Asphalt cement modification

• US 5,733,955 A
• Filed: 01/13/1997
• Issued: 03/31/1998
• Est. Priority Date: 02/10/1995
• Status: Expired due to Fees

• Current Assignee: Goodyear Tire & Rubber Company
• Original Assignee: Goodyear Tire & Rubber Company
• Inventors: Schulz, Gerald Owen, Klemmensen, Daniel Frederick
• Primary Examiner(s): Szekely, Peter A.
• Application Number:
  US08/782,746
• Time in Patent Office: 442 Days
• Field of Search: 524/59, 524/60, 524/69, 525/54.5
• US Class Current: 524/69
• CPC Class Codes: C08F 236/10 with vinyl-aromatic monomers
• CPC Class Codes: C08L 25/00 Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 95/00 Compositions of bituminous materials, e.g. asphalt, tar, pitch

Abstract

It has been determined that rubbery terpolymers of a conjugated diolefin monomer, a vinyl aromatic monomer, and N-(isobutoxymethyl) acrylamide (IBMA) can be used to modify asphalt cement to greatly enhance the resistance to shoving, rutting, and low temperature cracking of asphalt concretes made therewith. These rubbery polymers have a Mooney viscosity which is within the range of about 35 to about 80. It has further been determined that these rubbery terpolymers are compatible with virtually all types of asphalt. It is particularly preferred for the rubbery polymers of this invention to also contain repeat units which are derived from hydroxypropyl methacrylate (HPMA). The subject invention more specifically relates to a modified asphalt cement which is comprised of (1) from about 90 weight percent to about 99 weight percent of asphalt; and (2) from about 1 weight percent to about 10 weight percent of a rubbery polymer which is comprised of repeat units which are derived from (a) about 64 weight percent to about 84.9 weight percent of a conjugated diolefin monomer, (b) about 15 weight percent to about 33 weight percent of a vinyl aromatic monomer, and (c) about 0.1 weight percent to about 3 weight percent of isobutoxymethyl acrylamide, wherein the repeat units in the rubbery polymer which are derived from the conjugated diolefin monomer, the vinyl aromatic monomer, and the isobutoxymethyl acrylamide are in the backbone of the rubbery polymer.

Claims

1. An asphalt concrete which is comprised of (A) from about 90 weight percent to about 99 weight percent of an aggregate, and (B) from about 1 weight percent to about 10 weight percent of a modified asphalt cement which is comprised of (1) from about 90 weight percent to about 99 weight percent of asphalt;

and (2) from about 1 weight percent to about 10 weight percent of a rubbery polymer which is comprised of repeat units which are derived from (a) about 64 weight percent to about 84.9 weight percent of a conjugated diolefin monomer, (b) about 15 weight percent to about 33 weight percent of a vinyl aromatic monomer, and (c) about 0.1 weight percent to about 3 weight percent of isobutoxymethyl acrylamide, wherein the repeat units in the rubbery polymer which are derived from the conjugated diolefin monomer, the vinyl aromatic monomer, and the isobutoxymethyl acrylamide are in the backbone of the rubbery polymer.

3. An asphalt concrete as specified in claim 1 wherein the rubbery polymer has a Mooney viscosity which is within the range of about 35 to about 80.

4. An asphalt concrete as specified in claim 3 wherein the rubbery polymer is comprised of repeat units which are derived from about 72.5 weight percent to about 81.8 weight percent of the conjugated diolefin monomer, from about 18 weight percent to about 26 weight percent of the vinyl aromatic monomer, and from about 0.2 weight percent to 1.5 weight percent of the N-(isobutoxymethyl) acrylamide.

5. An asphalt concrete as specified in claim 4 wherein the vinyl aromatic monomer is styrene.

6. An asphalt concrete as specified in claim 5 wherein the conjugated diolefin monomer is 1,3-butadiene.

7. An asphalt concrete as specified in claim 6 wherein the modified asphalt cement is comprised of (1) from about 94 weight percent to about 99 weight percent of the asphalt and (2) from about 1 weight percent to about 6 weight percent of the rubbery polymer.

8. An asphalt concrete as specified in claim 7 wherein said asphalt concrete is comprised of (A) from about 94 weight percent to about 98 weight percent of the aggregate, and (B) from about 2 weight percent to about 6 weight percent of the modified asphalt cement.

9. An asphalt concrete as specified in claim 8 wherein the rubbery polymer has a Mooney viscosity which is within the range of about 40 to about 70.

10. An asphalt concrete as specified in claim 9 wherein the rubbery polymer is comprised of repeat units which are derived from about 72.5 weight percent to about 81.8 weight percent of the 1,3-butadiene monomer, from about 18 weight percent to about 26 weight percent of the styrene monomer, and from about 0.2 weight percent to 1.5 weight percent of the N-(isobutoxymethyl) acrylamide.

11. An asphalt concrete as specified in claim 10 wherein the modified asphalt cement is comprised of (1) from about 96 weight percent to about 98 weight percent of the asphalt and (2) from about 2 weight percent to about 4 weight percent of the rubbery polymer.

12. An asphalt concrete as specified in claim 11 wherein said asphalt concrete is comprised of (A) from about 92 weight percent to about 97 weight percent of the aggregate, and (B) from about 3 weight percent to about 8 weight percent of the modified asphalt cement.

13. An asphalt concrete as specified in claim 12 wherein the rubbery polymer has a Mooney viscosity which is within the range of about 50 to about 60.

14. An asphalt concrete as specified in claim 6 wherein the rubbery polymer is further comprised of repeat units which are derived from hydroxypropyl methacrylate, and wherein the repeat units which are derived from the hydroxypropyl methacrylate are in the backbone of the rubbery polymer.

15. An asphalt concrete as specified in claim 14 wherein the weight ratio of hydroxypropyl methacrylate to N-(isobutoxymethyl) acrylamide is within the range of about 0.5:

1 to about 4;

1.

16. An asphalt concrete as specified in claim 14 wherein the weight ratio of hydroxypropyl methacrylate to N-(isobutoxymethyl) acrylamide is within the range of about 1:

1 to about 3;

1.

17. An asphalt concrete as specified in claim 14 wherein the weight ratio of hydroxypropyl methacrylate to N-(isobutoxymethyl) acrylamide is within the range of about 5:

4 to about 7;

4.

18. A pavement which is made utilizing the asphalt concrete specified in claim 1.

19. An asphalt concrete as specified in claim 14 wherein the rubbery polymer is comprised of repeat units which are derived from about 71 weight percent to about 81.5 weight percent of the conjugated diolefin monomer, from about 18 weight percent to about 26 weight percent of vinyl aromatic monomers, from about 0.3 weight percent to 1.0 weight percent isobutoxymethyl acrylamide, and from about 0.2 weight percent to about 2 weight percent hydroxypropyl methacrylate.

20. An asphalt concrete as specified in claim 14 wherein the rubbery polymer is comprised of repeat units which are derived from about 71.7 weight percent to about 81 weight percent of the conjugated diolefin monomer, from about 18 weight percent to about 26 weight percent of vinyl aromatic monomers, from about 0.4 weight percent to 0.8 weight percent isobutoxymethyl acrylamide, and from about 0.6 weight percent to about 1.5 weight percent hydroxypropyl methacrylate.

2. A modified asphalt cement which is comprised of (1) from about 90 weight percent to about 99 weight percent of asphalt;

and (2) from about 1 weight percent to about 10 weight percent of a rubbery polymer which is comprised of repeat units which are derived from (a) about 64 weight percent to about 84.9 weight percent of a conjugated diolefin monomer, (b) about 15 weight percent to about 33 weight percent of a vinyl aromatic monomer, and (c) about 0.1 weight percent to about 3 weight percent of isobutoxymethyl acrylamide, wherein the repeat units in the rubbery polymer which are derived from the conjugated diolefin monomer, the vinyl aromatic monomer, and the isobutoxymethyl acrylamide are in the backbone of the rubbery polymer, wherein the repeat units in the rubbery polymer which are derived from the conjugated diolefin monomer, the vinyl aromatic monomer, and the isobutoxymethyl acrylamide are in the backbone of the rubbery polymer.