compounds thereof
• CPC Class Codes: A61K 8/737 Galactomannans, e.g. guar; Derivatives thereof
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners
• CPC Class Codes: C08B 37/0087 Glucomannans or galactomannans; Tara or tara gum, i.e. D-mannose and D-galactose units, e.g. from Cesalpinia spinosa; Tamarind gum, i.e. D-galactose, D-glucose and D-xylose units, e.g. from Tamarindus indica; Gum Arabic, i.e. L-arabinose, L-rhamnose, D-galactose and D-glucuronic acid units, e.g. from Acacia Senegal or Acacia Seyal; Derivatives thereof
• CPC Class Codes: C11D 3/227 with nitrogen-containing groups

Abstract

A detergent composition useful for cleaning and/or conditioning human hair or skin or cleaning dishes or clothing which contains NaCl or NH₄ Cl and further contains a nonionically and cationically derivatized polygalactomannan, the molecular substitution of the nonionic substituent being between about 0.4 and about 1.2 and the degree of substitution of the cationic substituent being between about 0.20 to about 1.0, said detergent composition having a viscosity of greater than about 500 centipoises and said composition having greater than 75% light transmission at a wavelength of from about 500-600 nanometers is provided. Also disclosed is the use of an amphoteric and nonionic substituted derivatized polygalactomannan for such uses.

Claims

1. A detergent composition useful for cleaning and/or conditioning human hair or skin or cleaning dishes or clothing which contains NaCl or NH₄ Cl and further contains a nonionically and cationically derivatized polygalactomannan, the molecular substitution of the nonionic substituent being between about 0.4 and about 1.2 and the degree of substitution of the cationic substituent being between about 0.20 to about 1.0, said detergent composition having a viscosity of greater than about 500 centipoises and said composition having greater than 75% light transmission at a wavelength of from about 500-600 nanometers.

2. The composition according to claim 1 which is selected from the group consisting of personal care compositions and industrial cleaning compositions.

3. The composition according to claim 2 comprising a personal care composition useful for cleaning and/or conditioning human hair or skin.

4. The composition according to claim 3 wherein the composition includes NaCl present in an amount of between about 0.5 and about 3.0 percent by weight of the composition.

5. The composition according to claim 1 wherein said nonionic substituent comprises hydroxyalkyl groups, wherein alkyl represents a straight or branched hydrocarbon moiety having between 1 and about 6 carbon atoms.

6. The composition according to claim 5 wherein said nonionic substituents are selected from the group consisting of hydroxyethyl and hydroxypropyl.

7. The composition according to claim 1 wherein said cationic groups are quaternary groups.

8. The composition according to claim 7 wherein said cationic substituents are of the formula ##STR2## wherein R₁ is a monohydroxylated or polyhydroxylated alkyl group containing between one and about six carbon atoms;

R₂ and R₃ are independently, alkyl groups containing between one and about six carbon atoms;

R₄ is an alkyl group containing between one and about 24 carbon atoms; and

X is a halide.

9. The composition according to claim 1 wherein said cationic substituents have a degree of substitution between about 0.23 and about 0.80.

10. The composition according to claim 1 wherein said nonionically and cationically derivatized polygalactomannan is present in an amount of about 0.1 and about 2.0 percent by weight of the composition.

11. The composition according to claim 1 having a greater than 90% light transmission at a wavelength of from about 500-600 nanometers.

12. A detergent composition useful for cleaning and/or conditioning human hair or skin or cleaning dishes or clothing which contains NaCl or NH₄ Cl and further contains a nonionically, anionically and cationically derivatized polygalactomannan, the molecular substitution of the nonionic substituent being between about 0.14 and about 1.2, the degree of substitution of the anionic substituent being between about 0.10 to about 0.30 and the degree of substitution of the cationic substituent being between about 0.20 to about 1.0, said composition having a viscosity of greater than about 500 centipoises and said composition having greater than 75% light transmission at a wavelength of from about 500-600 nanometers.

13. The composition according to claim 12 which is selected from the group consisting of personal care compositions and industrial cleaning compositions.

14. The composition according to claim 13 comprising a personal care composition useful for cleaning and/or conditioning human hair or skin.

15. The composition according to claim 14 wherein the composition includes NaCl present in an amount of between about 0.5 and about 3.0 percent by weight of the composition.

16. The composition according to claim 12 wherein said nonionic substituent comprises hydroxyalkyl groups, wherein alkyl represents a straight or branched hydrocarbon moiety having between 1 and about 6 carbon atoms.

17. The composition according to claim 16 wherein said nonionic substituents are selected from the group consisting of hydroxyethyl and hydroxypropyl.

18. The composition according to claim 12 wherein said cationic groups are quaternary groups.

19. The composition according to claim 18 wherein said cationic substituents are of the formula ##STR3## wherein R₁ is a monohydroxylated or polyhydroxylated alkyl group containing between one and about six carbon atoms;

R₂ and R₃ are independently, alkyl groups containing between one and about six carbon atoms;

R₄ is an alkyl group containing between one and about 24 carbon atoms; and

X is a halide.

20. The composition according to claim 12 wherein said cationic substituents have a degree of substitution between about 0.23 and about 0.80.

21. The composition according to claim 12 wherein said anionic groups comprise carboxyalkyl groups wherein alkyl represents a straight or branched hydrocarbon moiety having between 1 and about 6 carbon atoms.

22. The composition according to claim 21 wherein said anionic groups comprise carboxymethyl groups.

23. The composition according to claim 12 having a greater than 90% light transmission at a wavelength of from about 500-600 nanometers.