Hydrocarbon gas conversion system and process for producing a synthetic hydrocarbon liquid

• US 5,733,941 A
• Filed: 02/13/1996
• Issued: 03/31/1998
• Est. Priority Date: 02/13/1996
• Status: Expired due to Term

• Current Assignee: REG Synthetic Fuels, LLC (Chevron Corp.)
• Original Assignee: Marathon Oil Company (Marathon Oil Corporation)
• Inventors: Waycuilis, John J.
• Primary Examiner(s): Geist, Gary
• Assistant Examiner(s): PADMANABHAN, SREENIVASAN
• Application Number:
  US08/600,565
• Time in Patent Office: 777 Days
• Field of Search: 518/703
• US Class Current: 518/703
• CPC Class Codes: C01B 2203/0244 the reforming step being an autothermal reforming step, e.g. secondary reforming processes
• CPC Class Codes: C01B 2203/0415 Purification by absorption in liquids
• CPC Class Codes: C01B 2203/062 Hydrocarbon production, e.g. Fischer-Tropsch process
• CPC Class Codes: C01B 2203/0883 by indirect heat exchange
• CPC Class Codes: C01B 2203/0894 Generation of steam
• CPC Class Codes: C01B 2203/1052 Nickel or cobalt catalysts
• CPC Class Codes: C01B 2203/1241 Natural gas or methane
• CPC Class Codes: C01B 2203/127 Catalytic desulfurisation
• CPC Class Codes: C01B 2203/1276 Mixing of different feed components
• CPC Class Codes: C01B 2203/141 At least two reforming, decomposition or partial oxidation steps in parallel
• CPC Class Codes: C01B 2203/142 At least two reforming, decomposition or partial oxidation steps in series
• CPC Class Codes: C01B 2203/148 involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
• CPC Class Codes: C01B 2203/1604 Starting up the process
• CPC Class Codes: C01B 2203/82 Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
• CPC Class Codes: C01B 2203/84 Energy production
• CPC Class Codes: C01B 3/382 Multi-step processes
• CPC Class Codes: C07C 1/0405 Apparatus
• CPC Class Codes: C07C 1/0485 Set-up of reactors or accessories; Multi-step processes
• CPC Class Codes: F23C 2201/301 with different fuels in stages
• CPC Class Codes: F23C 6/047 with fuel supply in stages
• CPC Class Codes: F23R 3/346 : for staged combustion
• CPC Class Codes: F23R 3/36 : Supply of different fuels
• CPC Class Codes: Y02P 20/10 : Process efficiency

Abstract

A system and process are provided for converting a light hydrocarbon gas to a synthetic heavier hydrocarbon liquid. The system includes an autothermal reformer, a Fischer-Tropsch reactor and a Brayton cycle that are structurally and functionally integrated. In the practice of the process, a mixture of a hydrocarbon feed gas, a compressed air feed and process steam is fed to the autothermal reformer to produce a synthesis gas. The synthesis gas is fed to the Fischer-Tropsch reactor where it is catalytically reacted to produce heavy hydrocarbons. The outlet from the Fischer-Tropsch reactor is separated into water, a low heating value tail gas, and the desired hydrocarbon liquid product. The water is pressurized and heated to generate process steam. The tail gas is heated and fed with compressed air and steam to the Brayton cycle having a combustor and a series of power turbines and compressors. The tail gas and air feed are burned in the combustor to produce a combustion gas that is used to drive a power turbine linked by a shaft to an air compressor, thereby driving the air compressor. The system further includes a plurality of heat exchangers that enable heat to be recovered from the outlet of the autothermal reformer. The recovered heat is used to make the process steam as well as to preheat the hydrocarbon feed gas before it is fed to the autothermal reformer, preheat the synthesis gas before it is fed to the Fischer-Tropsch reactor and preheat the tail gas before it is fed to the combustor.

Claims

1. A process for converting a lighter hydrocarbon gas to heavier hydrocarbons comprising:

a) reacting an air feed and a lighter hydrocarbon feed gas in a first reactor to produce a synthesis gas comprising hydrogen and carbon monoxide;

b) feeding said synthesis gas to a second reactor containing a hydrocarbon synthesis catalyst and reacting said synthesis gas in the presence of said hydrocarbon synthesis catalyst to produce heavier hydrocarbons, a dilute tail gas and water, wherein said dilute tail gas contains at least about 90 mole percent inert non-combustible components;

c) feeding said dilute tail gas to a combustor and combusting said dilute tail gas in said combustor to produce a combustion gas;

d) driving a power turbine with said combustion gas; and

e) driving an air compressor with said power turbine to compress said air feed to said first reactor.

2. The process of claim 1 further comprising heating said water with said synthesis gas to produce process steam.

3. The process of claim 2 further comprising feeding a portion of said process steam to said combustor.

4. The process of claim 2 further comprising feeding a portion of said process steam to said first reactor.

5. The process of claim 1 further comprising feeding a portion of said air feed to said power turbine.

6. The process of claim 1 further comprising feeding a portion of said air feed to said combustor having a burner.

7. The process of claim 6 wherein said portion of said air feed is split into a primary feed and a secondary feed, said primary feed fed to said combustor upstream of said burner and said secondary feed fed to said combustor downstream of said burner.

8. The process of claim 1 further comprising heating said dilute tail gas with said synthesis gas upstream of said combustor to increase the flame temperature of said dilute tail gas upon combustion in said combustor.

9. The process of claim 1 further comprising heating said lighter hydrocarbon feed gas with said synthesis gas.

10. The process of claim 1 wherein said power turbine is a first power turbine, said process further comprising driving a second power turbine with said combustion gas and wherein said second power turbine is positioned in series with said first power turbine.

11. The process of claim 10 further comprising driving a synthesis gas compressor with said second power turbine to compress said synthesis gas fed to said second reactor.

12. The process of claim 10 further comprising driving an electrical generator with said second power turbine to generate electric power.

13. The process of claim 1 wherein said combustor is external to said power turbine.

14. The process of claim 1 wherein said combustor is internal to said power turbine.

15. The process of claim 1 wherein said inert non-combustible components of said dilute tail gas include nitrogen.

16. The process of claim 1 further comprising driving an electrical generator with said power turbine to generate electric power and driving an electric motor with said electric power.

17. The process of claim 16 further comprising driving a synthesis gas compressor with said electric motor to compress said synthesis gas to said second reactor.

38. The process of claim 1 wherein the remainder of said dilute tail gas includes combustible components.

39. The process of claim 38 wherein said combustible components include hydrogen, carbon monoxide and hydrocarbons.

18. A process for converting a lighter hydrocarbon gas to heavier hydrocarbons comprising:

a) reacting a gaseous mixture comprising an air feed and a lighter hydrocarbon feed gas to produce a synthesis gas comprising hydrogen and carbon monoxide;

b) reacting said synthesis gas in the presence of a hydrocarbon synthesis catalyst to produce heavier hydrocarbons, a dilute tail gas and water, wherein said dilute tail gas contains at least about 90 mole percent inert non-combustible components;

c) preheating said dilute tail gas with said synthesis gas and combusting said dilute tail gas at an increased flame temperature to produce a combustion gas;

d) generating mechanical power with said combustion gas; and

e) compressing said air feed with said mechanical power.

19. The process of claim 18 further comprising heating said water with said synthesis gas to produce process steam.

20. The process of claim 19 wherein said dilute tail gas is combusted in the presence of said process steam.

21. The process of claim 18 wherein said dilute tail gas is combusted with a portion of said air feed.

22. The process of claim 18 further comprising heating said lighter hydrocarbon feed gas with said synthesis gas.

23. The process of claim 18 further comprising compressing said synthesis gas with said mechanical power.

24. The process of claim 18 further comprising generating electric power with said mechanical power.

25. The process of claim 24 further comprising compressing said synthesis gas with said electric power.

26. The process of claim 18 wherein said inert non-combustible components of said dilute tail gas include nitrogen.

40. The process of claim 18 wherein the remainder of said dilute tail gas includes combustible components.

41. The process of claim 40 wherein said combustible components include hydrogen, carbon monoxide and hydrocarbons.

27. A process for converting a lighter hydrocarbon gas to heavier hydrocarbons comprising:

a) reacting a gaseous mixture comprising a first portion of an air feed and a lighter hydrocarbon feed gas to produce a synthesis gas comprising hydrogen and carbon monoxide;

b) reacting said synthesis gas in the presence of a hydrocarbon synthesis catalyst to produce heavier hydrocarbons, a dilute tail gas and water, wherein said dilute tail gas contains at least about 90 mole percent inert non-combustible components;

c) combusting said dilute tail gas with a second portion of said air feed to produce a combustion gas;

d) generating mechanical power with said combustion gas; and

e) compressing said first and second portions of said air feed with said mechanical power.

28. The process of claim 27 further comprising heating said water to produce process steam and combusting said dilute tail gas in the presence of said process steam.

29. The process of claim 27 further comprising heating said lighter hydrocarbon feed gas with said synthesis gas.

30. The process of claim 27 further comprising compressing said synthesis gas with said mechanical power.

31. The process of claim 27 further comprising generating electric power with said mechanical power.

32. The process of claim 31 further comprising compressing said synthesis gas with said electric power.

33. A process for converting a lighter hydrocarbon gas to heavier hydrocarbons comprising:

a) reacting a gaseous mixture comprising an air feed a lighter hydrocarbon feed gas to produce a synthesis gas comprising hydrogen and carbon monoxide;

b) reacting said synthesis gas in the presence of a hydrocarbon synthesis catalyst to produce heavier hydrocarbons, a dilute tail gas and water, wherein said dilute tail gas contains at least about 90 mole percent inert non-combustible components;

c) heating said water to produce process steam;

d) combusting said dilute tail gas in the presence of said process steam to produce a combustion gas;

e) generating mechanical power with said combustion gas; and

f) compressing said air feed with said mechanical power.

34. The process of claim 33 further comprising heating said lighter hydrocarbon feed gas with said synthesis gas.

35. The process of claim 33 further comprising compressing said synthesis gas with said mechanical power.

36. The process of claim 33 further comprising generating electric power with said mechanical power.

37. The process of claim 36 further comprising compressing said synthesis gas with said electric power.